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全书3个压缩卷,解压后5.67M) B3 w- x7 ]- X% J- u6 o- _
书名An Introduction to the Analysis of Spin-Spin Splitting in High-Resolution Nuclear Magnetic Resonance
6 N: s6 O/ E/ b) |( Z) k* ?作者John ID. Roberts
" n D( k/ p! }2 [出版社W. A. Benjamin, Inc., New York
! D4 q; }: \' I" n7 S" h3 }# q出版日期1961
! Q8 `% }! a. ^3 k! D6 h出版号 61-12990 . i U4 {! y. `2 i/ L
页数133
, i9 F) \% m0 Q, E, I内容简介
) T r/ ^# e2 I) U4 z6 ?learn to apply the methods of wave mechanics in a prac- 8 \$ j" {) i: e* q1 ^! S
tical way seems to involve a quantum-like transition with a
6 v0 z0 O, E9 m$ C) Mrelatively low transition probability. Chemistry students by ' f& _9 ~- k+ F0 A
the thousands are exposed to the principles and jargon of 6 t0 i8 h' h" h! c3 F6 ]4 n
wave mechanics and are able to talk in a most knowing way % B6 ] e6 q+ y, L. }: f9 N
about orbitals, overlap, spin, etc. But very few of these stu-
6 O3 d8 g- d% w1 z; I6 ^- @dents can set about to make any sort of an actual calculation 5 O1 W7 {7 u" W- q8 i7 V9 m. t; i
of resonance energies of conjugated systems or the energy : d7 z2 i4 E) y2 q. Q$ n0 f
levels of nuclear spin systems, and this despite the fact that ! S$ P) e3 y; F, F$ Y
the mathematics involved, although perhaps tedious, usu- . ]9 @0 f! V& h% l2 [
ally does not require more than college algebra.
5 @& S! V! h% k7 l! N2 i4 N目录
: }# y8 Z4 A: h6 F1. INTRODUCTION. NUCLEAR MAGNETIC RESONANCE ABSORPTION 1 : ] K5 O; d* R7 Q- p5 Q7 ?7 y
1-1. Nuclear magnetic resonance absorption, 2 ) N6 C8 Y+ S2 }- x N% Y
1-2. Chemical shifts, 4 * D- |1 J) l5 ?- B1 w* O- ~( i
1-3. Spin-spin splitting-qualitative theory, 7 ( v8 t' K0 \0 c, t, y
2. QUANTUM MECHANICAL TREATMENT OF SPIN-SPIN 25 ' q9 V0 T8 e" [3 q
INTERACTION BETWEEN TWO NUCLEI $ m; w9 M6 }! f" e
2-1. Qualitative treatment of the AX system, 25 - T* B7 ~ ?9 r/ u8 g) P
2-2. Qualitative and quantitative treatment of the
/ z0 [3 y; e3 x- v5 l) H: O" s6 @+ QA2 system, 30 6 E) O- j- H* @8 v) t) Z
2-3. Quantitative treatment of the AB system, 49
, w$ T5 t0 {% i6 j3-1. The AMX and AX2 systems, 63
: L0 W5 ? q. L# u3 v* y7 C5 `# U3-2. The AB2 system, 65
' s% g) O8 N2 B4 ~; a v+ Z3-3. The ABX system, 71 0 T( A1 _/ V6 f
3-4. The ABC system, 85 ) r- j) n8 W/ \. |/ d& X
4. A FOUR-SPIN SYSTEM. A2X2 89 , }0 t9 w2 O: L6 i5 J
4-1. The A2X2 system, 90
8 D1 i& f# h8 }3 U' }. bPrognosis 103 6 |" U+ {4 @$ `& T3 ^1 J4 |
Name Index 107
' L. A9 X- s6 j7 S i1 e$ b) h3 zSubject Index 109
% Z v! j, a" Y0 }* v2 F( E( e& k& P7 K: v7 n7 @$ q% N4 l
[ 本帖最后由 fenglianxiang 于 2008-6-26 16:59 编辑 ] |
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