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循环流化床烟气脱硫技术实验研究
& u; U# i4 m6 j u0 j3 H王爱军,祁海鹰,由长福,徐旭常5 [0 j3 G# }# a) t/ w
(清华大学煤的清洁燃烧技术国家重点实验室,北京100084)
) `3 n" \ h% x2 S( z) ^摘 要:提出一种干式烟气脱硫技术方案,并在400~800℃的温度下进行了实验研究。为了提高脱硫效率和脱硫2 ?* P/ H1 Y9 G0 H9 B
剂的利用率,还对在床内循环的脱硫剂进行了蒸汽处理。研究了烟气温度、Ca/S、床内气流速度、床内固体物料浓度) A- o1 R- [0 l [" e
等参数对脱硫效率的影响,以及各参数之间的关系。研究发现温度对脱硫效率有明显的影响,近600℃时最高。增, |, T% Q: J( L9 i
加Ca/S可以大幅度提高脱硫效率。此外,适当降低床内气体流速使床内的总物料量增加,可以提高脱硫效率。研究: Z- B l& {0 @6 L; p" [ s
表明,蒸汽处理对脱硫效率的提高有明显效果,在本实验条件下,处理后的脱硫效率提高42.1%。+ T' v$ k0 Q5 E5 Y* j. ` I; K7 P" y
关键词:循环流化床;烟气脱硫;蒸汽活化;脱硫效率" D0 A4 r$ V6 [
中图分类号:TQ534.9 文献标识码:A 文章编号:1006-8740(2000)04-0351-05
4 L3 _. p- [3 ]7 ^+ mExperimental Study of FGD Technology by CFB at 400~800℃: m8 K. [, p" n: |4 j
WANG Ai-jun, QI Hai-ying, YOU Chang-fu, XU Xu-chang0 |5 W- h \5 p+ k( ~# T
(The State Key Laboratory of Clean Combustion of Coal,Tsinghua University,. Y3 t$ ~2 c$ `' _, u7 e+ I
Beijing 100084,China)
) C5 m- l5 N5 }0 T/ e* G" QAbstract:A new type dry flue gas desulphurization proposal in a temperature range of 400~800℃has been; a: [3 d K( r7 O( j; J& ~) o$ E
introduced.The experiment was done at 400~800℃in a circulating fluidized bed (CFB) using lime as absorbent. m* y8 }% c* d3 T, w' C
and fly ash collected from power plants as bed materials. To make the absorbents more effective, the spent+ H+ u1 T$ C+ b' z! S5 E1 z5 u
absorbent was treated by steam in the circulating loop. The experiments showed that the influence of gas3 }* \1 p' [! B6 [% t
temperature on desulphurization efficiency was obvious, and perhaps there was an optimum desulphurization' R0 M: ^% f$ T+ d
efficiency near 600℃.As Ca/S was increased the desulphurization efficiency would be increased greatly.The Total# ^2 w) e" r7 m9 m0 v
amount of bed materials was increased as the gas velocity inside the bed was decreased,so the desulphurization
. O/ y0 [7 `+ k# H* X- p- R9 ~efficiency would be increased. The steam reactivation was an effective method for increasing the absorbent
2 F( _' ]/ s4 j9 S7 w5 L5 R1 i$ nutilization because the desulphurization efficiency was increased by 42.1% after the absorbent was treated by
; E' q4 v, |2 \steam.Therefore the dry flue gas desulphurization technology in a CFB added steam reactivation is worth of5 i( E4 @' N1 v
researching further.
* w7 g4 u5 e- BKeywords:CFB;flue gas desulphurization;steam reactivation;desulphurization efficiency |
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