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发表于 2009-4-24 09:33:08
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来自: 中国黑龙江佳木斯
修改后《Crystals and Crystal Structures》[PDF+书签] Tilley
《Crystals and Crystal Structures》[PDF+书签] Tilley
( x; U3 z8 u0 nContents
- M' z1 T0 M' K' v! z" l4 n6 |Preface
' M: Z7 `: Z( R9 R$ C+ |4 O: T1 Crystals and crystal structures
+ e# \; t/ g: J+ p7 G1.1 Crystal families and crystal systems; w, w$ m2 x! w9 H
1.2 Morphology and crystal classes
) W! X: g* ?3 B1 C% {' Y/ m1.3 The determination of crystal structures8 |2 \- [6 f/ @7 ?! G' X* E
1.4 The description of crystal structures
) v0 R3 b4 p3 m) A- g$ A1.5 The cubic close-packed (A1) structure of copper1 \; L% R% Z) f& n
1.6 The body-centred cubic (A2) structure of tungsten1 Q* w# B. x# v* j5 k* V
1.7 The hexagonal (A3) structure of magnesium
! y% F0 y- p6 W. W l0 X1.8 The halite structure
0 x+ G/ Q, F: J6 G1.9 The rutile structure
& M: b6 i: J; h; R0 X1.10 The fluorite structure2 I2 @- q3 I |2 K7 I0 q
1.11 The structure of urea
4 M- C8 g0 l9 _, E) E( v$ X1 o1.12 The density of a crystal
7 Q8 b9 p6 ?- ?$ ^( hAnswers to introductory questions* @. |6 {, b& w" t! w! j
Problems and exercises
: I+ s% {$ n9 j( _% b `2 Lattices, planes and directions
- w5 G \/ M' S4 F- s2.1 Two-dimensional lattices
* R/ L$ y4 a) O, [2.2 Unit cells0 z* @* y! }* g% r* r2 q* O
2.3 The reciprocal lattice in two dimensions; a$ |- f, ?% s2 t
2.4 Three-dimensional lattices3 F' _# e% E# V9 N8 @
2.5 Alternative unit cells
4 g; t4 z$ w4 |! J; X2.6 The reciprocal lattice in three dimensions. }4 V# q5 U! g
2.7 Lattice planes and Miller indices# X5 |9 [3 a3 L! C1 b7 `4 T
2.8 Hexagonal lattices and Miller-Bravais indices; O4 R* j3 g2 B
2.9 Miller indices and planes in crystals
$ A+ D" {+ f2 i& _: @' B2.10 Directions6 V: A" x: A. Y. \) m ?, B
2.11 Lattice geometry
4 M& T* a* y2 o: @) m4 bAnswers to introductory questions+ k0 O9 [1 ], ~) G: ^
Problems and exercises
2 C- ?6 g; w. f/ J3 Two-dimensional patterns and tiling
+ m0 @" o) P: J* [3.1 The symmetry of an isolated shape: point symmetry
# |, K, S7 z2 O) C$ |. L5 Y7 `8 x3.2 Rotation symmetry of a plane lattice/ `% g3 R9 d- m6 x' [
3.3 The symmetry of the plane lattices
! r) b/ ?3 j, ]/ S' {" B h3.4 The ten plane crystallographic point symmetry groups) W6 w6 g/ O1 U8 V1 w4 L$ r
3.5 The symmetry of patterns: the 17 plane groups
, \, f' J1 V5 V% f3.6 Two-dimensional ‘crystal structures’
# ]/ ^# I" u% K3.7 General and special positions0 K7 s4 S$ k6 F! z7 ^1 Z# ~5 K# H
3.8 Tesselations
& x: z5 p7 Q, x) t* T- d6 a' {9 K& ?9 UAnswers to introductory questions
/ M8 Q g1 j1 m. i, AProblems and exercises
: T' w1 ~# E" \+ f/ e* R: @% `4 Symmetry in three dimensions
+ V* ~# }* E2 S, |" R4.1 The symmetry of an object: point symmetry
/ }& C$ Q# N8 b. Q2 i7 r4 f$ L4.2 Axes of inversion: rotoinversion+ _ [; e1 t6 m. B+ f- \7 G B' a% g( J+ p
4.3 Axes of inversion: rotoreflection( h6 |- q& j3 G6 J+ x1 q" Z
4.4 The Hermann-Mauguin symbols for point groups
) @% `5 }5 I! |8 y, f# [) ^+ o+ K4.5 The symmetry of the Bravais lattices& R* s, O7 q- y) X" g0 M9 l; L- g
4.6 The crystallographic point groups
0 b7 |% o' F- L, y# m( H. {' J4.7 Point groups and physical properties
9 P; @9 u; `; q4.8 Dielectric properties
H+ B h8 q5 `/ ~2 A) s4.9 Refractive index
! E- ]6 J) K6 v* a; ~ z4.10 Optical activity6 S! b" t, ^: b( d4 `
4.11 Chiral molecules! ?/ b, H% ~; D+ k
4.12 Second harmonic generation1 K5 @' H1 l4 W+ y
4.13 Magnetic point groups and colour symmetry
- V9 Z9 V: m* }9 R# s/ qAnswers to introductory questions2 u+ C& U% D1 V' X6 _
Problems and exercises4 |% @1 m, F- H5 g, }' i2 t
5 Building crystal structures from lattices and space groups* M5 J; D: y# U% q% Q8 V0 i+ i. }
5.1 Symmetry of three-dimensional patterns: space groups
3 Q9 b% g+ H& t9 V6 G6 {* j, S( K- l5.2 The crystallographic space groups6 K% I7 X- _' B. ?/ l( {4 l& o
5.3 Space group symmetry symbols
# Q$ s s. J" M8 @3 V7 t1 A6 `5.4 The graphical representation of the space groups7 l+ k$ I, r t4 n
5.5 Building a structure from a space group& V. v" E7 U7 P% y8 p. ?3 g2 L W- ?
5.6 The structure of diopside, CaMgSi2O6- R2 V& a7 J, q. {4 W; C
5.7 The structure of alanine, C3H7NO2
, A* z3 D! w- ^2 k" b7 K% O; r7 ], B) EAnswers to introductory questions
1 B1 Z+ i; i! BProblems and exercises G- e! N4 ]& s( M: j* `
6
- Y+ W I* P' i' ^Diffraction and crystal structures
+ V. {3 X: R( w" s- b2 D6.1 The position of diffracted beams: Bragg’s law: ?) M) p9 `2 u, V! }- ]
6.2 The geometry of the diffraction pattern) U* n2 i( k. m% x+ d3 B
6.3 Particle size
5 L; C4 l' M4 w: @" Y) q, i6.4 The intensities of diffracted beams6 r+ J- V! E* k! y
6.5 The atomic scattering factor
! L2 u3 D, E- m& d) |6.6 The structure factor
- Q' f. w" K S9 {6.7 Structure factors and intensities
+ N s0 r" }1 }% k6.8 Numerical evaluation of structure factors
+ A* g, ^( i. w! Q! e4 T: ~- w6 \6.9 Symmetry and reflection intensities K& g, Y% y k5 @4 \
6.10 The temperature factor: d4 e4 ?& @2 K( V, _& Q5 @/ p
6.11 Powder X-ray diffraction0 s" U0 M/ [! A* P
6.12 Electron microscopy and structure images# F ^" G7 v, G3 r
6.13 Structure determination using X-ray diffraction- i* v7 P' ^7 O$ X" W
6.14 Neutron diffraction
6 ^4 O! k, ]- Y9 k- q% q3 B6.15 Protein crystallography5 l$ S, F- c' n
6.16 Solving the phase problem
" S Z1 r$ {; b6.17 Photonic crystals
8 U* b/ T5 E& G! r1 uAnswers to introductory questions
. Q: b, {0 O7 U* v7 J5 VProblems and exercises5 u$ h% E! g5 F. |
7 The depiction of crystal structures1 R4 @7 A, A8 O2 x1 A6 _! H$ |
7.1 The size of atoms
+ ?7 L/ d8 x$ k# y I1 g+ z7.2 Sphere packing
3 a0 @6 ~4 B7 k' y$ W$ S% h$ L7.3 Metallic radii+ p, w; u5 }) ^2 f8 Q4 K
7.4 Ionic radii" ?1 g& ~# h$ Q" F6 t6 f0 }# \
7.5 Covalent radii w2 v3 p* `! }& r# U7 t
7.6 Van der Waals radii+ V. X# H5 ?% b0 M; e* }3 Y- F
7.7 Ionic structures and structure building rules
7 P9 L5 T0 i* \0 T7.8 The bond valence model
/ D0 K$ u+ r, q% s8 N' k" D9 v+ @7.9 Structures in terms of non-metal (anion) packing4 R% |, G# g! s( V1 c" i9 w
7.10 Structures in terms of metal (cation) packing
1 T Q- s5 _# H1 ^: \- `. }& {7.11 Cation-centred polyhedral representations of crystals
1 S# S3 c; i; U, t7.12 Anion-centred polyhedral representations of crystals- A$ ~1 D7 g) `, S" |$ Y7 v
7.13 Structures as nets
. l/ z/ l& S& x& z, m: G8 b7.14 The depiction of organic structures
' b0 M! K5 D& u# ?2 J7.15 The representation of protein structures" s5 M4 ?+ r# \! s! B+ a
Answers to introductory questions
w' \, ^ @8 j6 U/ XProblems and exercises7 K. F1 V X3 E* K* i/ D- [
8 Defects, modulated structures and quasicrystals
) K* P2 S, Q& O1 a4 @% o; h8.1 Defects and occupancy factors
/ d* w9 d3 z8 _8 j8.2 Defects and unit cell parameters
$ T. q+ m7 H0 ?) _( X/ H8.3 Defects and density
W) @' f7 h4 Z& m7 X8.4 Modular structures0 B3 B0 r2 J. @) J9 g0 l; t5 g
8.5 Polytypes
' m5 h! w2 g; V( U8.6 Crystallographic shear phases
3 w% q- b, L! O$ P# Q8 e' }3 {! y8.7 Planar intergrowths and polysomes
& s- i E' P5 f0 K5 f$ @6 A2 r8.8 Incommensurately modulated structures
" I% v# Q" ?9 B( c8.9 Quasicrystals
3 e* s$ @! S7 T& K, O. @, vAnswers to introductory questions0 a" E$ }5 r9 [/ t1 s5 N* y
Problems and exercises
' `7 Z- n+ z' U' s% RAppendices; v- z4 V; D W5 v$ R
Appendix 1 Vector addition and subtraction
) w; `# w9 G, `Appendix 2 Data for some inorganic crystal structures* X8 ^) @1 _- i2 Z1 I/ U
Appendix 3 Schoenflies symbols+ [4 d E; @5 m! ^5 v
Appendix 4 The 230 space groups
. G" P, z) g# M/ N, nAppendix 5 Complex numbers
9 ~% d1 \ y$ ^: A, bAppendix 6 Complex amplitudes" V2 j1 ^% s2 \' O0 J9 B V
Answers to problems and exercises
1 a9 s3 k6 o. a2 vBibliography0 d( ^2 |1 ~! Z
Formula index5 J' j5 S5 M. {3 X8 ?( X. J
Subject index) s H- E2 n, P; }
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