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Polyolefins: Processing, Structure Development, And Properties
2 v) Q8 K1 ]+ iBy James Lindsay White, David D. Choi ! x4 k2 u; |6 F3 `
Publisher: Hanser Gardner Publications
; U# V9 O& `$ SNumber Of Pages: 2713 I* X$ T- T+ c" p$ g5 m ~
Publication Date: 2004-09-30
+ i5 X; z" Z9 `, A }/ u* JISBN-10 / ASIN: 1569903697 ; @4 }$ {4 N/ H
ISBN-13 / EAN: 9781569903698
( u/ y5 J$ B/ R2 \2 B7 _Binding: Hardcover , W8 ~; D2 @" m' x
共4个压缩卷，解压后9.32M
* M) }+ M: j6 Z/ s# e( UBook Description:
4 O" A, A$ _; \. D' b2 `8 f s6 L" y y* N. E/ A- t1 ^* L( |* y$ g
This comprehensive volume brings you a resource covering the very latest technological developments for polyolefins. You'll benefit from the expertise of noted authorities and for the first time will find a comprehensive description of the structuring of molten polyolefins in fiber, film and molding processes with correlations between structural order such as crystalline unit cell, polymorphic effect and orientation, and processing parameters. 7 X' ]: e) g9 I4 \: L5 j5 E- @7 Y6 h
Written by leading experts, this book provides a truly authoritative resource for polyolefins. The book treats the history, commercialization, characterization, and crystallography of various commercial polyolefins and polystyrenes and describes development of structure during fabrication of these polymers into various shapes. 1 X: {) m1 w" J$ A
目录4 f! X. P0 b9 k; i7 I* X) w. ]
Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .V& H" M! w% ^/ _" ]" a
1 Origins of Polyolefins . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1/ t3 z6 Z" V' ~; j, O: F3 ]
1.1 Introduction and Prehistory . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
7 }3 P7 e& u& a& @& A o5 {! g, V1.2 Polyethylene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
3 [. B6 ^6 v7 `1.2.1 Low Density Polyethylene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
; Z: G* p4 a2 k2 n& A3 f, E7 e7 P* L1.2.2 Karl Ziegler and High Density Polyethylene . . . . . . . . . . . . . . . . . 32 c% B' @! G' y% d
1.2.3 Standard Oil of Indiana . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
) O) o; e, b$ a9 ~% E5 N1.2.4 Phillips Petroleum and High Density Polyethylene . . . . . . . . . . . 5
3 p2 Y) a; A3 Q# S1.2.5 Linear LowDensity Polyethylene . . . . . . . . . . . . . . . . . . . . . . . . . . 69 A' J% k( J1 k$ b( y) [* T
1.3 Isotactic Polypropylene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
* {/ y& z- I. v; p4 |7 T2 r$ `$ E1.3.1 Giulio Natta,Milan Politechnico and Montecatini . . . . . . . . . . . 71 v, a( n, d1 Y
1.3.2 Standard Oil of Indiana and Phillips Petroleum . . . . . . . . . . . . . 8: R; a1 Y) n- \/ K0 a, D% W
1.4 Isotactic Polybutene-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
" r/ R" K% p- {1 J4 Q1.5 Isotactic Polymers of Higher Olefins and Poly(4-Methyl Pentene-1) . . 10
9 ]. Q% r* _# K9 [. _1 _" M/ s1.6 Ethylene-Propylene Rubber . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115 i( B B1 c: Y+ I
1.7 Metallocene Polymerization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12- }. ^; w5 w( }$ O- P* ~
1.8 Stereoregular Polystyrenes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
1 b) B6 O" j0 s1 V& t. m1 B1.8.1 Isotactic Polystyrene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13/ O/ Y/ y# x! H! C
1.8.2 Syndiotactic Polystyrene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132 P$ j$ ^; o! N: U: z
1.9 Syndiotactic Polypropylene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14# h( j' ^; i# Y1 k2 ~
1.10 Cyclopolyolefins . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140 F3 }# F& j! C
1.11 New Metallocene Polyolefin Copolymers . . . . . . . . . . . . . . . . . . . . . . . . 16( f. C6 Q' t) ~. k
1.12 Current Production Levels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
; ^. ^1 Y) t% b" d2 {% [- p1.13 Bulk Polymer Properties and Chemical Stability . . . . . . . . . . . . . . . . . . 17+ Y3 g; c4 [. N. ?$ m0 P
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
* y/ \) r4 m/ y8 g* e2 Characterization Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
- q. U o+ p$ M* V2.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23: Y' r& E5 s- B
2.2 Asymmetric Carbon Atoms and Tacticity . . . . . . . . . . . . . . . . . . . . . . . . 23
% d6 k' f+ K. E- p8 x& e2 H2.2.1 Low Molecular Weight Compounds . . . . . . . . . . . . . . . . . . . . . . 23
: N7 x+ K' _ L8 R% u2.2.2 Polyolefins [5] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
( ]- i/ V1 ?: f9 z7 P0 v5 r, l* X2.2.3 Tacticity Levels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26) d* |6 J/ S8 y S' a
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