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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。
8 t5 `, z9 G' u2 ]- E% f
. N2 G& @5 ^9 X3 O, B& w- B! |Volume I/ K7 T- D! H6 x# D" `# o ]4 ~
1 Introduction
/ t2 D" U0 }9 r0 S, ]# a4 WAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 t( O/ ?+ _9 q+ l. O
2 Historical Perspective8 D0 x/ N# }$ E8 q' F3 y" c% c
Henri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
n; r3 o( Z1 r) E% k& @1 {3 Basic Principles of Asymmetric Synthesis
: J) {" ]% u+ L* j8 v& k6 Y2 }Johann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
/ g2 D- B M3 o: a4 General Aspects of Asymmetric Catalysis* }# G" m3 Q4 V; y
4.1 Non-Linear Effects and Autocatalysis6 S% n, z" e1 Q1 f. U2 Y% K0 Q
Henri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 101
* b( w& G% r0 X+ V+ H4 j5Hydrogenation of Carbon-Carbon Double Bonds7 \/ U8 o- t6 l6 }( ^: C3 y( [
5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds
, j- p' C1 Q; sJohn M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121; S. g6 ~% m1 n8 d
5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds9 `1 Y% Q5 V( u1 ?) l- e7 A
Ronald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183
9 X% D% [0 X: j: ^% S7 b6 Reduction of Carbonyl and Imino Groups" i; \. N$ _: v- x* m1 l; L7 A: D
6.1 Hydrogenation of Carbonyl Groups) q8 N4 d. H. }% W- o# w
T. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 1998 v. r$ S) Z8 T( M0 s
6.2 Hydrogenation of Imino Groups9 f5 q9 O4 x0 G* p
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 247
) ~/ ?; B" ~2 i4 u/ ^+ p6.3 Hydrosilylation of Carbonyl and Imino Groups. J4 G3 s& x `+ n A
Hisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267$ T' o! g. K* ^3 M6 \# U
6.4 Hydroboration of Carbonyl Groups
# | J1 i5 a3 Q2 \9 ~Shinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289
$ l6 N8 l. Q$ F8 I$ n7 c7 Hydrosilylation of Carbon-Carbon Double Bonds
- V( |0 @ T$ K8 q" m- {4 {0 ?$ b9 rTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3193 H+ e" P8 p6 L5 l! y" f% Q
8 Hydroalumination of Carbon-Carbon Double Bonds
5 u/ N; x% g% Z/ b* sMark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 337
% [* Y# R- ?: _: n& f9 Hydroboration of Carbon-Carbon Double Bonds
1 U2 j% H* }" N6 F0 g+ dTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351+ T; n, {( W# \' R1 C
10 Hydrocyanation of Carbon-Carbon Double Bonds
^6 m: \8 H; UT.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 367
. u7 N. t3 Z! h4 A; u9 L+ ~3 |" n11 Hydrocarbonylation of Carbon-Carbon Double Bonds: E) j, V! x- \5 r$ z- v Y
Kyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3812 p4 [/ B, J! z7 O
12 Hydrovinylation of Carbon-Carbon Double Bonds8 X, O3 b" b3 E+ I9 M
T.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 417( \+ S5 |. T' K* f2 X1 r: `
13 Carbometalation of Carbon-Carbon Double Bonds
2 r2 D: `: H& L I5 JAmir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 431
- v. R% f# H0 G, E! |14 Heck Reaction; B6 o a/ D+ C! l
Masakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 4570 G6 b3 E4 D, m7 l2 x, K
Volume II
/ n/ |; ]2 F# v1 W15 Pauson-Khand Type Reactions
4 B+ C( f. w0 ]: S0 @: sStephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 491
, K" T* E2 d6 p, R16 Cyclopropanation and C-H Insertion Reactions: [" i% D4 H: O; H1 U
16.1 Cyclopropanation and C-H Insertion with Cu
9 N, ]7 l7 y3 X2 P iAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513
( Q5 L4 f4 x' ?6 s9 `" Y" {16.2 Cyclopropanation and C-H Insertion with Rh
' t: X9 @) i5 }" e$ I* xKevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 539
3 i' m& ^( T2 N3 f! y" @16.3 Cyclopropanation and C-H Insertion with Metals
2 _; g% b2 h1 N# _ R: i0 xOther Than Cu and Rh7 } x: T J5 x- h
André B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 581
9 B" |; `8 `1 l) P2 K9 ]17 Aziridination, c7 f8 T! W, K9 o
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 607
8 d$ z) g" S n18 Epoxidation
: m' k) Y& d& m J- S18.1 Epoxidation of Allylic Alcohols
i9 N7 H3 W; fTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 621
0 R" H" @: @0 r- c* `& |8 ?4 N18.2 Epoxidation of Alkenes Other than Allylic Alcohols
/ x; Q; ]# ^, kEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 649/ M1 t8 r5 S8 ?0 h
18.3 Epoxide Formation of Enones and Aldehydes 0 P X s0 O+ ^$ i
Varinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679- P/ `2 c- ]- p4 B+ [2 R* B( i
19 Oxidation of Sulfides4 F% y' L* s: x" p
Carsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 697
7 a3 |6 X) {& i) M# ?20 Dihydroxylation of Carbon-Carbon Double Bonds
+ j6 P& n" |% v! }0 rIstvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 713
9 i4 ?- z# \8 c4 U, k5 `21 C-H Oxidation
, o7 X8 o# N. H# j* c; \Tsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 791
3 j$ A4 a9 L- n/ U9 ^22 Baeyer-Villiger Reaction
; ^: z" t5 p( u7 zCarsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 8031 C3 T9 T. {8 B: ^& j+ j
23 Isomerization of Carbon-Carbon Double Bonds" Z, Y1 Z& e: }/ u- X/ j
Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 813
" N# q6 x; c) F5 o, z24 Allylic Substitution Reactions
$ Y2 x1 T+ ^& I. }, g) Q9 vAndreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 833
; b, l1 V$ P! ^% y, P3 ?25Cross-Coupling Reactions- Y# ^+ O) X& a3 R2 g+ V
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 887 B' |: T' g/ A* L% J* G0 Z1 k
26 Alkylation of Carbonyl and Imino Groups. c- C, Q0 k# d4 {8 a5 M
26.1 Alkylation of Carbonyl Groups e" ]& L% ^3 U0 g0 \7 i! O& k
Kenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 911% s" a. F( p7 a3 Y
26.2 Alkylation of Imino Groups
* H/ {! \4 M! P" Y7 m! W! C% M: cScott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 923& K4 Y; e5 q& c* {% J$ D$ O
27 Allylation of Carbonyl Groups
( O' N ? H2 S( ^6 W) }Akira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 965* a. \! p; X- P1 v X( I# |
28 Cyanation of Carbonyl and Imino Groups( [& K. b- ^2 X" ?) Y; o
Atsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 9839 e, _- b, W. X( S8 N" \
Volume III$ _/ H# G& Y: m; o7 _
29 Aldol Reactions
f0 \9 V& F% g. m29.1 Mukaiyama Aldol Reaction
8 `* q% [8 W2 ?' w/ v5 ZErick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997/ O3 g3 Q8 m1 ^8 ?4 A* x ]' g9 e
29.2 Addition of Isocyanocarboxylates to Aldehydes
2 A+ g" Q! ^( t! k: Y/ ERyoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 1067
9 W2 A8 z- V; q9 n& a' F29.3 Nitroaldol Reaction
8 P) B8 H7 U4 W/ Y- u- KMasakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 10752 y8 R, E6 n2 ^$ _' M: q
30 Addition of Acyl Carbanion Equivalents to # z9 V1 h; {5 ~7 H$ u$ x
Carbonyl Groups and Enones
O1 K* y `, D* f# K' RDieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093* z1 g/ t6 D* V3 o+ K! p i8 o, ~/ x
31 Conjugate Addition Reactions
# B D: ^' [' L1 Y( W. T# B31.1 Conjugate Addition of Organometallic Reagents' a9 L" E* F9 m0 w
Kiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 1105% ^, T0 l1 t0 m. B
31.2 Conjugate Addition of Stabilized Carbanions
+ R- D# ]4 k: `Masahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121, z% S9 r# t. Y/ Z
32 Ene-Type Reactions
0 [7 B$ z0 G' JKoichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 1143
. p# P% D/ t7 F0 ]# A33 Cycloaddition Reactions, K K4 o4 M5 ?
33.1 Diels-Alder Reactions
3 t X" p2 F2 U$ T( ZDavid A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 1177/ o# j1 E% \( {) F( f2 n
33.2 Hetero-Diels-Alder and Related Reactions" S4 b" O. @( T
Takashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237
) a/ R+ S) T5 I33.3 [2+2] Cycloaddition Reactions
- ?! Q! S* D, I' u- gYujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 1255
( A0 M' O) R& y$ T' e+ n34 Additions to Enolates* o M4 K+ Z2 H$ F# O" K c
34.1 Alkylation of Enolates( j, I: }5 F3 M! n
David L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1273
# l b- t$ o; m" ?; ]34.2 Protonation of Enolates, E0 l+ r& D' S
Akira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 1295 p# e2 I8 Z" t" A
35Ring Opening of Epoxides and Related Reactions
1 F X" }5 d1 }% ]& \' T4 WEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 1309" @; v! s+ B) a6 ?+ K" _. _
36 Polymerization Reactions, E U; X6 X2 E" h, x. d3 f+ {5 R
Geoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13294 u/ F/ p! `2 ]# _" |2 R/ T6 o, v1 n
37 Heterogeneous Catalysis5 {9 O9 e$ _" Q& e
Hans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 1353
, a. G! O; v8 p2 Z8 v9 q38 Catalyst Immobilization
9 F( v6 g+ X2 X5 G% ?38.1 Catalyst Immobilization: Solid Supports
8 q* ]4 n6 r1 bBeno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 13673 ?5 X1 }0 @+ M7 X% h* [) [
38.2 Catalyst Immobilization: Two-Phase Systems
. h8 V2 Y0 J+ F, x% dGünther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377( a/ u0 d9 z# H m& [- U5 _' P
39 Combinatorial Approaches M/ m3 s w# u4 U: v
Ken D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 13897 A! I+ Z$ s5 \3 v7 {$ W
40 Catalytic Antibodies- O: e, ~7 {! m! Z2 @/ x, o5 I7 ]* w
Paul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 1403
6 t' A% X, O7 a3 j7 u' |+ G41 Industrial Applications
/ ?2 d+ n- `) p) l) d7 T7 {; G+ j41.1 The Chiral Switch of Metolachlor+ \$ B6 R: f/ I6 {+ ]
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 1427
+ {) \4 k% m/ c& A0 {0 ]& V' O41.2 Process R&D of Pharmaceuticals, Vitamins,
# m/ v+ `/ x6 g( ^7 zand Fine Chemicals' v( D% t/ x- I- @( L
Rudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 1439
1 I, |& Q- L) H [. e+ d0 N41.3 Cyclopropanation: }1 p! V! w% ~/ K" M% |( b- I! p
Tadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1451
8 }4 e M! S0 ~1 k V41.4 Asymmetric Isomerization of Olefins& D' N3 m, `" C' c. x
Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1461
9 r3 D% f; N& i% _42 Future Perspectives in Asymmetric Catalysis5 s0 a4 l4 e! X) {
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14736 U8 j9 n0 r4 a
Subject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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