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Green Chemistry and Catalysis绿色化学与催化剂 k- O% e9 N" J# {' L
Composition :K+V Fotosatz GmbH, Beerfelden
! E3 [( F3 H, O) I2 h2 cPrinting :betz-druck GmbH, Darmstadt9 R, c% ~' J; u6 S* f
Bookbinding: Litges & Dopf GmbH, Heppenheim4 m" E9 N o) Z- r: F
Cover Design :Schulz Grafik-Design, FuSgonheim7 ~- d! Y! q3 z6 l
Wiley Bicentennial Logo Richard J. Pacifico# C* K/ N% l G1 J" `4 n. Y) B
Printed :in the Federal Republic of Germany9 `! S! V" c* d6 A
ISBN 978-3-527-30715-9/ y: W, X: \, f! |% b
page:4450 k r5 c2 q3 s) p5 g3 N
The Author:Prof. Dr. Roger Sheldon
/ G* B- A3 t( a- W1 s- ~Each generation has its unique needs and aspirations. When Charles Wiley first0 j6 A) d; h+ o5 u5 g
opened his small printing shop in lower Manhattan in 1807, it was a generation4 R& g- H" j: ` k3 R0 O! H* h
of boundless potential searching for an identity. And we were there, helping to5 `# A* N. s, L w' ]
define a new American literary tradition. Over half a century later, in the midst. Y9 F, d- i5 G7 Z7 u S' b
of the Second Industrial Revolution, it was a generation focused on building
9 P ~" x, M% J* {. wthe future. Once again, we were there, supplying the critical scientific, technical,
1 X) A$ n9 u, b6 v9 g1 band engineering knowledge that helped frame the world. Throughout the 20th
- F# j& O# o" FCentury, and into the new millennium, nations began to reach out beyond their
* K5 @, ?& s! R3 [" v- k& qown borders and a new international community was born. Wiley was there, ex-
* x$ r3 v& A3 {/ C6 A) epanding its operations around the world to enable a global exchange of ideas, J6 ?, q% j3 O" C
opinions, and know-how.( | m w! k3 ]7 u
Contents- ]+ G3 A5 t6 N2 q0 J
Preface XI6 H8 Y2 \& O! {& O, J$ u
Foreword XIII
9 c$ X/ X+ L9 ~$ ]1 Introduction: Green Chemistry and Catalysis 11 a/ l9 V. {; `. |+ l
1.1 Introduction 18 K7 q7 m0 A# S6 A
1.2. E Factors and Atom Efficiency 2$ V# G0 R8 C* G [. i% K
1.3 The Role of Catalysis 5
3 ^7 M; J, X* O" k* K3 n8 k1.4 The Development of Organic Synthesis 8
; `2 B% S9 V2 W' _9 w0 ^# k( x1.5 Catalysis by Solid Acids and Bases 10' I6 x( W1 ^4 }7 `
1.6 Catalytic Reduction 146 x/ ~ _5 m& b
1.7 Catalytic Oxidation 18
! A5 E/ O* g# b1.8 Catalytic C–C Bond Formation 23
: t3 P; s3 V. o0 J; }: L1.9 The Question of Solvents: Alternative Reaction Media 273 x5 Y5 j; E2 V7 u Y1 u: q0 x
1.10 Biocatalysis 29
. a2 a t! w" g5 @1.11 Renewable Raw Materials and White Biotechnology 34
6 U% N* @6 x- x( Q+ I6 Q) P9 j1.12 Enantioselective Catalysis 354 i. A4 q3 d) ]4 L3 i
1.13 Risky Reagents 38) _: m3 v' c& P7 r$ [5 F- O
1.14 Process Integration and Catalytic Cascades 39
2 h% [* h5 T; p! G9 r" ]& MReferences 43. X* x- h% F& i( b G
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