《Ionic Liquids in Synthesis》[PDF+书签] Peter Wasserscheid

ztjy2008

《Ionic Liquids in Synthesis》共三个压缩包。
Ionic Liquids in Synthesis
Edited by Peter Wasserscheid and Tom Welton
Second, Completely Revised and Enlarged Edition Volume 1
% a, C; l: g3 @7 B8 y" jIntroduction
6 r8 ^% [- K% W8 R$ X  ZJohn S. Wilkes, Peter Wasserscheid, and Tom Welton Ionic liquids may be viewed as a new and remarkable class of solvents, or as a type of materials that has a long and useful history. In fact, ionic liquids are both, depending on your point of view. It is absolutely clear that whatever “ionic liquids” are, there has been an explosion of interest in them. Entries in Chemical Abstracts for the term “ionic liquids” were steady at about twenty per year through 1995, but grew to over 140 in the year 2000 and to more than 1500 in 2005. The reason for the increased interest is clearly due to the realization that these materials, formerly used for specialized electrochemical applications, may have greater utility as solvents for reactions and materials processing, as extraction media or as working fluids in mechanical applications, to name just a few of the more recent applications of ionic liquids.

Contents
6 e8 s1 [! \4 E% gPreface to the Second Edition xv
: B; T7 T& l, F; C6 IA Note from the Editors xix
Acknowledgements xix
List of Contributors xxi
1 Introduction
1 i7 j4 H. [9 @John S. Wilkes, Peter Wasserscheid, and Tom Welton
2 Synthesis and Purification
2.1 Synthesis of Ionic Liquids
& f5 g& I; C; W  u: ~* z0 HCharles M. Gordon and Mark J. Muldoon
( x; K1 v5 _3 `# J1 ~2 n2.1.1 Introduction
2.1.2 Quaternization Reactions
2.1.3 Anion-exchange Reactions
! X# d: w; ]9 Q! ^9 y8 m( p1 l2.1.3.1 Lewis Acid-based Ionic Liquids
1 h* l- b9 M! @. }$ C2.1.3.2 Anion Metathesis
9 l) c+ P6 S" z! v, P" d$ i7 g2.1.4 Purification of Ionic Liquids
5 z- @5 X# e3 X4 N$ t4 p4 j2.1.5 Improving the Sustainability of Ionic Liquids
2.1.6 Conclusions
2 b3 z6 M) p2 ^& _- A- r2 L9 P2.2 Quality Aspects and Other Questions Related to Commercial Ionic Liquid Production
Markus Wagner and Claus Hilgers
2.2.1 Introduction
, R# c. b- Q( K6 C2.2.2 Quality Aspects of Commercial Ionic Liquid Production
2.2.2.1 Color
; j+ O! Z# h1 {% g1 E/ ?2.2.2.2 Organic Starting Material and Other Volatiles
2.2.2.3 Halide Impurities
, W% V/ Y! l% T+ W& l1 A* ^2.2.2.4 Protic Impurities
, v' w$ F. J- T3 E( X) k、、、、、、
5 \8 ?4 N( Z% L+ D+ z9 Industrial Applications of Ionic Liquids
Matthias Maase
" m0 q% m7 g2 ~, `3 z8 V0 q+ `' L9.1 Ionic Liquids in Industrial Processes: Re-invention of the Wheel or True Innovation
9 {/ A1 I" C2 e1 @' M; g. V) m9.2 Possible Fields of Application
# M( D) O. h2 W& c4 c# k% w3 L9.3 Applications in Chemical Processes
9 X  V( R: N! C9.3.1 Acid Scavenging: The BASILTM Process
' \6 C% d9 l9 F# n2 I! ^/ ?) A9 e、、、、、、

' B1 {/ [# |6 |1 {1 d* x10 Outlook
Peter Wasserscheid and Tom Welton
8 x) R$ ?5 F, f/ N. Q8 J# {. IIndex 705