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Green Chemistry and Catalysis绿色化学与催化剂
# ?9 Z5 I+ U( MComposition :K+V Fotosatz GmbH, Beerfelden4 U. j# P4 m: _
Printing :betz-druck GmbH, Darmstadt9 X* S2 T* T$ \$ v8 k
Bookbinding: Litges & Dopf GmbH, Heppenheim& P1 i2 q- s9 D% s. t
Cover Design :Schulz Grafik-Design, FuSgonheim' S4 l3 Q2 D9 E8 ?2 b+ w# v; @3 x
Wiley Bicentennial Logo Richard J. Pacifico! y; ] }5 ?% u* e# z5 x7 x
Printed :in the Federal Republic of Germany+ u2 x( w# M2 u
ISBN 978-3-527-30715-94 w! l- \5 J$ W" Y3 b/ J
page:445
- f2 n8 O& k: r& c3 I3 XThe Author:Prof. Dr. Roger Sheldon' o1 X* Q6 y. m, N+ p
Each generation has its unique needs and aspirations. When Charles Wiley first
( j, y- Z' u" j5 Z; Popened his small printing shop in lower Manhattan in 1807, it was a generation
- C* Y- Y0 X, B' Y1 h1 [. o1 U3 j$ i9 ^: Oof boundless potential searching for an identity. And we were there, helping to
4 K I3 i* G. H# x6 Cdefine a new American literary tradition. Over half a century later, in the midst
' I+ C" x; X, Xof the Second Industrial Revolution, it was a generation focused on building& \, E8 ]$ V8 J) a( q
the future. Once again, we were there, supplying the critical scientific, technical,8 s+ [+ b5 T- z* b, M, T# l
and engineering knowledge that helped frame the world. Throughout the 20th4 q+ m5 [+ O+ H: N* {! R* [' Y
Century, and into the new millennium, nations began to reach out beyond their l2 [5 v! X' X" f3 n& r* m" v- J A
own borders and a new international community was born. Wiley was there, ex-9 J, U0 y9 I; b8 C* `( u8 J
panding its operations around the world to enable a global exchange of ideas,& e$ X$ p. S+ Y2 u/ a' N
opinions, and know-how.
1 {$ P0 X+ b5 M) F, D2 I9 yContents& v+ | s; z3 ]' Y, R* a
Preface XI9 s) i# F" u1 E, _6 K0 l3 {
Foreword XIII
# s( ]5 |- o* W3 s1 Introduction: Green Chemistry and Catalysis 10 f! U- I& _% I# n
1.1 Introduction 1 ? E7 |5 y7 `( k, {- q6 r" W O
1.2. E Factors and Atom Efficiency 2
; Q5 q8 [* c+ ?, `5 f, f1.3 The Role of Catalysis 5
3 t% D3 f- n \6 ^. h( w+ O) d# v1.4 The Development of Organic Synthesis 8
" C# U0 s! b# S- D% U+ `1.5 Catalysis by Solid Acids and Bases 104 L, V0 y5 a9 @' o$ H
1.6 Catalytic Reduction 14$ f- G1 H3 L$ s( ^6 \$ ]. o
1.7 Catalytic Oxidation 18
) m. Y0 f* L. N2 l0 A5 A: A# {1.8 Catalytic C–C Bond Formation 23' B9 R& Y" f" Y# N
1.9 The Question of Solvents: Alternative Reaction Media 27" T+ W% S5 Z8 S# h! L9 Z. y0 F
1.10 Biocatalysis 29
- l4 c$ {2 D. V( m6 h* D1.11 Renewable Raw Materials and White Biotechnology 34; _* G! j. C( D0 s5 u$ U& ~
1.12 Enantioselective Catalysis 357 o8 u& ~! r# U
1.13 Risky Reagents 38
1 M, C8 n' y( i* p1.14 Process Integration and Catalytic Cascades 39
- M$ L, w" ^2 z6 HReferences 432 s; j7 y/ p/ E% R. j' Y
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