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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。
, N$ O$ }, ^/ M6 g- n T8 F5 d! m# y# n! m5 c5 K# g7 {8 l8 v" N
Volume I
5 w! z1 |3 v6 [% K1 Introduction
0 @/ |3 T; B9 X+ y1 L- JAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
& U' ]$ k o% X7 G' s9 Q5 D! c2 Historical Perspective
3 z# [/ a/ f8 K z$ AHenri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 W' V& d, h. u
3 Basic Principles of Asymmetric Synthesis
7 l3 X! o2 I; r# @! o7 jJohann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
3 t5 M) S4 x E4 General Aspects of Asymmetric Catalysis
9 B$ }( Z$ A# O4 j8 g" |4.1 Non-Linear Effects and Autocatalysis% ?# u0 E2 k% q" g
Henri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 101
1 U6 G9 ], j' s6 N: j/ v5Hydrogenation of Carbon-Carbon Double Bonds, w4 C5 t4 s) s( y6 f
5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds7 Q$ i5 X$ N& T! b; _5 \3 {3 M" ^
John M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1216 k5 o2 Y0 m% n+ r& j
5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds- l. M! Z0 `8 T9 O8 j4 t; }
Ronald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183( R. a; x* q% }$ m1 T7 R
6 Reduction of Carbonyl and Imino Groups' Q7 v- ~1 ]- _; \
6.1 Hydrogenation of Carbonyl Groups# [" J# F! ~+ N. A/ `8 D
T. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
: t* Z# W7 R: ]. n9 {. d" K4 `# R6.2 Hydrogenation of Imino Groups
/ J% u* W2 r p7 ]& a! t: X1 Q; BHans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 247 y+ a; ~! d I9 x1 C5 S
6.3 Hydrosilylation of Carbonyl and Imino Groups5 i7 @1 l% D9 r% b: O% I
Hisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2673 R6 G( }! w; n/ O) t h2 m& t
6.4 Hydroboration of Carbonyl Groups/ Q: M' I E. c" w
Shinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289 [, o- r1 |8 S# `2 R- _2 e& M
7 Hydrosilylation of Carbon-Carbon Double Bonds* k4 j5 z# ]" }5 G6 V; m
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319, @. w, b' K' X# a* Y% M$ K
8 Hydroalumination of Carbon-Carbon Double Bonds
I) q! h, m( I% S2 N3 K& `% GMark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 337
. u+ j5 p# M* u) Y9 Hydroboration of Carbon-Carbon Double Bonds
' v$ C; U- ~4 GTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3511 m. ~% D# o7 h* R- R' P, X/ e0 V
10 Hydrocyanation of Carbon-Carbon Double Bonds
4 j$ f* V3 ~( tT.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 3677 b; e( b! ^% P+ Z
11 Hydrocarbonylation of Carbon-Carbon Double Bonds* \/ R% Q& z, C- Z. e: i& p0 e8 i
Kyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 381
2 ?- I; L, C" s; C$ p" i, \12 Hydrovinylation of Carbon-Carbon Double Bonds1 s. @& {" b7 k6 e. Q
T.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 417' N# {# F/ M. @( g% z. T
13 Carbometalation of Carbon-Carbon Double Bonds' y% s5 V5 ^2 O' h$ ]% A3 ^# x1 k
Amir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 431
: f/ o7 A# V0 H8 n2 t14 Heck Reaction: A0 e# K" v5 I7 T. s6 M
Masakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 457
, ^' Z& l( ]9 RVolume II! Z5 h7 I! ~/ E1 _: s# b' _, _
15 Pauson-Khand Type Reactions
1 j5 R. D# U1 P( S; ^" ?Stephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 491" A, E" g+ {' j; D
16 Cyclopropanation and C-H Insertion Reactions
; @* b* b9 h6 y- U: C# g16.1 Cyclopropanation and C-H Insertion with Cu
4 O( O& {* Q8 D* |% M: rAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513# Q# z+ j: S h3 X0 l, u b
16.2 Cyclopropanation and C-H Insertion with Rh
: s7 V; M% W3 K$ _Kevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 539. @1 M+ H# A7 y* A! U) a
16.3 Cyclopropanation and C-H Insertion with Metals
( H) Y G9 w- Y0 l$ vOther Than Cu and Rh
: a! n2 w! A" T: f) KAndré B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 581
7 M+ ~$ Y' [4 t2 D; ?3 y0 G: h- R17 Aziridination
- W0 K+ f# G2 y6 m, d: i, TEric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 607
, F; L0 T. U. Q18 Epoxidation
0 i- z& _8 L+ k- Y, D$ P5 o$ J1 E; B18.1 Epoxidation of Allylic Alcohols
# _, v6 f4 i9 @2 M+ r ~Tsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 621
- a+ ]4 w4 a0 u4 o" A8 z18.2 Epoxidation of Alkenes Other than Allylic Alcohols
& c2 z7 c% l% C2 g, ]; w7 ~+ IEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 649
/ H+ k/ V G/ d2 H7 V' ~0 H) r+ X18.3 Epoxide Formation of Enones and Aldehydes # {6 j- k% y# u7 M
Varinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679! i3 m+ X. }2 A$ h' i
19 Oxidation of Sulfides1 e. X8 p. G: F7 f- L2 @* O: ~& T( Q
Carsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 697# ^/ b9 \! ~: ^9 U# I; B
20 Dihydroxylation of Carbon-Carbon Double Bonds
4 { K4 {9 ~2 u: Q7 M5 c& b% RIstvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 713
( U3 k) F/ N* h4 X21 C-H Oxidation
" Z1 h7 n% _5 F! |1 KTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 791, @9 G* `' N/ z
22 Baeyer-Villiger Reaction9 f& _* P8 V6 d8 k: F
Carsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 803& @' ?2 u# t) P0 w
23 Isomerization of Carbon-Carbon Double Bonds
6 M0 X' Z, x! ?* x, ^Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8137 W# E m3 i$ V" q9 F
24 Allylic Substitution Reactions
1 [8 n7 i8 z6 K4 j7 s' YAndreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 833
$ }4 B, \8 z2 O9 T5 U, }25Cross-Coupling Reactions- Z/ F- e; B' B% T. P
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 887- [$ p8 t: t' x+ g2 Y" ?' ]
26 Alkylation of Carbonyl and Imino Groups
* c, P) U5 u0 `! H, V: O26.1 Alkylation of Carbonyl Groups7 q* Q6 T( U7 V! I
Kenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 911
8 v& ~- }/ Z& ]0 [26.2 Alkylation of Imino Groups
: ^, E* T3 t' B; z# B) E( bScott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 923
: ~* Q( T) b7 ~, j- p: z8 q/ E27 Allylation of Carbonyl Groups5 f; R8 q7 L0 q; t% l
Akira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 965
. c6 H8 X5 Y: W3 O/ I2 X28 Cyanation of Carbonyl and Imino Groups
8 _9 \: X0 z. ZAtsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 9834 n3 P! t3 h+ U0 v* ^8 X5 q
Volume III
5 A; o, h% `6 R29 Aldol Reactions
" e; c" f" `3 i5 a, [1 G/ C29.1 Mukaiyama Aldol Reaction3 [; C6 n4 i% ?; n: Y
Erick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997
, @$ N; b" r% z5 S3 U29.2 Addition of Isocyanocarboxylates to Aldehydes
( u! k! I- _# a$ F' J4 SRyoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 1067. A* v* O* Q" h$ \* \1 j, o
29.3 Nitroaldol Reaction
8 b" r2 _" w$ Z' gMasakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 10757 u4 Y& }* F" l6 H
30 Addition of Acyl Carbanion Equivalents to
+ S4 Q; j& M) u6 P% {& b; NCarbonyl Groups and Enones- g- H& ~7 h" ?2 R( Q+ E% S
Dieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093( ~2 I/ U+ ^8 Q2 I
31 Conjugate Addition Reactions1 v* C" G4 T& g' E9 g! j4 i
31.1 Conjugate Addition of Organometallic Reagents. }* Z: M7 ^ c, \3 u
Kiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 1105+ z. [, X4 d8 y
31.2 Conjugate Addition of Stabilized Carbanions
) W% c6 ~8 ^* jMasahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121& I) O# b* i/ k4 _/ i) S' ?; w5 Y) I: m$ D
32 Ene-Type Reactions# N `: q7 ` l
Koichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 1143
. e& [. t: r- k$ ]33 Cycloaddition Reactions! J( Q! r3 G& n* p. K( [3 S! d
33.1 Diels-Alder Reactions
: K5 P" _6 B* I7 NDavid A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 11773 G7 _) C$ x* `7 [5 q/ {
33.2 Hetero-Diels-Alder and Related Reactions1 i( @4 Y& z) v' \
Takashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237
2 M, k2 P0 C* h* z: z w S8 K33.3 [2+2] Cycloaddition Reactions
: x' l! ?0 t* x/ ?3 K7 c- AYujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 1255
4 N( q+ v- F" X34 Additions to Enolates
4 Z3 _: x3 {0 i' n, M' t% I34.1 Alkylation of Enolates
7 V8 K) }2 @7 {/ u- s( g, NDavid L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12734 S# Q# `2 J5 D
34.2 Protonation of Enolates$ Y+ a+ Z9 B% i3 ]8 Z# @
Akira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 1295
5 J! u! k4 R9 o* q- d" l35Ring Opening of Epoxides and Related Reactions
0 n, M+ _* o! y2 nEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 13094 }: o+ S# t4 F
36 Polymerization Reactions
. q4 u( N6 P# lGeoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1329
( d- ^3 g" y5 O% b6 u2 Q3 a9 [37 Heterogeneous Catalysis
9 s/ d/ h$ t2 y; y' ZHans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 1353, ]' Z; e- _; Q: w* i
38 Catalyst Immobilization; H% Y% E& a8 Q; G
38.1 Catalyst Immobilization: Solid Supports
: Q/ |; O5 Z5 e5 L' m+ uBeno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 1367
+ @* z- A; ]8 H9 M0 O( C38.2 Catalyst Immobilization: Two-Phase Systems
8 |9 ]! T q, p) |3 ]Günther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377" ^: ^, C6 V U0 I* L. H
39 Combinatorial Approaches1 }5 M9 d/ f1 |
Ken D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 1389
$ y4 P B9 D/ J! `$ Z3 ]( E) B40 Catalytic Antibodies
( n2 E( B2 v f$ o4 WPaul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 14038 _8 v+ r/ m2 ~& h% ^$ P
41 Industrial Applications( ^2 }, f8 `* k8 j) s
41.1 The Chiral Switch of Metolachlor# b- ?( k! _( }; a$ s7 g5 Y: m6 ]5 f
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 1427& F0 U/ n5 G( I9 E
41.2 Process R&D of Pharmaceuticals, Vitamins, $ b3 u O2 t4 L$ O9 \9 g) H
and Fine Chemicals5 f0 d2 ~6 k' S Y( I4 V5 a2 ]6 D f
Rudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 1439
5 p4 H' Y: F) [; I; }3 X% d41.3 Cyclopropanation
4 l8 U/ q% x5 k# wTadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14514 ]( m$ K6 g0 b1 R t( d! x* R
41.4 Asymmetric Isomerization of Olefins7 U, G8 O3 Q" s& ]) S
Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1461
- R! S+ a+ C! u4 \( \42 Future Perspectives in Asymmetric Catalysis+ F" ?" b$ v( Q" P) J! k
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1473' v/ ~6 H& T" J4 ?
Subject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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