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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。7 A, O$ s* r; e
! E" x- V0 j {$ [) J
Volume I
0 r# i: e( @8 x7 n& ]# T, u3 c1 Introduction; O& i' I1 _! c" x2 M8 ~. e
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3) n- a7 v0 `5 a/ M9 G' H9 C- R( g5 v
2 Historical Perspective, P! X+ `4 q4 U% V+ O0 q, f
Henri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9& `* ^# M$ o' ^ ~9 G& @
3 Basic Principles of Asymmetric Synthesis
6 P/ T$ _6 x& r7 v! LJohann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
$ |8 s6 Z( M% d' ~/ C4 General Aspects of Asymmetric Catalysis
- J# U g2 `- ]& i) P; \4.1 Non-Linear Effects and Autocatalysis% L5 `& i) l# U' B( A2 w" ~/ _+ F
Henri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 101
+ g$ @9 b) t+ L, m5Hydrogenation of Carbon-Carbon Double Bonds% \4 x. Y3 `7 P3 ?; N. h
5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds# I0 r6 ]7 _) s3 @2 o0 p9 J; n
John M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121
* Y' r( t; Q' O# d& c2 b5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds
# K8 _/ t/ H! O$ F! K# ARonald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1838 V3 x" y J ^, f8 D$ D# ~" H
6 Reduction of Carbonyl and Imino Groups6 J+ Y' W6 I- J7 k
6.1 Hydrogenation of Carbonyl Groups
' ]% y3 a# N# PT. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
' `! e; b& c: o9 s6.2 Hydrogenation of Imino Groups
) {7 ~1 _ W9 g' Q GHans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 247
$ t7 j8 v3 g4 _6 `6.3 Hydrosilylation of Carbonyl and Imino Groups
- B- S; V- _5 W+ HHisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267
d$ K- I8 `/ n1 f+ R# ]6 T6.4 Hydroboration of Carbonyl Groups+ f# O* r7 R4 f6 h$ I8 L \8 t$ x
Shinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289
4 |/ B/ N9 |+ b9 a( Y3 E* t7 Hydrosilylation of Carbon-Carbon Double Bonds1 ?" p7 V% @+ s/ N8 a7 G
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319
3 C! F9 t- w. j) \" u0 ]% W" S8 Hydroalumination of Carbon-Carbon Double Bonds m. A$ i. |2 {
Mark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 337
" x; t" ], [% X& _0 N+ X! {9 Hydroboration of Carbon-Carbon Double Bonds; d4 p' ]+ [2 C+ T6 p, }3 L
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351% v$ G# X- `% V7 r; r* j- Z" e! Y7 H
10 Hydrocyanation of Carbon-Carbon Double Bonds& ]% A1 I4 v z& P8 p( {
T.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 367/ o; j& a5 j# L8 L3 F! p6 @, w% x. ]
11 Hydrocarbonylation of Carbon-Carbon Double Bonds
& g, ^8 v/ j0 B# q" T3 p4 W$ J: ^Kyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3819 Y# z* j/ X( {9 b' z
12 Hydrovinylation of Carbon-Carbon Double Bonds
5 z! Y& s, h* t3 a( j7 s0 UT.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 417
& g S" t* a; U7 R4 h. M13 Carbometalation of Carbon-Carbon Double Bonds
9 i. P/ I) U' Z6 Y1 m1 C8 O8 nAmir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 431/ j$ v" K& I2 h8 }
14 Heck Reaction; `0 s9 I; s' k
Masakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 457
9 ?9 |; C1 i- N* _2 lVolume II
$ n! I7 E% `* L; F. G6 R3 d15 Pauson-Khand Type Reactions
1 e/ t7 a2 d0 |, L5 F* z3 f' W/ \Stephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 491
5 z4 Q! ?9 q+ [, Z3 i: K16 Cyclopropanation and C-H Insertion Reactions
7 j/ q3 h/ i; T16.1 Cyclopropanation and C-H Insertion with Cu6 k+ K; g- D% j/ w9 U
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513
! e" h- T3 N# `5 _16.2 Cyclopropanation and C-H Insertion with Rh
/ b$ M* [* t( @* NKevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 539
+ p& }2 @* k$ _$ i7 k7 s16.3 Cyclopropanation and C-H Insertion with Metals
. G" Q6 ?! K6 D7 ]2 W; D1 S7 \: EOther Than Cu and Rh: b7 x( L, \3 }! ]( V
André B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 581
9 U6 U3 G4 H" c17 Aziridination
( O2 e& Y: [8 Y5 u0 FEric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 607
1 Q5 o5 h6 t' G6 K) z6 L0 N0 {/ L18 Epoxidation3 w- ]/ D! a- o' { I4 b& c
18.1 Epoxidation of Allylic Alcohols. R) U' t( Q: n8 q, @* s% T0 C: B) @
Tsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6213 g4 {; x2 i& l, p3 z
18.2 Epoxidation of Alkenes Other than Allylic Alcohols! M# w! F5 j8 V" M
Eric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 649% o0 q2 h( E' E( Y# c$ I9 T1 Q
18.3 Epoxide Formation of Enones and Aldehydes
. M5 F" [1 `1 D8 W; r. c, e( F5 _5 OVarinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679
0 H A% n" p% J' L$ A) @19 Oxidation of Sulfides& z$ A! r8 _% M/ K
Carsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 697( P3 z3 g0 _" Q3 a+ a& @& X( v' k
20 Dihydroxylation of Carbon-Carbon Double Bonds9 }* v d2 D: x! I; c! v6 @
Istvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 7134 [7 Y" k$ I8 ~' i0 }; F
21 C-H Oxidation
7 b0 x# U, l/ C2 `! N w; HTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 791
E* i/ t* u" ]22 Baeyer-Villiger Reaction; v- P0 n3 j! K- a; {
Carsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 803
. y$ R6 V5 `2 ?' n- Z$ T& W9 d23 Isomerization of Carbon-Carbon Double Bonds
9 _8 f. L, w# u5 @Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 813- a5 W$ o- D8 v( ?- m5 q
24 Allylic Substitution Reactions
' G6 v* @& i7 }0 ~Andreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 833
" a* g* f2 q2 Y% \25Cross-Coupling Reactions
$ `% a3 Y/ ]& L. ~- t9 JTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 887
! B% V" h4 A* j' U8 `% _( e$ l26 Alkylation of Carbonyl and Imino Groups$ Z6 S! N1 T3 v* z; E
26.1 Alkylation of Carbonyl Groups
" k# R C, J" I* c2 _: ~, nKenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 911& r* f( P- B3 H
26.2 Alkylation of Imino Groups# J+ q! H2 B+ @1 f$ @' P3 e! j6 ^& D k: D
Scott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 923
; k1 s: ?& {& _, n$ q. i I3 O27 Allylation of Carbonyl Groups
' g* l4 w1 d( a' dAkira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 965
* X* C" _( f/ e4 i' I: V28 Cyanation of Carbonyl and Imino Groups# g7 K2 E. ~& k( M6 h, q, o
Atsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 983
2 c9 V8 J# |* U# {- G; fVolume III! P+ \, R2 E- x7 ?
29 Aldol Reactions# s4 J X% X& S( \2 n+ a
29.1 Mukaiyama Aldol Reaction' V: X+ |( t1 G/ _
Erick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997$ z0 F1 N9 B9 @3 Y$ x3 ?
29.2 Addition of Isocyanocarboxylates to Aldehydes1 k! R( a# K3 [$ w0 j/ N
Ryoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 10670 X7 |' ~' {$ i4 p+ q0 ]# g& l8 t
29.3 Nitroaldol Reaction& S& c9 U' c8 R7 N5 }
Masakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 1075, L4 p+ G8 l p d' b
30 Addition of Acyl Carbanion Equivalents to + H/ y# R& q1 o9 {, d8 N
Carbonyl Groups and Enones: ]% y0 F c/ V7 a3 E; t4 y) A# ^
Dieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093
$ b. @3 ?; v, [- D; h31 Conjugate Addition Reactions4 A, Q2 L& I3 k
31.1 Conjugate Addition of Organometallic Reagents" c `7 S7 h& A% q4 M
Kiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 1105% _& d8 n' o% l9 B8 J& k! o' f+ Q
31.2 Conjugate Addition of Stabilized Carbanions
# [7 n/ q& v: b* p: \+ ~Masahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121
; w, [8 H. P2 c+ F32 Ene-Type Reactions* B+ V2 T& m2 t; f3 t/ s& @
Koichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 1143
% B! `6 I; p" g1 f33 Cycloaddition Reactions
% c+ P, _/ v8 R: R33.1 Diels-Alder Reactions
! A8 n9 V' `. j+ XDavid A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 1177+ `! o- h) X: e, L! z* [
33.2 Hetero-Diels-Alder and Related Reactions
% N4 D$ {) A6 k/ b0 D) TTakashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237
( h3 w9 y6 o8 c ]5 }$ ?6 a33.3 [2+2] Cycloaddition Reactions
/ I, ^* N8 X' e% ~" v3 gYujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 1255" o6 L5 ~0 I3 r/ k8 Z
34 Additions to Enolates
, ?" j) g2 Z- _) t. P34.1 Alkylation of Enolates
! m; q- m% j+ Y: O5 zDavid L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1273
- a6 J$ b: B+ Z% [" d; R* u34.2 Protonation of Enolates
2 a0 S- V: m! ?5 w yAkira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 1295* Y v- q: k6 x
35Ring Opening of Epoxides and Related Reactions8 H1 |% @1 O2 Y. W& ~& T
Eric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 1309; T4 L- |1 @7 m4 a6 w, \: ]1 I
36 Polymerization Reactions$ U! r. q) o% g9 G" f7 {- |
Geoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1329
# w( r1 g! O9 I; r, V9 A37 Heterogeneous Catalysis
3 V4 W7 H5 i' I! p# J6 L) M+ g' Y, B1 pHans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 1353
) y9 @% B1 {4 Y" ?0 ?4 `& V2 P4 \9 D" k38 Catalyst Immobilization0 G6 \$ e$ H) A* Q. M
38.1 Catalyst Immobilization: Solid Supports8 _. Y7 } g' B2 D- e, s$ v
Beno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 1367
$ O$ G( L4 L" F; _6 N38.2 Catalyst Immobilization: Two-Phase Systems
& \6 L7 v+ e: P0 W+ i7 f$ oGünther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377
) Q4 F- z8 ^# \/ X7 y+ \39 Combinatorial Approaches
$ _$ @$ W |7 H& IKen D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 1389
! @3 ~4 i& p3 ?: H% I$ w40 Catalytic Antibodies9 E% Y) n8 O0 c# m1 T
Paul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 1403
- v, F2 ?* f" H. p: p7 E1 T7 p2 z41 Industrial Applications
y C" S% t7 E( q7 T) K41.1 The Chiral Switch of Metolachlor
) L. N( V% j$ b6 g/ m1 eHans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 1427: f3 p/ R7 A' u6 T
41.2 Process R&D of Pharmaceuticals, Vitamins, 1 R/ x! ~' s: L/ Z6 D- Q% t; m
and Fine Chemicals
. j) A: q( O' @. rRudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 1439
% _& h0 w; @0 X [0 a3 h41.3 Cyclopropanation
2 u+ g0 l- E% Y( S3 a2 eTadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1451
5 W+ W6 `7 n+ M41.4 Asymmetric Isomerization of Olefins8 d8 s+ Z7 T4 x3 G
Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1461
+ ?' n+ D2 t' i" t( h3 G% f3 D42 Future Perspectives in Asymmetric Catalysis
4 H8 R! F5 }9 G# W( c9 [) j* cEric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1473
7 {/ g( P: A! S4 ^+ `3 s0 `Subject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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