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[书籍] 《核磁共振在有机化学中的应用》英文PDF电子书

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全书4个压缩卷,解压后7.91M
8 J7 Y4 r. @. B+ b1 J4 o: u书名Nuclear Magnetic Resonance  applications to organic chemistry
' D0 V1 h) l* }- a( y作者John ID. Roberts 4 S; C6 M: N% j
出版社McGRAW-HILL  BOOK  COMPANY, IN
- O' k" g; ^$ k% u6 C出版日期1959
1 o) |0 a" A; D5 E出版号 58-13888
! ~5 O" ~' O9 v( n页数133
. J( j9 ^  J$ S7 G( \内容简介0 O; a& l3 K0 b% R4 \
This brief book is the outgrowth of  some forty lectures in which it was 3 w; d4 X  H( A% L$ g) D
attempted to explain the phenomenon of  nuclear magnetic resonance
; y1 z' }  @3 Zabsorption and the uses of  high-resolution nuclear magnetic resonance
; h" f; Z- H+ W4 Wspectroscopy to organic chemists whose background, like that of  the
1 Y* A) c! K* f/ {$ t( Xauthor, has often been deficient in nuclear and-qlectromagnetic theory. 1 G3 K  n) p  @4 J& x- K5 V" C
Quite a number  of  suggestions were received for presentation of  the
0 ]' Z. O. [# _1 b# Dmaterial in printed form with illustrations based on the lecture slides. ( n) o9 ~( g; u" `# q$ U  y  Y
This has now been done, and it is hoped that the result will bepf service
9 L5 P8 H! Q; T% Z2 }5 s4 A2 po practicing chemists and students as a guide to various applic+ns  of
* P3 t* y9 r) u4 B; @NMR spectroscopy and an introduction to more authoritative works. 8 S+ y3 Z# t+ h: @' z7 M! w' o
Throughout, the coverage is illustrative rather than comprehensive. 5 @; {) u5 Y; s  k
目录
; ?( V# y1 ?& K; {% U1 . Introduction . The Nuclear Resonance Phenomenon
4 P2 h. @0 Y& `8 {% }: P1.1 . Introduction  ...........
7 j% ^  |  b3 ]/ p% H1 v# Y1.2 . Nuclear Magnetic Resonance Spectrometers  .
. p& B2 D; c4 s% ~3 Z! i1.3 . Magnetic Properties of  Nuclei . Nuclear Spin
7 m) d! x$ ~# J6 e. D8 A1.4 . Magnetic Quantum Numbers  ......
: x! ^8 d* Z$ y1.5 . Nuclear Precession  .........
8 S2 f6 y0 [0 T, J7 b% n0 r1.6 . Nuclear Relaxation  .........
1 I$ s$ i8 E! }  ?& [! @  w1.7 . Longitudinal Relaxation, TI  ...... * s0 P+ @# c# E2 n6 j1 n' O
1.8 . Transverse Relaxation, T,  ....... . F3 k8 b: R7 T" \3 R: V! o6 \: R: v' o, L
1.9 . The Nuclear Resonance Signal  ..... ! S8 z) E$ k  s
1.10 . Relaxation Effects on NMR Signals .... . M" _: H1 R- ~" F
1.11 . Properties of  Magnetic Nuclei of Interest to
1 u: A1 z3 Y" dOrganic Problems .......... 1 K# |; J; u- Y$ _9 e
2 . The Chemical Shift ..............
9 H. J4 u- u7 U( g8 k; n2.1 . Introduction . The Chemical-shift Parameter  .... / W6 K8 w/ I# S; {" O1 y% p/ P( b
2.2 . Measurement  of  Chemical  Shift  . .......
0 l( L0 r: A% N: {3 g2 W1 S3 c5 ~& \2.3 . Some Factors Which  Influence 6  ....... . m, N0 N1 u- e8 t$ [9 N5 `
2.4 . Chemical Shifts for Other Nuclei  ....... " U! |, d' Y) g& m3 o/ D
2.5 . Proton 6 Values and Electronegativity ......
3 h" P1 E; V4 @/ |( Q/ I% r2.6 . 6 and Hammett's a Constants .........
4 H- c; j' r/ d+ Q8 ~- ?) C2.7 . Resonance Signal Areas and Widths  ......
1 Q% X8 E, D$ ~2 k" P2 E) [2.8 . Chemical Shifts and Organic Structure Determinations .
& P1 @6 o9 U! D3 E! U& q8 r) MGeneral  Considerations  .......... 5 n% y: P& l9 e" S. z! c+ d
2.9  . Illustrative Analysis of  a Reaction Product  ....
1 M  r0 L1 c* B+ f  |7 r4 O2.10 . Accentuation of  Chemical Shifts by Paramagnetic Salts
2 J% h9 t+ }6 N% ^3 . Spin-Spin Splitting  ........... 2 C7 j: h' Y, f, m2 f3 S! W
3.1 . The High-resolution Ethanol Spectrum ... ..... 42
2 o9 U* F$ d1 D: ~# z# k2 a& W3.2  . Spin-Spin Splitting in a Single Crystal  ... ..... 43
  E* u/ E7 U2 j) E& E$ R: E3.3  . Spin-Spin Splitting in  Liquids ...... ..... 45
  `, W3 U8 ^" g* }1 I3.4 . Spin-Spin Splitting in the Ethyl Group  ... ..... 46 0 e- N: A& x, K
3.5 . More Complex Spin-Spin Splittings .... ..... 48
0 L7 f* p8 q/ o! ~4 w0 }3.6 . Magnitudes of Coupling Constants  .... ..... 53
" p" g+ F' }3 {0 F' S2 L* _" c3.7 . Coupling between Equivalent and Nearly Equiv ,alent Protons .  55
) I, s6 T9 Q: M' a4 J3.8 . Spin-Spin Couplings in Rigid Systems  ... .... 57
+ N6 L2 ^! Y1 W4 C# B: t8 B2 l% G3.9  . Spin-Spin Splitting and Molecular Asymmetry  ..... 58 3 ^' \  D& d4 g' Y0 X' s/ J
4 . Nuclear Magnetic Resonance and Reaction Kinetics  ..... 61 9 z! ~6 A0 I+ Z" s- Z9 w7 z
4.1 . Introduction . Proton Exchange in Water-Acetic 5 w9 x2 a; q& i+ t' L9 W4 K
Acid Mixtures  ................ 61
& B/ J$ y3 C& K4.2 . Relationship between Resonance Line Shapes and 5 o; ~, w1 V' D6 N& U
Exchange Rates  ............... 63
  a) u) ~& l( a5 ~+ W* G/ j1 c3 y( ~4 G4.3 . Proton  Exchange  in  Ethanol-Water  Mixtures  ..... 64
6 T# Y8 n$ ]$ \1 g2 g; X4.4  . Ethyl Acetoacetate and Its En01 Form  ........ 67
* O7 S, @- i* I$ X, S+ U4.5 . Rates of  Rotation Around 40-N< Bonds of Amides ... 69
7 P) b; P3 S! z- J6 d' g4.6 . Restricted  Rotation  in  Ethane  Derivatives  ...... 71 $ f& s% |* K9 O  g& Z( s' O& k2 v
4.7 . Nitrogen Inversion Frequencies of  Cyclic Imines  .... 74 3 O8 b3 |+ a, E( S0 J' Q5 N  ?
4.8 . Proton Exchange in Ammonia and Ammonium Ions  ... 76 ; B6 Y3 Q7 h# A. b0 z* }6 I; t
5 . Nuclear Quadrupole Relaxation Effects . Double Resonance ... 80
4 v5 ?/ e5 m$ R. Y+ N( h1 U7 a5.1 . Proton Resonance Line Broadening by  1iN  ...... 80 - p0 r  b, b7 e- C1 r
5.2 . Nuclear Quadrupoles and Quadrupole-induced Relaxation .  .  81
6 }3 R' g1 k! b$ [, p5.3  . Proton N-K  Resonance of Pyrrole . Double Resonance  .  .  83 , I% t  P2 L) L0 o9 c
5.4 . Quadrupole-induced Relaxation with Other Nuclei .... 84
# Z! N+ H$ C8 |  A; [( k6 Y5.5 . Applications of  Double Resonance  ......... 86 7 j' h, w& n9 R4 p( @8 m, M% @
Appendix A . The Bloch Equations  ............ 88 # n+ {% ]1 Q4 J0 i$ I, R- O
Appendix B . Bibliography  .............. 99
: \  q$ B) g1 tAppendix C . Problems ................ 100 7 e5 z- ^; n( m5 K7 f  T6 S
Name Index  ................... 111
+ L" V+ Q! s/ a  R! v- n( PSubject Index ................... 113
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