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全书3个压缩卷,解压后5.67M
; K/ x, {% s& j/ Z" h2 X: J1 _/ ?书名An Introduction to the Analysis of Spin-Spin Splitting in High-Resolution Nuclear Magnetic Resonance, w) p; j. f' O! A
作者John ID. Roberts
- S/ y) w, j) w: m出版社W. A. Benjamin, Inc., New York
( m+ e. J" \+ b1 q" Y出版日期19611 K7 i; F) U6 ]9 X
出版号 61-12990 7 o5 x1 G2 K/ [0 @$ \% i
页数1336 S7 r3 d# ~6 [8 n1 F y
内容简介
9 A. |% U& V- Q& m' ?; t& \learn to apply the methods of wave mechanics in a prac- 4 t7 }: Z5 [; z# n& F6 L1 G
tical way seems to involve a quantum-like transition with a
- ]" O1 s+ _1 X3 y! _0 Qrelatively low transition probability. Chemistry students by
. s/ p$ Y! z4 r# ^5 mthe thousands are exposed to the principles and jargon of 1 _$ U- ]! E1 C# J6 X
wave mechanics and are able to talk in a most knowing way ! E7 j% A8 F! u. r7 B1 q
about orbitals, overlap, spin, etc. But very few of these stu- ( R8 ^6 H/ a5 }2 J3 ?3 Z
dents can set about to make any sort of an actual calculation ( C& ~% V' _% {, M, Y5 j
of resonance energies of conjugated systems or the energy
0 k9 u: [& C" g! g$ olevels of nuclear spin systems, and this despite the fact that
! P4 L2 \# H9 O1 Xthe mathematics involved, although perhaps tedious, usu-
( I" V. Z7 m* R0 F; f! a4 Ually does not require more than college algebra. + S. E5 j! d5 c. p! E+ T
目录 ) q7 j' w" |( ~ [5 x+ X, K& y
1. INTRODUCTION. NUCLEAR MAGNETIC RESONANCE ABSORPTION 1 : Z& E+ A1 F( |1 [7 `' a p! W! b9 V
1-1. Nuclear magnetic resonance absorption, 2
8 h$ A. E) C! U" M! d5 L1-2. Chemical shifts, 4
w2 b. a! \5 u# x5 I S7 I* M3 H1-3. Spin-spin splitting-qualitative theory, 7
% q3 S) X* f, V; o4 F2. QUANTUM MECHANICAL TREATMENT OF SPIN-SPIN 25
a) r, F2 P0 v( wINTERACTION BETWEEN TWO NUCLEI q& I/ v* S! M, F6 b* q. ?
2-1. Qualitative treatment of the AX system, 25 / f4 A D0 o, n: a! y7 j! z1 B
2-2. Qualitative and quantitative treatment of the
% W1 l7 k' ` @% z, a) | NA2 system, 30
8 \' h# g, a! k# R: W) p* P( _7 g& j2-3. Quantitative treatment of the AB system, 49
1 m8 B% a- i8 r# f8 Q/ {* M5 \6 h3-1. The AMX and AX2 systems, 63
/ o5 ~/ A+ Q' k; k3-2. The AB2 system, 65
& c) ^) t4 Q* b& x; ]3-3. The ABX system, 71
3 K3 i$ ]+ h! B/ Q6 o( k3-4. The ABC system, 85 $ o9 J0 j: E/ D, P2 k6 p7 K' n, ^
4. A FOUR-SPIN SYSTEM. A2X2 89 / L; ~ a7 A0 ?- c' Z6 `
4-1. The A2X2 system, 90 . t% r5 w: [, {, Y' y7 x: S1 E; X
Prognosis 103 : ^9 W2 _" E( ?* \& p& W
Name Index 107 ! S/ L& m0 ?) n8 Y4 s7 u
Subject Index 109 _- C3 I# z8 m9 `* `
8 g o* P, s, V( E[ 本帖最后由 fenglianxiang 于 2008-6-26 16:59 编辑 ] |
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