《高吸收核磁共振谱》英文PDF电子书

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书名An Introduction to the Analysis of Spin-Spin Splitting in High-Resolution Nuclear Magnetic Resonance
; L% ?2 d7 y% R/ A/ H8 x$ G6 d作者John ID. Roberts
7 `, Z. l7 i# N出版社W. A. Benjamin, Inc., New York
出版日期1961
  y. b: v) N  }- q- Q) b出版号 61-12990
  `5 N4 e! b2 h2 ~: h页数133
内容简介
2 O$ [% q. q& }# }( O: P' w1 Ylearn to apply the methods of wave mechanics in a prac-
tical way seems to involve a quantum-like transition with a
- j1 ^6 p: U) C( erelatively low transition probability. Chemistry students by
the thousands are exposed to the principles and jargon of
/ `' e5 W$ g# p' m/ H: m# gwave mechanics and are able to talk in a most knowing way
about orbitals, overlap, spin, etc. But very few of these stu-
8 F, u) q3 N$ x. S% O3 C$ rdents can set about to make any sort of an actual calculation
of resonance energies of  conjugated systems or the energy
" x- y4 M( e, h( x" Wlevels of nuclear spin systems, and this despite the fact that
the mathematics involved, although perhaps tedious, usu-
ally does not require more than college algebra.
目录
: p% d" l8 z3 \. o- M" [1 ?) G- S) t1. INTRODUCTION.  NUCLEAR  MAGNETIC RESONANCE ABSORPTION  1
1-1.  Nuclear magnetic resonance absorption, 2
1-2.  Chemical shifts, 4
1-3.  Spin-spin splitting-qualitative  theory, 7
2. QUANTUM MECHANICAL  TREATMENT  OF  SPIN-SPIN  25
INTERACTION  BETWEEN TWO  NUCLEI
- m/ d2 y2 T' B  N2-1.  Qualitative treatment of  the AX system, 25
2-2.  Qualitative and quantitative treatment of  the
, k; w6 r2 x! \- u& m  {A2 system, 30
$ z# A! {8 n* E2-3. Quantitative treatment of the AB system, 49
% P" h/ i3 y' @2 e. L3-1.  The AMX and AX2 systems, 63
3-2.  The AB2 system, 65
5 H+ t7 o' V3 v7 c7 f% P3-3.  The ABX system, 71
3-4. The ABC system, 85
2 b+ u# S9 p5 \4 D% `* ]. l4. A  FOUR-SPIN  SYSTEM.  A2X2  89
4-1.  The A2X2 system, 90
+ Y" [' ]/ q, ~5 ^8 QPrognosis  103
Name Index  107
# W) ?7 e/ d2 e6 m) Z9 N2 N- W& ]Subject Index  109

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