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全书3个压缩卷,解压后5.67M) Q/ p, Z& i' P6 i( t
书名An Introduction to the Analysis of Spin-Spin Splitting in High-Resolution Nuclear Magnetic Resonance/ s( O+ h, x' b1 j
作者John ID. Roberts
e) ?' M# _% E2 G$ J& l4 t出版社W. A. Benjamin, Inc., New York7 }* N3 g( g! d. e! G! K
出版日期1961$ k. i/ \2 V; c& a
出版号 61-12990 4 T1 l( p* z, v" q" X D9 f
页数133
+ \; m& T: X7 e8 H- _内容简介, j! b W( O3 {! i/ L1 q
learn to apply the methods of wave mechanics in a prac-
, S# I# W& O4 y2 ?# Ftical way seems to involve a quantum-like transition with a
5 O# U' ^( ?0 u9 E7 N6 Y7 Jrelatively low transition probability. Chemistry students by
: p$ L( \7 g/ l8 @& q7 ?the thousands are exposed to the principles and jargon of
! H; _' b+ M4 {; K) ?3 ~wave mechanics and are able to talk in a most knowing way
: f* y. J, n5 r$ V4 i) Wabout orbitals, overlap, spin, etc. But very few of these stu- 7 Q5 I$ p8 D2 h7 H7 Q! p
dents can set about to make any sort of an actual calculation + P& r' j2 u Q9 i% G# P' @
of resonance energies of conjugated systems or the energy : f% t' H8 ~$ e* k/ Y j
levels of nuclear spin systems, and this despite the fact that
3 J' @' }5 }3 L3 p0 Vthe mathematics involved, although perhaps tedious, usu-
9 R4 K2 y/ r' U9 ^# N7 S2 @5 v8 Ially does not require more than college algebra. 2 i6 n. u, x% z6 U3 H
目录 7 l$ e; W( K' t1 }. _9 S- n5 _
1. INTRODUCTION. NUCLEAR MAGNETIC RESONANCE ABSORPTION 1 3 z; ^& M2 f# U+ z' }
1-1. Nuclear magnetic resonance absorption, 2 & G3 d' n6 c0 [8 g0 P, C# M
1-2. Chemical shifts, 4 ! W% m! N: C' m; i8 ^! o
1-3. Spin-spin splitting-qualitative theory, 7
% o1 @/ D4 z7 |2 E7 o% l2. QUANTUM MECHANICAL TREATMENT OF SPIN-SPIN 25 - x& ~5 a0 D! q, v& |( t; h' b; C
INTERACTION BETWEEN TWO NUCLEI " O! D1 |0 j. [2 k3 f3 B
2-1. Qualitative treatment of the AX system, 25
* p: B% h+ |$ Y* |2 p2-2. Qualitative and quantitative treatment of the
4 T- y \+ O6 NA2 system, 30
p5 @# D4 G t- d* e* b, B2-3. Quantitative treatment of the AB system, 49
! r/ ~. G% w+ h- j# t8 Z1 [' k* ]( I$ J3-1. The AMX and AX2 systems, 63 . [1 B) T `9 J+ z5 Q
3-2. The AB2 system, 65
1 ]- ^% t: b3 b3-3. The ABX system, 71 8 F8 B# y2 w2 c+ g1 C- t. |1 l
3-4. The ABC system, 85
9 h0 E% V% j! O9 t- J4. A FOUR-SPIN SYSTEM. A2X2 89 3 l* N: E2 A" f% i+ f ?/ U( {7 N
4-1. The A2X2 system, 90
' _3 ?1 ]$ D! ^- J {( OPrognosis 103
! N/ V9 v( x7 y1 M' y& VName Index 107
2 J# `2 R2 s: S, [: rSubject Index 109
9 R) e/ ~8 A4 c$ H8 y% z- }2 e& I
[ 本帖最后由 fenglianxiang 于 2008-6-26 16:59 编辑 ] |
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