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Green Chemistry and Catalysis绿色化学与催化剂
G% ^' B5 Z" ^( zComposition :K+V Fotosatz GmbH, Beerfelden( l; a, W) K1 k7 D* O# [8 C* s
Printing :betz-druck GmbH, Darmstadt, @* H" e6 C' B6 x# ]& F
Bookbinding: Litges & Dopf GmbH, Heppenheim. F! y/ Z# d( ^+ \* u2 Y$ d
Cover Design :Schulz Grafik-Design, FuSgonheim
( `' q5 E/ u/ r( R1 i6 PWiley Bicentennial Logo Richard J. Pacifico
* M0 {4 H2 q8 N, P# m4 }Printed :in the Federal Republic of Germany
, W. G, h% r5 uISBN 978-3-527-30715-9
7 r+ Z! W4 N G2 o( |2 Bpage:445
7 \' X6 P# u% Z" S( h: o- F: vThe Author:Prof. Dr. Roger Sheldon8 V" O0 u$ p$ F g
Each generation has its unique needs and aspirations. When Charles Wiley first
2 t# f8 j( j6 F; ~" i, `/ J9 o& Aopened his small printing shop in lower Manhattan in 1807, it was a generation* U1 h# `3 W# J6 |7 i
of boundless potential searching for an identity. And we were there, helping to4 i2 M8 X. W8 H x$ _
define a new American literary tradition. Over half a century later, in the midst
: p, B/ B% c! {3 _( yof the Second Industrial Revolution, it was a generation focused on building; \! A* P. w, B5 l( Y( s& ?! K* q7 c
the future. Once again, we were there, supplying the critical scientific, technical,
+ B( x2 A# ~$ P2 land engineering knowledge that helped frame the world. Throughout the 20th
( s+ G5 ?2 C9 z- C; O0 ?9 ACentury, and into the new millennium, nations began to reach out beyond their
+ p; c) n/ n jown borders and a new international community was born. Wiley was there, ex-7 ?- E8 T, |9 I+ _& v% }1 t8 ]5 f. l
panding its operations around the world to enable a global exchange of ideas,
, d# X2 F& p9 z% Y2 | [opinions, and know-how.0 b% W* t# B+ m$ b$ s- @2 ?; E
Contents5 U7 c' s- e8 i
Preface XI0 ?" B# u8 r# d( V2 s
Foreword XIII6 j' _) n5 k+ z3 ]" `9 W
1 Introduction: Green Chemistry and Catalysis 1
/ h, ^+ H3 }* l' [6 X% X, ~1.1 Introduction 1
1 I# p, ]' _+ o" y) n i) v1.2. E Factors and Atom Efficiency 28 t" R! O% f+ Y, G- d' O O
1.3 The Role of Catalysis 5' o* B* l2 a$ Y
1.4 The Development of Organic Synthesis 8
) @; }0 M9 C2 Y9 L# O1.5 Catalysis by Solid Acids and Bases 10 |6 g: {, c& [+ M4 p o1 y
1.6 Catalytic Reduction 14
6 w7 Q5 {; V2 [7 R1.7 Catalytic Oxidation 18
3 _( U- ~0 ^% K J5 H1.8 Catalytic C–C Bond Formation 237 ~2 C. X8 Z% n3 h3 p' `2 s Q" L
1.9 The Question of Solvents: Alternative Reaction Media 27+ E8 J' n2 K( }/ m# |- m: `
1.10 Biocatalysis 29
4 [% Q* U: R& Q% D/ |& W1.11 Renewable Raw Materials and White Biotechnology 34
* q$ T9 R) @8 E2 k+ x" ]6 u1.12 Enantioselective Catalysis 35
c6 R" H$ v' _5 h8 H1.13 Risky Reagents 38
4 Y" J. U/ k' o# A- O l7 V1.14 Process Integration and Catalytic Cascades 39, D5 d+ I3 |$ k$ ~0 ^6 V- m6 X5 E
References 43
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