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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。
/ O! I# X+ C' h n" m8 H! M+ h1 F8 b: a+ q% k" ~, T: ]" R5 z
Volume I
* R/ Y$ x! _9 n1 q8 `9 g9 b1 Introduction" Y& Y8 t8 B: N/ w' i) Z
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
8 o# f3 g$ p: P1 m2 Historical Perspective/ P6 l, t6 n6 C6 A/ w& n$ v" d. [! U( m
Henri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9+ P( G6 ~) M4 V [
3 Basic Principles of Asymmetric Synthesis
. C4 \/ A+ N) h0 LJohann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33& ~! y& [' J' }" l, @
4 General Aspects of Asymmetric Catalysis
) h6 t" F9 T% J7 k1 S) g4 ]4.1 Non-Linear Effects and Autocatalysis
. w" S X' R' {* l" p( }1 d% ^Henri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 1012 X4 _/ s( Y2 {# _0 k/ c
5Hydrogenation of Carbon-Carbon Double Bonds9 o: m# v. P( H0 a4 i: g: F
5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds
8 B" \ v- C3 |4 e* K( vJohn M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121% l" Y( [% ^' m2 L7 g
5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds2 O5 b" D- Z2 ~ l" D |
Ronald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1837 F# G; I+ ?- M( o' i2 t4 J# r
6 Reduction of Carbonyl and Imino Groups
" p; H) A& X! T4 g4 G# y8 E/ u8 P6.1 Hydrogenation of Carbonyl Groups E/ v& u( T+ D2 i" Y( c. `
T. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
6 F* D& K/ o, ^# @6.2 Hydrogenation of Imino Groups& c( Y9 U1 m. F% T! o7 j( W
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 247
% _: }( z8 l% ?) V0 ]7 b6.3 Hydrosilylation of Carbonyl and Imino Groups" O/ _+ @/ }& R. d5 j7 D6 n7 ~
Hisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267
5 F2 z1 r# M+ H( u8 L! n9 p6.4 Hydroboration of Carbonyl Groups
) q. u5 B# ]' MShinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289
" W. E. a( w, _7 Hydrosilylation of Carbon-Carbon Double Bonds2 v2 G) ^# R4 P3 }. H. z( y
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319: D( Z- w$ M; d8 A4 t3 p
8 Hydroalumination of Carbon-Carbon Double Bonds
8 N# o- R% Z* V1 qMark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 337, o& p# H# l1 x- F
9 Hydroboration of Carbon-Carbon Double Bonds
& [$ |; p+ c# r0 n" HTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351
7 z9 \6 C" J( ?$ P" O10 Hydrocyanation of Carbon-Carbon Double Bonds/ b ]/ q7 z% G! I& P9 s
T.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 367
: Q2 z' K$ M& U: X11 Hydrocarbonylation of Carbon-Carbon Double Bonds
/ K! }2 i' f3 o. |& ?, `' OKyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 381
+ _' R) V; H r: }12 Hydrovinylation of Carbon-Carbon Double Bonds
8 W Q5 y+ v5 R$ K {" B" N; `T.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4172 `) l+ I* w8 Q+ r
13 Carbometalation of Carbon-Carbon Double Bonds: M9 e1 u. U, X- v1 X0 i4 ^
Amir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 431
2 i6 v1 P1 l( `" v5 `0 [8 o14 Heck Reaction6 b" ]5 V- W7 G9 O
Masakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 457
- x5 D7 E3 N. X1 E/ \Volume II
+ V! u- f$ i% [/ ?15 Pauson-Khand Type Reactions
: I" k4 ?, e5 X. @% d( iStephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 491
9 z9 Y2 X. J4 X16 Cyclopropanation and C-H Insertion Reactions$ Y' d. i5 s. e2 N; `
16.1 Cyclopropanation and C-H Insertion with Cu% c6 v* k5 I2 j( c/ `6 x# g
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513; K0 A* O9 l+ m
16.2 Cyclopropanation and C-H Insertion with Rh Y9 U( }6 ^4 Z8 d, T* ?$ [
Kevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 539
' e3 a' J2 l4 F! _) Z16.3 Cyclopropanation and C-H Insertion with Metals 4 o7 d8 s7 a- U* V
Other Than Cu and Rh
( b' `' h B/ @( d- T# uAndré B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 581
& E6 s9 W5 a, L w1 t2 A17 Aziridination, |% F* ?. z/ r' }
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 607' a D. x% O7 p) o% \& z3 G
18 Epoxidation
9 C" X- t9 _) T- s5 U18.1 Epoxidation of Allylic Alcohols
+ d$ i9 ^& `, ?" aTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 621
9 f( L- `+ g- x7 Q$ w18.2 Epoxidation of Alkenes Other than Allylic Alcohols
6 r, C& G2 V- P( c( f4 w% t$ b3 fEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 649
) F+ o. |7 q) h18.3 Epoxide Formation of Enones and Aldehydes
4 U' k d; c* O$ D! t8 N" S" o u" XVarinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679' U: ?0 D1 R; H; n5 y' l7 E
19 Oxidation of Sulfides- I& ?( l: {6 q/ ^5 `4 C
Carsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 697
+ L* e( ?1 F9 _ }2 m6 z20 Dihydroxylation of Carbon-Carbon Double Bonds3 ~# s& w' Y. j
Istvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 713! W+ j! o. j& z7 j/ T
21 C-H Oxidation
4 V/ Q) H+ [/ H0 ]( M8 F XTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 791( u1 |+ h: P0 A! A5 ]. {
22 Baeyer-Villiger Reaction
3 F) _4 Y6 _& b8 mCarsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 803, E; q. h& q; H
23 Isomerization of Carbon-Carbon Double Bonds7 J& q( d- q- r4 _+ h
Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 813
) G. g# N1 V; U v" _7 V% ?" J( Y24 Allylic Substitution Reactions6 U2 w$ p$ ]" {) ]2 v! P3 _ I
Andreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 833
+ G3 b( t |% w$ O/ A9 t8 U1 [25Cross-Coupling Reactions! @8 P; }: t6 W9 Y
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 887" o; t4 v5 c1 h/ O1 ]# }. N
26 Alkylation of Carbonyl and Imino Groups! q2 Q0 t5 q5 Q& d% @. A+ H$ Z C
26.1 Alkylation of Carbonyl Groups
" W& B/ p ?7 `+ {& i$ |' OKenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 911! p) B& B6 E1 y! i
26.2 Alkylation of Imino Groups
$ p/ m/ d) ?: j9 n8 D9 d vScott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 923
0 R0 O' v+ m% W8 m1 C27 Allylation of Carbonyl Groups
8 w5 ~. }0 [ @: c# P% ]Akira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 965
# p* b8 D: o+ J28 Cyanation of Carbonyl and Imino Groups+ O2 Q$ D; ~' C
Atsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 983
^* p+ G& p/ X# t7 Q- j. Y+ Q# UVolume III
4 w+ L G% }1 }, s/ b2 p3 z29 Aldol Reactions
$ s4 b& j/ ^7 k4 S, d: f- c29.1 Mukaiyama Aldol Reaction1 m+ t$ G) N4 ^* K: F1 `4 H, G3 s
Erick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997
" d* U* N7 L6 S( M29.2 Addition of Isocyanocarboxylates to Aldehydes
3 w6 y g# s% b" z) u) CRyoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 1067
0 O3 `/ L& _: \: P/ v! C9 ~' k29.3 Nitroaldol Reaction
7 Y: E0 l' {$ ]5 }Masakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 10757 F" J6 q6 p+ N7 Q! F
30 Addition of Acyl Carbanion Equivalents to * I3 J9 U0 d8 {
Carbonyl Groups and Enones4 P' m( d, e/ H: H% a
Dieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093
' b5 D4 |8 y% I7 B% l& l* U! B3 x. g31 Conjugate Addition Reactions+ m1 Q" I7 Q7 s$ M) J
31.1 Conjugate Addition of Organometallic Reagents
! Z; O7 n/ |6 J5 jKiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 1105
% ^4 S" |: t/ q31.2 Conjugate Addition of Stabilized Carbanions
; v4 v- j8 P3 DMasahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121
# i' ]' M( F v! ]% n7 W. D# A: G32 Ene-Type Reactions$ [. C) j8 O6 l& e1 A
Koichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 1143$ F2 z9 h2 j7 m) q5 ~
33 Cycloaddition Reactions
* l) ^* N6 T0 u, g) y33.1 Diels-Alder Reactions
2 I5 F! B j" x7 G" t4 |0 gDavid A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 1177
4 _; r+ q$ t6 N+ e& T! i8 Z1 |33.2 Hetero-Diels-Alder and Related Reactions5 ~' _ C9 U% I, i) b
Takashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237
( E* z2 p; L, [5 H8 p9 w33.3 [2+2] Cycloaddition Reactions . d' G: \# m$ i4 i
Yujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 1255* w2 N, M, |) y7 u/ W! H
34 Additions to Enolates/ j( g" n1 ]$ @1 ~7 r' j
34.1 Alkylation of Enolates& e! s! R, {$ H" g. B3 Q/ m: l* ?
David L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1273
. C1 Y% D Z; h* ~34.2 Protonation of Enolates; v: U3 m7 u' |, _) t" M* w2 N- {
Akira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 1295
- i% e/ `2 a) S" D9 c) G6 ?) x( N35Ring Opening of Epoxides and Related Reactions0 F+ \+ l0 N; A& y+ O& ^! s- F
Eric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 1309: C* X0 j, b5 P
36 Polymerization Reactions- U- P" S! P" c- B [# K3 w' {
Geoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1329
5 {3 m3 H: O# L6 _( c$ H37 Heterogeneous Catalysis
1 T: I5 m7 U/ c+ B# w( ^, nHans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 1353
) m' _% o: T6 X& n38 Catalyst Immobilization
. Z5 \ y7 A$ `# j5 l; w! h38.1 Catalyst Immobilization: Solid Supports
( Q- `% w! y, cBeno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 13674 o8 A0 M) A5 c4 @/ j
38.2 Catalyst Immobilization: Two-Phase Systems
* Y+ p% n0 X1 G# RGünther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377
4 P6 l% m# r1 Y f- V39 Combinatorial Approaches; g# q6 A3 W& S2 h- j# V/ c
Ken D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 1389
) ~. o1 L/ I' u e40 Catalytic Antibodies: G7 c" [2 ^9 _; }, n6 `: @2 e
Paul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 1403
' a" c u7 f- p4 @41 Industrial Applications1 @. R9 V8 X6 U, E
41.1 The Chiral Switch of Metolachlor
" z% ?& i/ K. G/ ]8 KHans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 1427
6 O2 Y; j* p6 y( u41.2 Process R&D of Pharmaceuticals, Vitamins, 1 t/ C! u, [9 y* y! [& D
and Fine Chemicals
" V: n2 F. w/ ?7 }Rudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 1439
' h/ i) _- B, c. I4 x1 ]$ ~9 R41.3 Cyclopropanation" y3 J5 c* o" ]. y' y; K
Tadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1451; E$ J N, x. B8 j9 U g
41.4 Asymmetric Isomerization of Olefins
, O9 R8 |* x' H7 v. X) JSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1461% ^, a3 r5 d! W, @ ` f! e5 D
42 Future Perspectives in Asymmetric Catalysis5 D0 }! ~7 a& e/ o
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1473
7 A# g# L4 r6 ?+ Y- J* L+ ZSubject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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