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[书籍] POLYMER SOLUTIONS(聚合物溶液)

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发表于 2007-10-27 12:05:57 | 显示全部楼层 |阅读模式 来自: 中国山东济宁

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POLYMER SOLUTIONS(聚合物溶液)
; t4 J1 J- N- k6 }" F% U* p2 OPOLYMER SOLUTIONS: w7 I2 M/ v- E3 F8 O
9 {' k# P' w8 v  I
An Introduction to Physical Properties
8 T! ]1 }! k, t
  S. W% W4 D" W3 m
IWAO TERAOKA
: w2 O. r3 l3 j- ]- z7 w; D0 b: tPolytechnic University& k1 U3 D+ P: o( ^
Brooklyn, New York

5 h' F) N6 ^7 B. I$ I
: p1 i. [& {  R! x" G: EDesignations used by companies to distinguish their products are often claimed as trademarks. ! |" E- s$ `# A% {0 a# l. Q6 l7 M
In all instances where John Wiley & Sons, Inc., is aware of a claim, the product names appear
4 h' y  u' P, _, ?: D! win initial capital or
ALL CAPITAL LETTERS. Readers, however, should contact the appropriate companies
! g8 _  r0 T/ O9 X7 w! E. r4 gfor more complete information regarding trademarks and registration.
) q- K; l8 q1 LCopyright © 2002 by John Wiley & Sons, Inc., New York. All rights reserved.
2 T. D" I8 M5 T; R9 M8 T; `No part of this publication may be reproduced, stored in a retrieval system or transmitted in any
; T, k, F' {+ s7 l' }1 }form or by any means, electronic or mechanical, including uploading, downloading, printing,6 X# U* u; U( Y2 Q
decompiling, recording or otherwise, except as permitted under Sections 107 or 108 of the 1976
( d  a6 ?/ z. g  `United States Copyright Act, without the prior written permission of the Publisher. Requests to the
  f: W3 A  e" w+ E* E1 W: OPublisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc.,' C* G; X/ o7 u1 b1 v3 ]
605 Third Avenue, New York, NY 10158-0012, (212) 850-6011, fax (212) 850-6008,# [; e1 f0 r! i- U# s) X7 n' y' C" ^
E-Mail: PERMREQ @ WILEY.COM.
7 k! Z) y, r* }* |2 @' o% a$ LThis publication is designed to provide accurate and authoritative information in regard to the subject4 _4 t  H5 P: J; J  a. t& l
matter covered. It is sold with the understanding that the publisher is not engaged in rendering7 z" }5 O9 g$ Y. d7 R
professional services. If professional advice or other expert assistance is required, the services of a/ y& b7 N* j- m
competent professional person should be sought.
1 z0 W9 y* U$ v0 U  a
4 L2 F( H9 i2 r* Y( q8 g, ~
ISBN 0-471-22451-06 l3 v- {* z8 h" o; }

0 ^2 w( |/ ?3 K" s! CThis title is also available in print as ISBN 0-471-38929-3.- v' D7 _8 U. [2 T
For more information about Wiley products, visit our web site at www.Wiley.com.
6 I, m; C8 E+ R, F% B

) R1 E3 }5 u  o: n
6 r  F1 }1 F% m* K. C8 kPREFACE7 f8 _) a; K& \3 `% t

3 M) C6 E0 m* W2 g: y1 dThe purpose of this textbook is twofold. One is to familiarize senior undergraduate0 _4 }- {' m. v3 u. j& y5 J
and entry-level graduate students in polymer science and chemistry programs with2 ^- Q& w$ v: {" r; J
various concepts, theories, models, and experimental techniques for polymer solu-
" Q- T9 ~9 y  X: z6 gtions. The other is to serve as a reference material for academic and industrial
+ T* `* Y  }; _5 i/ A4 C2 bresearchers working in the area of polymer solutions as well as those in charge of  P9 k% m: _& b4 O- @/ ^
chromatographic characterization of polymers. Recent progress in instrumentation of  X+ |% |6 _3 s8 r- y+ R
size exclusion chromatography has paved the way for comprehensive one-stop char-
" ^2 D. ~7 m, \0 K" r" D5 y2 C" H4 Eacterization of polymer without the need for time-consuming fractionation. Size-7 B/ ?5 P9 e% O, @) v9 y1 ?. w
exclusion columns and on-line light scattering detectors are the key components in
6 G5 P# V: V: Y, {: ithe instrumentation. The principles of size exclusion by small pores will be explained,; l$ A; ~% R; y1 m
as will be principles of light-scattering measurement, both static and dynamic.
3 Y& q/ U! Z1 h) g# M: j5 ?
. K1 S& H  s% i5 ]1 U
This textbook emphasizes fundamental concepts and was not rewritten as a re-: y7 d; X+ h5 W: X. W
search monograph. The author has avoided still-controversial topics such as poly-
0 Q; H2 n2 ~% G& zelectrolytes. Each section contains many problems with solutions, some offered to$ ^% j& p; o; }  M  q- R( U0 o
add topics not discussed in the main text but useful in real polymer solution systems.. w2 ]. _7 C! F( O! Z
The author is deeply indebted to pioneering works described in the famed text-  T9 m7 f1 v5 N3 s& [) l* m# C0 n
books of de Gennes and Doi/Edwards as well as the graduate courses the author! Y( g* O/ {; w% s# k
took at the University of Tokyo. The author also would like to thank his advisors
1 ^8 [5 \: t& aand colleagues he has met since coming to the U.S. for their guidance.
4 a$ S5 o/ t8 Z# m( p. u5 SThis book uses three symbols to denote equality between two quantities A and B.8 K* N7 y) m6 R/ v; d2 V: C
" y" {" k1 K2 s
1) ‘A  B means A and B are exactly equal.
0 _6 Z$ u& d) K8 b

: a* B" U% i3 {" }/ g' c2)A  B means A is nearly equal to B. It is either that the numerical coefficient4 \' \7 H/ i( K0 F- O/ {
is approximated or that A and B are equal except for the numerical coefficient.
: n+ u6 a( I: S! |# j

3 D! H8 M/ j, n8 Y5 w& M8 o3)A  B and A  B mean A is proportional to B. The dimension (unit) may1 f  c; A; m2 j( ~/ A0 @" Y
: F( T0 ^: {$ @) R% q
be different between A and B.
( O: }9 r' ]8 l' b' @1 fAppendices for some mathematics formulas have been included at the end of the
" R7 i' _& U, G( P+ u* l: d' Rbook. The middle two chapters have their own appendices. Equations in the book-9 ~* i' _. J. z
end appendices are cited as Eq. Ax.y; equations in the chapter-end appendices are1 Z5 g' A: `/ @! I3 j5 f
cited as Eq. x.A.y; all the other equations are cited as Eq. x.y. Important equations
) X( P9 D) p: t- R! t. r$ Jhave been boxed.

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发表于 2007-10-29 21:05:21 | 显示全部楼层 来自: LAN

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