|
|
马上注册，结识高手，享用更多资源，轻松玩转三维网社区。
您需要 登录 才可以下载或查看，没有帐号？注册
x
POLYMER SOLUTIONS（聚合物溶液）: h `; G- m: E- B' F
POLYMER SOLUTIONS( a2 f/ ]9 P5 ]/ g% _
, Q- n( E0 O- u1 n# X; B
An Introduction to Physical Properties3 R# }7 P9 T* p- s' M- ^
4 W0 t0 `- W' t; L0 b3 fIWAO TERAOKA& F5 o0 `- v2 |% W% V
Polytechnic University
/ k% N2 p0 n& B; P! dBrooklyn, New York
$ P' W4 T- ?0 u6 _
1 b d( S# O3 _: [& L' a# xDesignations used by companies to distinguish their products are often claimed as trademarks.
) @- q3 R" ^" _In all instances where John Wiley & Sons, Inc., is aware of a claim, the product names appear , P* E2 Q" z) O1 i1 X, m6 {
in initial capital or ALL CAPITAL LETTERS. Readers, however, should contact the appropriate companies
3 ?2 i! K( i4 P ufor more complete information regarding trademarks and registration.1 e, t( }9 p/ H+ W' @
Copyright © 2002 by John Wiley & Sons, Inc., New York. All rights reserved./ v; y3 [# Y* {- K6 ?* z- N6 Q
No part of this publication may be reproduced, stored in a retrieval system or transmitted in any . g9 A. Q. J+ Q6 l7 T7 ~! x5 J
form or by any means, electronic or mechanical, including uploading, downloading, printing,
0 z Z( V% ~4 T; \; d7 A& ?decompiling, recording or otherwise, except as permitted under Sections 107 or 108 of the 1976
7 b6 D' ~1 o8 P% C9 BUnited States Copyright Act, without the prior written permission of the Publisher. Requests to the/ o% N8 ^! d5 u" `" ^+ a
Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc.,9 o9 a; S Z7 ^. E
605 Third Avenue, New York, NY 10158-0012, (212) 850-6011, fax (212) 850-6008,5 k* p$ @! Z+ X/ I2 Q: z3 L
E-Mail: PERMREQ @ WILEY.COM.+ A, ]* `+ I. `4 x
This publication is designed to provide accurate and authoritative information in regard to the subject! C2 y& N9 i$ h2 {8 i2 }+ J3 \! Y
matter covered. It is sold with the understanding that the publisher is not engaged in rendering* p, K3 s N5 `. T% ~5 v
professional services. If professional advice or other expert assistance is required, the services of a
, C, n, j. C: ?* D; Kcompetent professional person should be sought.* Q# o$ j0 g# F J/ X0 p3 Z
' Y4 F! R& s8 ?7 w
ISBN 0-471-22451-0
1 E/ s/ l, @$ |+ H, g
, h+ T) J. Z) w5 ^ O1 GThis title is also available in print as ISBN 0-471-38929-3.: [2 D- L/ T H9 Q8 f
For more information about Wiley products, visit our web site at www.Wiley.com. : ]$ O2 E7 n4 G0 \. ?' Q
4 Y" K3 u, V' N# X
) j; z& E/ D0 \2 A& K$ g: v `PREFACE
! j f: B Z m( f) H7 S0 H& H) q( A. k. u; ]; L$ m0 \0 j
The purpose of this textbook is twofold. One is to familiarize senior undergraduate
$ @+ r; \8 C, A4 Y! M. vand entry-level graduate students in polymer science and chemistry programs with
+ X( X; I9 X) @: Y2 ~- B3 ]various concepts, theories, models, and experimental techniques for polymer solu-9 O8 E) U; }/ q# T
tions. The other is to serve as a reference material for academic and industrial' x- C/ s% i& w6 o
researchers working in the area of polymer solutions as well as those in charge of0 R) B0 U6 B9 Q. p) V
chromatographic characterization of polymers. Recent progress in instrumentation of
% ^+ l. y: ^1 q9 Q& lsize exclusion chromatography has paved the way for comprehensive one-stop char-
( _* o: a+ S2 c3 K, S( eacterization of polymer without the need for time-consuming fractionation. Size-
+ e/ g, f6 H9 wexclusion columns and on-line light scattering detectors are the key components in
) \% X1 w: V0 h1 Ithe instrumentation. The principles of size exclusion by small pores will be explained,: g5 u6 C' \- J2 R0 P
as will be principles of light-scattering measurement, both static and dynamic.
3 u' J! ?0 s$ Z2 S" A5 g7 R$ o2 s0 q7 A2 \
This textbook emphasizes fundamental concepts and was not rewritten as a re-4 f0 M* @8 L s Z9 ?
search monograph. The author has avoided still-controversial topics such as poly-
+ e+ S! F2 Y( f& w0 m4 ~electrolytes. Each section contains many problems with solutions, some offered to
8 d! d. g l: w# n" u7 D* X& `add topics not discussed in the main text but useful in real polymer solution systems.
5 A# o4 V. Y7 ~ eThe author is deeply indebted to pioneering works described in the famed text-
1 [5 v* S y$ R7 T5 w( O9 gbooks of de Gennes and Doi/Edwards as well as the graduate courses the author4 {5 p& N+ y8 i, P, @& z: A
took at the University of Tokyo. The author also would like to thank his advisors6 E7 ?8 I# Z5 p* a/ l5 V
and colleagues he has met since coming to the U.S. for their guidance.
5 ?4 C. W y* K; {This book uses three symbols to denote equality between two quantities A and B.
. d5 O. T) Z n( e1 A
" Q9 R7 O" f3 |( k" D2 m% Z1) ‘A B’ means A and B are exactly equal.- l, [( z+ a& c
2 {% A% S9 ~) f- d+ L1 ^; M
2) ‘A B’ means A is nearly equal to B. It is either that the numerical coefficient
% m4 B# r% Y! ^; Iis approximated or that A and B are equal except for the numerical coefficient.1 F9 R. g6 J: `4 v' O
; c. l5 B4 G. y5 {
3) ‘A B’ and ‘A B’ mean A is proportional to B. The dimension (unit) may
; q* G" Q, a1 E! S5 V f% O5 q
be different between A and B.
& L7 \9 t' r- d! ]* `8 h8 Z; n2 oAppendices for some mathematics formulas have been included at the end of the
$ e/ D) \) W# O$ l! Sbook. The middle two chapters have their own appendices. Equations in the book-
4 X) c6 s7 B. {9 D$ mend appendices are cited as Eq. Ax.y; equations in the chapter-end appendices are
5 L5 c8 `: z% J# S7 i/ Kcited as Eq. x.A.y; all the other equations are cited as Eq. x.y. Important equations
) q0 I) v; Z: }have been boxed. |
|
[复制链接]
发表于 2007-10-27 12:05:57
