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循环流化床烟气脱硫技术实验研究
8 ]7 c. e3 \9 v. L王爱军,祁海鹰,由长福,徐旭常
" I. c, I3 F) F1 U6 B+ a0 ~(清华大学煤的清洁燃烧技术国家重点实验室,北京100084)# P- y; K4 v S
摘 要:提出一种干式烟气脱硫技术方案,并在400~800℃的温度下进行了实验研究。为了提高脱硫效率和脱硫
g: W2 C0 a- |: M& j9 K$ ]剂的利用率,还对在床内循环的脱硫剂进行了蒸汽处理。研究了烟气温度、Ca/S、床内气流速度、床内固体物料浓度) x/ R) e* y. e7 }8 c/ [% d# Z
等参数对脱硫效率的影响,以及各参数之间的关系。研究发现温度对脱硫效率有明显的影响,近600℃时最高。增
0 J: X. _3 Y$ X6 ~9 t: I% |加Ca/S可以大幅度提高脱硫效率。此外,适当降低床内气体流速使床内的总物料量增加,可以提高脱硫效率。研究: b& d e# k4 D/ `& z6 V
表明,蒸汽处理对脱硫效率的提高有明显效果,在本实验条件下,处理后的脱硫效率提高42.1%。+ O9 D: T9 E/ A7 w6 a
关键词:循环流化床;烟气脱硫;蒸汽活化;脱硫效率9 Z1 k! R U6 g2 R
中图分类号:TQ534.9 文献标识码:A 文章编号:1006-8740(2000)04-0351-054 w) Q) I) K3 y" q4 S& e6 m3 d
Experimental Study of FGD Technology by CFB at 400~800℃ Q! o. h% ^! x8 ^. P0 F
WANG Ai-jun, QI Hai-ying, YOU Chang-fu, XU Xu-chang
, T) H* |8 B) C i8 g: D7 L(The State Key Laboratory of Clean Combustion of Coal,Tsinghua University,
% j! ]5 p! O* B/ F+ W4 ~7 a, K8 n) mBeijing 100084,China)
# @! M+ M/ h) H+ J5 rAbstract:A new type dry flue gas desulphurization proposal in a temperature range of 400~800℃has been1 w3 `/ u2 D1 V
introduced.The experiment was done at 400~800℃in a circulating fluidized bed (CFB) using lime as absorbent
$ s" P% r# a# G' `and fly ash collected from power plants as bed materials. To make the absorbents more effective, the spent+ r2 ?$ ~. P$ k6 ?1 @/ B, Y
absorbent was treated by steam in the circulating loop. The experiments showed that the influence of gas
* Q& S* U1 c7 v1 |7 p3 s( ^temperature on desulphurization efficiency was obvious, and perhaps there was an optimum desulphurization
5 b' U8 ]* f+ C) s! w' n, `efficiency near 600℃.As Ca/S was increased the desulphurization efficiency would be increased greatly.The Total2 P, v8 @! F5 {( l
amount of bed materials was increased as the gas velocity inside the bed was decreased,so the desulphurization
7 y" V' _+ p7 \, Nefficiency would be increased. The steam reactivation was an effective method for increasing the absorbent
4 `& E5 O; `+ mutilization because the desulphurization efficiency was increased by 42.1% after the absorbent was treated by; n+ N3 Q9 q4 {- t, q5 o* S% B; B
steam.Therefore the dry flue gas desulphurization technology in a CFB added steam reactivation is worth of( x- c9 l/ E) Z$ k: h' G/ i/ U5 R
researching further.7 e1 K' Y" L h+ i7 \
Keywords:CFB;flue gas desulphurization;steam reactivation;desulphurization efficiency |
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