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[太阳能] 令人惊艳的奈米碳管太阳能电池

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发表于 2007-9-13 00:09:25 | 显示全部楼层 |阅读模式 来自: 中国湖南株洲

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令人惊艳的奈米碳管太阳能电池 + Y6 A# `* Q/ _9 c. Y
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) k- x' N7 {- V: F! f% t       美國科學家近期發表了一項利用奈米碳管來提昇染料敏化太陽電池(dye-sensitized solar cell, DSSC)轉換效率的研究,這種太陽電池以二氧化鈦(TiO2) 為材料,這是一種容易取得且便宜的化合物,經常被用於塗料及遮光劑中。聖母大學(University of Notre Dame)的Prashant Kamat等人將二氧化鈦的奈米顆粒吸附於單壁式奈米碳管(single-walled carbon nanotube, SWNT)上,並由量測發現其紫外光轉換為電流的效率為僅使用二氧化鈦的兩倍。
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2 \  d' s& D4 v1 t3 A$ p) A       科學家對於利用奈米級光觸媒(photocatalyst)來設計太陽電池一向相當感興趣,特別是以奈米級二氧化鈦薄膜來修飾增感染料的太陽電池。這種太陽電池的魅力在於此奈米顆粒具有很大的潛力來吸收光能,並產生電子。雖然這類元件的太陽光轉換效率剛出場就達到10%,但之後要再進一步提昇其效能卻變得相當困難,而且其轉換效率仍然低於傳統的矽太陽電池,這是由於主動層(奈米級TiO2薄膜)產生的電子,很難被順利的傳導出來形成電流。, B0 r" m* |: x& F" U' }

! E9 P3 g) ]9 q, E       最近,Kamat等人利用奈米碳管來引導光生電荷載子(photogenerated charge carrier)的流動,使電荷更容易到達電極成為電流。為了達成這個結果,研究人員於電極(碳纖維或導電玻璃)上形成一層奈米碳管,這層奈米碳管就如同支架一般,支撐著後續沉積於其上的TiO2奈米顆粒。奈米碳管不但可以有效地收集生成的電子,並且提供一個更直接的路徑指向電極,因此可以改善太陽能電池的效率。/ q* ]! S7 I. d# c- o9 H

$ ~$ A+ A8 p8 H9 Z) d        這個新的奈米碳管與奈米顆粒系統目前尚未實際應用於太陽電池的模組上,這是由於TiO2僅能吸收紫外光,而大部分的可見光波仍會被反射。然而,研究者說明,藉由在奈米顆粒表面上包覆量子點(quantum dots)的方式,目前已經可以吸收入射光中的可見光波段;由於量子點能將高能量的光子轉換為多個電子,並非像在傳統材料中一個光子僅能產生一個電子,因此可以使整體的轉換效率更加提升。
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[ 本帖最后由 清风明月008 于 2007-9-13 19:06 编辑 ]
发表于 2007-9-13 14:07:40 | 显示全部楼层 来自: 中国上海
图呢?楼主如果有DSSC最新的资料还望上传一些,谢谢!
发表于 2007-9-13 15:17:36 | 显示全部楼层 来自: 中国上海
怎么全是繁体字的?
 楼主| 发表于 2007-9-13 19:09:01 | 显示全部楼层 来自: 中国湖南株洲
我同时将英语原文发在下面:
# v, P4 \0 ^! x+ vNew look for solar cells- X# @, d% \, @$ ^; h8 @& w
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7 March 2007" R: L- ]* x: m& }
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Researchers in the US have shown that carbon nanotubes can significantly improve the efficiency of solar cells made of titanium dioxide, a readily available and cheap chemical routinely used in paint and sunscreen. Prashant Kamat and colleagues at the University of Notre Dame, Indiana, anchored titanium dioxide nanoparticles on single-walled carbon nanotubes and found that the efficiency of converting ultraviolet light into current was doubled compared to that using the nanoparticles alone.
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+ ^& C; ]- R% h$ D+ ~; d! \2 d       Researchers are interested in using the photocatalytic activity of nanostructured semiconductor films to design solar cells. Of particular importance is the dye-sensitized solar cell, which uses nanostructured titanium dioxide (TiO2) films modified with sensitizing dyes. Such cells are appealing because nanoparticles have a great potential for absorbing light and generating electrons. However, despite the initial success of achieving 10% solar conversion efficiency, efforts to further improve their performance have been difficult and the performance of devices made of such cells lies well below that of conventional silicon solar cells. This is because it is difficult to harness all the electrons generated in the nanostructured TiO2 cells to create a current. 6 \8 q5 r3 z# b2 _% r+ S

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http://images.iop.org/objects/nano/news/thumb/6/3/7/070307.jpg
  [. g3 ]" b* oNanostructured films
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       Now, Kamat and colleagues have used carbon nanotubes to direct the flow of photogenerated charge carriers so that they can reach an electrode more easily, where they can then generate an electrical current. The nanotubes effectively "collect" the electrons and provide a more direct route to the electrode, therefore improving the efficiency of the solar cells (see figure). 0 B6 f& j8 n0 {
       The Notre Dame researchers achieved their result by forming a mat of carbon nanotubes on carbon fibre and glass electrodes. The nanotubes serve as a scaffold on which TiO2 particles are then deposited. Kamat says that this is a very simple solution for bringing order into a disordered structure. 7 u" }3 W1 `  z% H/ a, R7 Q9 ]
        The new carbon nanotube-nanoparticle system has not yet been made into a practical solar cell because the TiO2 only absorbs ultraviolet light – most of the visible spectrum of light is reflected. However, the researchers say they have already shown ways to absorb light in the visible region too, by coating the nanoparticles with quantum dots (tiny semiconductor crystals). Here, the dots can convert high-energy photons into multiple electrons, unlike in conventional materials in which one photon generates just one electron. 5 _5 V5 H& B* V1 K/ s* j
        The researchers reported their work in Nano Lett..
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[ 本帖最后由 清风明月008 于 2007-9-13 19:10 编辑 ]
发表于 2008-2-4 16:48:27 | 显示全部楼层 来自: 中国广东深圳
斑竹,这是什么啊,看不懂啊!
发表于 2008-2-5 09:42:10 | 显示全部楼层 来自: 中国江苏南京
请教楼主,奈米碳管是不是比纳米碳管更小?谢谢楼主!!!
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