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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。
* v) [' l5 m6 `& t4 O7 K) a$ t1 X; O$ @4 R; e; [
Volume I
. C/ ~/ v" V3 P1 Introduction& L U& K4 N: R" k
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3. j5 ~0 g( B& i- d' k
2 Historical Perspective
3 c+ G& }# ]6 P O& n) f) xHenri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9- ?7 h! V1 W, K0 O, r$ \
3 Basic Principles of Asymmetric Synthesis8 O7 I4 q y: g* w0 ?/ j' m/ J! f
Johann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33( z; k3 B# u0 w
4 General Aspects of Asymmetric Catalysis
7 z: T6 B4 J7 E2 H. a4.1 Non-Linear Effects and Autocatalysis$ i6 i4 t/ ]* R1 S# [5 L4 S# _
Henri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 1012 R* z, C, J. l8 k8 \
5Hydrogenation of Carbon-Carbon Double Bonds
; B9 f1 u' g/ {% E& ? x! Z) {5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds2 \8 x& j/ ?# \; L- { h6 _5 ?8 c& M
John M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121
v* u6 ?' f5 ]7 I8 [5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds# a/ j; M) n* h: z
Ronald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183
; k' ] n( c( @8 P2 m8 ?8 J. g6 Reduction of Carbonyl and Imino Groups
" {# r6 ] q2 K7 r: U* a; u( M6.1 Hydrogenation of Carbonyl Groups3 _- J/ G0 T* [1 g, D
T. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 199/ z4 T% H2 g! H3 H
6.2 Hydrogenation of Imino Groups
& y. }3 n6 D& _ b: k& GHans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 247
7 l6 d; Z: Q* a5 h# ^7 q3 ]* k# g6.3 Hydrosilylation of Carbonyl and Imino Groups! C+ S) H1 |; o1 K( h3 E0 V2 d
Hisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2671 Z1 \% ~& `" O" b* u' F
6.4 Hydroboration of Carbonyl Groups) y4 O9 U* Y9 H- B
Shinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289
X" `2 J, m' D9 G; J$ M* v7 Hydrosilylation of Carbon-Carbon Double Bonds9 s* Z9 ]% f' } d% Z
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319
6 t" S- T+ z' \2 U8 Hydroalumination of Carbon-Carbon Double Bonds: w1 L! `! B/ H
Mark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 3377 n9 u/ V0 ~: c' _2 s
9 Hydroboration of Carbon-Carbon Double Bonds1 I! d6 u5 N, U, m. V6 q
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3517 n2 r+ ~; D8 w) p2 r
10 Hydrocyanation of Carbon-Carbon Double Bonds( F' _: L# D3 ~8 a2 V
T.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 367
9 H" O+ x8 `( h& `2 [% M% B7 N1 ]11 Hydrocarbonylation of Carbon-Carbon Double Bonds
, p1 V. k7 T6 E5 G/ WKyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 381! g5 z; I) a% {8 }0 k. ^2 i
12 Hydrovinylation of Carbon-Carbon Double Bonds
1 I% @3 c$ O# mT.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 417
4 |% X, l2 [# N0 [0 ^1 h2 ^2 w13 Carbometalation of Carbon-Carbon Double Bonds' E* P3 U) q. e/ Y. l, t, h
Amir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 431
. L8 j j' q4 c$ i+ M14 Heck Reaction2 e: z- X1 N$ \. W1 Q- n1 Z; v& e, G
Masakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 457: a1 [5 k/ L$ f* q
Volume II0 S. b/ D' p% N# x* d
15 Pauson-Khand Type Reactions# J" U3 N+ h" L: Q7 g+ \
Stephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 491
7 v' U, u! \& Z S% G0 ~. i16 Cyclopropanation and C-H Insertion Reactions/ v# N% j; S# k6 z' x
16.1 Cyclopropanation and C-H Insertion with Cu3 o: O4 e" |8 c' C, ^, D8 [, {- @
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513( g" g& |2 y8 ]* H n) d
16.2 Cyclopropanation and C-H Insertion with Rh3 \. w+ Y" ? U v# W
Kevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 5397 A- w8 M+ ^) {) p5 O+ G
16.3 Cyclopropanation and C-H Insertion with Metals # [& H( S2 W0 R* i1 B
Other Than Cu and Rh
0 A5 A0 @ `. r# L5 w: j$ v7 g7 _André B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 581+ M5 O. P( Y g5 o( a1 g* X
17 Aziridination
$ ^. v( |) H3 N' d5 X8 w, k gEric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 607. d4 E4 G9 H: _& d5 X. ^$ y1 [
18 Epoxidation
8 y. ?5 U6 K; Y. d2 }+ d18.1 Epoxidation of Allylic Alcohols
2 Z4 l; i e/ w" ?. J# T4 w& e6 s2 \Tsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 621
( J$ [! P+ @) W' X" ]18.2 Epoxidation of Alkenes Other than Allylic Alcohols
& m' m- A0 ?) N3 _+ k; e. tEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 649 U/ s# B3 |( J8 Q$ q e
18.3 Epoxide Formation of Enones and Aldehydes : O8 \0 |3 U5 _! _2 y
Varinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679
+ E1 p( I$ Q5 ~# I( d19 Oxidation of Sulfides
, n& f* M6 ` c$ q8 SCarsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 697: ~: @" l3 f7 S9 a1 ^! F7 q
20 Dihydroxylation of Carbon-Carbon Double Bonds
4 K+ b% l+ q% E/ dIstvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 713- w8 R, k8 K2 r) `$ P9 G
21 C-H Oxidation
( i' f& g: N' F5 U; H. kTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 791
! c _8 A5 E# t22 Baeyer-Villiger Reaction- k# r& w0 ?# y
Carsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 803# G# _$ n; q, Q; F& F, o
23 Isomerization of Carbon-Carbon Double Bonds
5 H2 V) ]. n# c- rSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 813
( p+ X) ^* a* d24 Allylic Substitution Reactions
# I. P0 ^, Q1 T4 y0 @- o! iAndreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 833 k8 [% U& O1 J, G! p& D
25Cross-Coupling Reactions
* g9 z+ {. \. a2 N$ x$ X) J, S# TTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8875 `7 t9 Y/ ?0 R7 |; j- G/ r; Z
26 Alkylation of Carbonyl and Imino Groups
8 w/ ^7 W6 O: t! u( h26.1 Alkylation of Carbonyl Groups
$ {# z9 M& R' F, R7 F- fKenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 911
! B7 T7 p) k& ~; a26.2 Alkylation of Imino Groups' X# W$ |* P: J0 j
Scott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 923
# H/ P$ ^4 q6 s3 V5 s- ^27 Allylation of Carbonyl Groups) R! e, T' E. \3 U9 s' A
Akira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 965& `. N5 [& q( Z% C0 E$ y
28 Cyanation of Carbonyl and Imino Groups, x" U6 e) u7 l( H! j
Atsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 983# D. Z e- E. V5 @2 W [8 D
Volume III2 ]3 U, D3 A# q8 R8 L+ B; E
29 Aldol Reactions
$ g; d8 w0 p* s0 u! _29.1 Mukaiyama Aldol Reaction
2 J; H9 Q1 p9 e( J4 F: ~Erick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997
: Y" _8 t E1 s2 L% J29.2 Addition of Isocyanocarboxylates to Aldehydes
/ a( \; i/ g+ }; URyoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 1067# n, ?( S1 F- `
29.3 Nitroaldol Reaction
, T3 U$ i' @ i) K- m3 E; {Masakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 1075
% x2 k* n* K$ S. c* l3 q30 Addition of Acyl Carbanion Equivalents to
@3 Q* R7 o6 \( s0 H: LCarbonyl Groups and Enones
& u& S% v6 Y/ r1 ~2 E. V9 _! KDieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093; ]- m7 }& w1 f* A `6 a5 X4 E7 n+ Z
31 Conjugate Addition Reactions% P# h: B8 y5 R. q: J/ s
31.1 Conjugate Addition of Organometallic Reagents& O9 ^$ J' j2 i) R- g- u/ N( Z
Kiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 1105- f8 E7 B5 f9 ?* G' |" e2 A7 e3 X
31.2 Conjugate Addition of Stabilized Carbanions; C) k" O* b) ~ d
Masahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121. P4 X. ?/ j0 c. N# h- }8 g6 G
32 Ene-Type Reactions/ U; L2 r# T. y G- ~
Koichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 1143- |4 O/ x7 G& {, S( c
33 Cycloaddition Reactions5 G5 _: f* M6 R) S% j
33.1 Diels-Alder Reactions/ f8 P& N3 t+ ?4 w
David A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 1177. |* l/ V. P! V e' {
33.2 Hetero-Diels-Alder and Related Reactions
8 N: ^ C% i4 _9 [( G; U- b+ WTakashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237( G" c# j, q% `& V8 |
33.3 [2+2] Cycloaddition Reactions
0 H7 W7 ?" ~' W, Y, L( g$ P* N0 `Yujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 1255
. @) J; M3 j" v; Q7 q. u34 Additions to Enolates4 s* `2 s+ N, q5 y
34.1 Alkylation of Enolates, R ~7 R" t P/ E/ j
David L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1273
3 D1 J4 E/ G! |# u4 H$ s; A34.2 Protonation of Enolates3 ?% B2 ~% Z. E* l6 K5 t7 M, H3 u1 Y
Akira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 12950 }8 f/ {8 Q* R6 P
35Ring Opening of Epoxides and Related Reactions9 F, c$ a+ ]; ^- g( U6 A6 d9 q& [
Eric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 1309
2 {% n: E+ j+ b p& x36 Polymerization Reactions4 h3 X6 R6 b, W, K2 D8 H2 W0 O" l! v
Geoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1329
( b/ E3 p. W9 [% a4 x' j) C* p* P8 I37 Heterogeneous Catalysis$ V5 X$ M$ y8 \5 y* `0 N
Hans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 13535 q7 _5 O4 l' T: k+ U, n, j0 z) S% M
38 Catalyst Immobilization8 A# ^) J1 p& M9 ^( f ^& \5 [
38.1 Catalyst Immobilization: Solid Supports9 d# h9 \* ?2 C a2 X
Beno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 1367) f7 X" c& N, x( A- p& e
38.2 Catalyst Immobilization: Two-Phase Systems7 |& R! d* ? [9 O* i3 x; u3 k4 x
Günther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377
& a" G2 T. P3 Y6 I1 ?39 Combinatorial Approaches
5 F% N0 z/ G% N( `2 F3 M7 zKen D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 13892 a+ X$ o7 b7 O- n4 w) D
40 Catalytic Antibodies
0 x0 b2 |7 _1 {' H8 _8 JPaul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 14034 @5 F% I$ k# o' r) P
41 Industrial Applications
6 f' P! c1 P! I# i: Z N41.1 The Chiral Switch of Metolachlor+ v- f: K j; {& D
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 1427# K% a$ I3 {; m x
41.2 Process R&D of Pharmaceuticals, Vitamins,
2 p) W1 K' q/ f' A# ]and Fine Chemicals
) m4 |/ O' o% l0 BRudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 1439; {8 g! y% k$ j u% Q" v
41.3 Cyclopropanation2 @$ D( C, T* m5 A0 A. a7 Z
Tadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1451
! m1 g9 @# ?2 d0 \41.4 Asymmetric Isomerization of Olefins
& x, U- K5 p2 m) E' |0 sSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1461( C# c3 m* F8 b( _; i$ \/ ]1 c
42 Future Perspectives in Asymmetric Catalysis
' a0 r. `5 d; T& s+ u3 hEric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1473. T: R) Q7 t. _, Y7 d- h! _% l7 F& |
Subject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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