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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。
4 K; N! w; N% S$ @6 c0 H1 L) I
3 d( M+ I3 t3 o+ |+ ], B% r1 x; ?( NVolume I
; X h1 d0 _" r5 n$ Z+ V1 Introduction5 d- y( w: t& ?) C A
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
9 S4 s( G; T4 X' S5 n/ b0 m) P7 R2 Historical Perspective0 s- a3 c: c7 s* E, G
Henri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
, a5 P: @8 m g) h2 \5 g& {# p3 Basic Principles of Asymmetric Synthesis
6 j0 S% r$ n ?+ fJohann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
* s" B. F. L' w. M4 General Aspects of Asymmetric Catalysis7 h) s8 U" s2 i4 u1 O) X! q
4.1 Non-Linear Effects and Autocatalysis# P* v" u' M; b. j: y, `4 V$ D) K& h
Henri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 1011 E0 [9 Z9 x* j0 d/ b6 v: Q( D
5Hydrogenation of Carbon-Carbon Double Bonds3 c' Q$ }+ U! d; H; D# C2 L. ~7 U! b
5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds
2 R; v7 c: y# h* w8 m5 r# @John M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121# ~9 v% m7 w: W* L& `# i
5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds* ^* w0 S! C( ?4 S) M, ]5 H! V$ i) Z
Ronald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183
) z8 n8 D6 j2 ?; O6 Reduction of Carbonyl and Imino Groups# I1 s/ Y. N. ]- R5 T) d
6.1 Hydrogenation of Carbonyl Groups- Q3 w O+ T3 r e8 a: q1 h9 i/ j
T. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 1990 [0 k# Y* a t6 B7 i! w' B* F
6.2 Hydrogenation of Imino Groups
6 R$ f3 Q8 l/ K3 r" g ]0 QHans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 247! u: P) n# u7 y! V _1 f
6.3 Hydrosilylation of Carbonyl and Imino Groups1 v" z7 H j* y6 z! o8 u
Hisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267/ n- Y9 L3 J, |# Z
6.4 Hydroboration of Carbonyl Groups
6 N8 o- @8 I7 U7 R4 W3 {Shinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289
4 J" d5 A& s+ O* z' c/ D7 R7 Hydrosilylation of Carbon-Carbon Double Bonds
7 g1 `' Z2 i: U Y' JTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3197 R' t+ V7 ^2 o7 u
8 Hydroalumination of Carbon-Carbon Double Bonds
, Y5 {9 t' {0 F- a6 Y4 E6 AMark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 3378 z! a" K/ n0 ~ l3 E7 K0 b
9 Hydroboration of Carbon-Carbon Double Bonds- {9 N7 ?! W" p- L' i {8 P l4 n* V
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351
# @" Q( _) p5 F+ y8 W10 Hydrocyanation of Carbon-Carbon Double Bonds
2 t- G! v3 p' _& XT.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 367
1 F7 W" S* `8 z0 j- S11 Hydrocarbonylation of Carbon-Carbon Double Bonds
+ {' m# I7 U+ QKyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 381
. e& i2 Z' B: o ]3 ?" s- ]12 Hydrovinylation of Carbon-Carbon Double Bonds
( H7 ^; `9 P# W7 X+ sT.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 417/ a7 Z! P6 y0 T4 Y3 Y' k
13 Carbometalation of Carbon-Carbon Double Bonds2 a/ y4 T. ~$ L) c" g) ?+ A* k
Amir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 431+ I) U( i5 |1 E
14 Heck Reaction
0 y& F2 Q, z5 o. e2 hMasakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 4575 Y" W) M3 B. j( J) r
Volume II$ t* o3 i! r2 j
15 Pauson-Khand Type Reactions* W8 z8 [* ]9 r- n( z1 P
Stephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 4913 j! W4 @" R1 X* g- C7 I
16 Cyclopropanation and C-H Insertion Reactions3 b3 u1 i. b# o- j2 C
16.1 Cyclopropanation and C-H Insertion with Cu, W7 ?) E4 @( Y; a' d: Q; {8 _
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513
$ r8 X) c! s$ `0 L7 a. [16.2 Cyclopropanation and C-H Insertion with Rh
( E) S: T1 j- `, R( O" ZKevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 5392 g, \) M( `, R ^ G- U7 ?( @4 z4 \( ~
16.3 Cyclopropanation and C-H Insertion with Metals
@. E- Z" M" o9 @* ]: b! n6 {Other Than Cu and Rh: E( l; Z4 ?2 @7 _4 l! r- m2 B! b
André B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 5819 S7 p& X; S! Z
17 Aziridination
& k. P/ @- T( o0 z2 D$ vEric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6077 U1 ?4 |# ?/ m5 h) F3 ~. r
18 Epoxidation
6 G0 Y* |* T) g- q: R7 r18.1 Epoxidation of Allylic Alcohols
; a0 Z4 k1 w7 M* K' aTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 621
9 Z: Z/ \3 A, ?" }$ {- p" k18.2 Epoxidation of Alkenes Other than Allylic Alcohols
' L, \+ U3 M' x. C ?Eric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 649
- Q# q0 T$ I( v9 V18.3 Epoxide Formation of Enones and Aldehydes
q1 @9 F, g& uVarinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679 i% g6 v& e4 n, Y8 y3 j
19 Oxidation of Sulfides
7 i8 d" E6 y7 L/ UCarsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 6978 C0 `; F* g& n) }: `- R
20 Dihydroxylation of Carbon-Carbon Double Bonds
7 J' q8 }. }. ?9 G: S( i5 WIstvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 713
! x2 t( a. }; R( l# N- x* L; ?! R21 C-H Oxidation
+ s: p& A I: uTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 791+ f4 p! i, {! ]/ ]5 O
22 Baeyer-Villiger Reaction; D/ S. G9 I, ~: b3 w
Carsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 803) K( @8 j5 @/ v9 X/ ?
23 Isomerization of Carbon-Carbon Double Bonds
P: O; e! O( u j' [4 qSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 813
& D( @9 U8 H/ p# {3 K) G2 Y: P24 Allylic Substitution Reactions
6 j# u( @" y! C% }Andreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 833
- R( }: g# ~& M/ n25Cross-Coupling Reactions
2 M% V- ]3 h' W; Y4 rTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8874 {# ? r/ P. V. [' _+ i
26 Alkylation of Carbonyl and Imino Groups
) n6 O* P+ d" v" f& f; f" v26.1 Alkylation of Carbonyl Groups
# E, v/ ?* f l8 A8 DKenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 9118 R; h/ I0 ^6 _; }1 J, S
26.2 Alkylation of Imino Groups
8 ?& n( ~. @/ H: u( v; KScott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 923+ n/ h$ F" k: r, c, u7 s% ~
27 Allylation of Carbonyl Groups8 i" y W& I8 ~( z4 N
Akira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9658 C, j8 E) M: B7 E
28 Cyanation of Carbonyl and Imino Groups
% P; m7 X. y" U$ lAtsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 983
# Z8 S# z+ I1 [! g! ?Volume III/ W4 V& c2 ?0 b$ K: V! E; t( W; T
29 Aldol Reactions
! L5 ^1 K1 q; H; l* a. @* a29.1 Mukaiyama Aldol Reaction0 }9 e( o+ X6 }8 K/ A
Erick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997" r$ L/ X3 s; w& T1 ^
29.2 Addition of Isocyanocarboxylates to Aldehydes3 v7 n- `2 D" Z# w' J4 p
Ryoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 1067
" B! N5 \" e/ z29.3 Nitroaldol Reaction
, d( K4 f4 H4 ?9 }, R, KMasakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 10756 W& P) V2 G: N( e
30 Addition of Acyl Carbanion Equivalents to 2 x4 Q! P" Y# D, {' a9 C! v
Carbonyl Groups and Enones
$ a3 ]2 v5 i6 Z' N, f0 {Dieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093
$ q1 J9 s. y% @& I- F/ c, ^. C31 Conjugate Addition Reactions
8 w+ A' f3 O, g, R5 o1 k& C31.1 Conjugate Addition of Organometallic Reagents- A- t+ P5 _+ Q. k& s6 A; R
Kiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 1105
" V$ z; K! K) C' P' z31.2 Conjugate Addition of Stabilized Carbanions( A% V3 R- X# I8 h+ E: x' X9 o2 S
Masahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 11210 t( v0 ^# @7 m9 ]& n5 H( G2 W
32 Ene-Type Reactions( W0 Z) k" [9 e
Koichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 1143
` U% ^! p3 j' a- F P' R33 Cycloaddition Reactions
& n( y$ p5 f7 N2 @/ D33.1 Diels-Alder Reactions
& ?# b9 @& M* W6 l9 n1 M# CDavid A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 1177
' O9 V1 A& \$ N" N33.2 Hetero-Diels-Alder and Related Reactions
7 H4 P+ R2 F7 M/ h& S- @' GTakashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237
" S+ }# {2 v% E0 t7 \8 f3 E4 x33.3 [2+2] Cycloaddition Reactions
- Q2 {: @5 e! d8 G: ^; zYujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 1255) \& m' o4 ?6 l' c' v6 b& t" `
34 Additions to Enolates- @, e; u6 m. t( y3 y9 Z$ e
34.1 Alkylation of Enolates: h, G- g$ _ z W% r1 ^8 F
David L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1273" T4 }6 E& m/ b9 m
34.2 Protonation of Enolates m9 s7 C! C, U7 r$ T. o' O
Akira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 1295, j# r3 ^0 }4 \' a2 l6 l" ]% `
35Ring Opening of Epoxides and Related Reactions; J. y- b) f6 y' W* G& L; \3 q
Eric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 1309$ e$ E3 g5 z3 j; w
36 Polymerization Reactions7 [2 |4 n" w. ]3 U, K8 U
Geoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1329
( R2 a* s$ u1 K% }3 d$ h37 Heterogeneous Catalysis
* Y* x! N J/ U( b& v5 lHans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 1353
" x: T7 b- E1 Y$ {% g38 Catalyst Immobilization
6 q1 j5 g& y3 `& c4 }# ~38.1 Catalyst Immobilization: Solid Supports
1 L1 m7 |4 v7 S' R7 e9 @8 iBeno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 1367" J7 j% L5 t# W* ]: E) {
38.2 Catalyst Immobilization: Two-Phase Systems
( Z' p4 }& a% G. _7 q8 \6 nGünther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377
- E, C- i% Z& ~/ f0 } _) [% r39 Combinatorial Approaches
. e( u/ K6 y; l. H. P1 J4 }1 ?0 {! A; x0 ?Ken D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 1389
7 W- C) p U+ {4 P40 Catalytic Antibodies
! f, }! y; n& x* R7 Z* mPaul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 1403% c. Q) ^. w0 g4 d2 C7 ^
41 Industrial Applications! ?7 ~; [. p+ `3 J1 _: ]' G
41.1 The Chiral Switch of Metolachlor; |# {! n+ d1 C! F a* e; q7 J6 v. A
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 1427
8 i5 N% u- J& D- {- _: ?( Q41.2 Process R&D of Pharmaceuticals, Vitamins,
; E4 g/ N# A& X* `4 T: _and Fine Chemicals; r$ d+ Q- T/ T) w5 B
Rudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 1439
7 m) J" f' d8 y- P41.3 Cyclopropanation, y# G: K5 s q6 b/ l' n# C* u# X& S
Tadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1451' C1 Z( c) j7 R
41.4 Asymmetric Isomerization of Olefins! h9 m0 }8 ]5 I! g) I4 v g+ Y2 M3 Y
Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14610 Q- k: F& x% @4 T) I. K5 w
42 Future Perspectives in Asymmetric Catalysis
! E$ H$ Q1 ~( G |8 KEric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1473
( B( T8 ]/ C6 [& ~# A& DSubject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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