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Green Chemistry and Catalysis绿色化学与催化剂
& E1 k L9 I* q) ?Composition :K+V Fotosatz GmbH, Beerfelden; ]% h9 X( G$ V5 s, F
Printing :betz-druck GmbH, Darmstadt9 V+ d7 A9 B8 d, \( k+ a
Bookbinding: Litges & Dopf GmbH, Heppenheim) F6 v. |6 b9 ]
Cover Design :Schulz Grafik-Design, FuSgonheim, y, D+ p8 N5 ?% ?2 x# J, j
Wiley Bicentennial Logo Richard J. Pacifico
, t W4 x# ~1 V$ G0 uPrinted :in the Federal Republic of Germany7 R( A8 y7 b+ ?+ w/ p
ISBN 978-3-527-30715-9
+ L7 H; @- w" g- M1 i2 x/ n, Zpage:445
' V2 T2 B1 i) j' M$ r6 IThe Author:Prof. Dr. Roger Sheldon
$ T) e7 @$ [* H+ O: yEach generation has its unique needs and aspirations. When Charles Wiley first; v9 q4 ?! v, |6 J7 X" e
opened his small printing shop in lower Manhattan in 1807, it was a generation
6 F9 ?6 t {7 q( _: @: kof boundless potential searching for an identity. And we were there, helping to
7 p3 N2 w! M5 ndefine a new American literary tradition. Over half a century later, in the midst
# K5 F# Y0 m& u/ e9 i: rof the Second Industrial Revolution, it was a generation focused on building
/ U: v2 _# v, e/ wthe future. Once again, we were there, supplying the critical scientific, technical,
) K4 l" A" T4 C6 \" R3 \5 S! l2 Gand engineering knowledge that helped frame the world. Throughout the 20th
8 c+ k$ e5 o7 h& T* |7 sCentury, and into the new millennium, nations began to reach out beyond their+ b) G$ i3 J7 X
own borders and a new international community was born. Wiley was there, ex-. ~* z# J7 f( N X& D
panding its operations around the world to enable a global exchange of ideas,* `" R& z# c5 ]/ u5 {
opinions, and know-how., l1 T$ b: X& o
Contents
; j X, V+ c1 ?5 UPreface XI9 J$ l: o- K$ e: j( D
Foreword XIII
. f% E' \ \6 D" J+ D$ x1 Introduction: Green Chemistry and Catalysis 1
; g- n! r0 r1 C1.1 Introduction 1; s K8 i. N5 A
1.2. E Factors and Atom Efficiency 2% D# o/ B; }4 i Q2 s
1.3 The Role of Catalysis 52 M8 t/ b5 d$ B5 N% F/ v1 I
1.4 The Development of Organic Synthesis 89 S( ]$ R0 j' X- J# @+ C
1.5 Catalysis by Solid Acids and Bases 10
" `% J/ ^6 I# n5 ?% F1.6 Catalytic Reduction 142 w4 ~9 Y) w# X5 S: B3 P/ C
1.7 Catalytic Oxidation 18& T3 B5 ?) k" i3 y" {) [2 m1 w
1.8 Catalytic C–C Bond Formation 23
; W- _$ w: O7 A0 G1.9 The Question of Solvents: Alternative Reaction Media 273 `- W! {! A5 e) W' \
1.10 Biocatalysis 29
" \; o m @- D( G Q$ p& E1.11 Renewable Raw Materials and White Biotechnology 34% `% E0 s% a, c
1.12 Enantioselective Catalysis 352 A) |) O* s/ k" O% J& s8 H% M
1.13 Risky Reagents 38: \' n# o/ f. v C; e
1.14 Process Integration and Catalytic Cascades 39
* S' V" m* Q- @: g$ t8 F nReferences 43& X1 n! g9 g0 k% c; m0 }
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