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Green Chemistry and Catalysis绿色化学与催化剂
$ |( i& l- S; \6 T' LComposition :K+V Fotosatz GmbH, Beerfelden4 {& w' E; k7 v" p
Printing :betz-druck GmbH, Darmstadt
. b# j7 E5 N9 O7 nBookbinding: Litges & Dopf GmbH, Heppenheim
5 M+ v- b* J" P4 m8 g/ E# t1 @Cover Design :Schulz Grafik-Design, FuSgonheim
! ~7 m2 S9 z" d! k& a0 n* oWiley Bicentennial Logo Richard J. Pacifico2 k! X* s( z: o4 Z" l* K
Printed :in the Federal Republic of Germany
# [6 f2 C6 m1 u! HISBN 978-3-527-30715-9
2 K0 y3 K q* J+ q8 gpage:445
8 U% _- ?, \) e4 T/ ZThe Author:Prof. Dr. Roger Sheldon* C3 c1 k* @- @$ r
Each generation has its unique needs and aspirations. When Charles Wiley first
; K g; |; A5 u% a8 Xopened his small printing shop in lower Manhattan in 1807, it was a generation
( C$ g/ A W- j4 `. o5 qof boundless potential searching for an identity. And we were there, helping to
) A! Y( v4 Q2 N# M! ^/ edefine a new American literary tradition. Over half a century later, in the midst
7 R, V: t* D! H& y6 f A% X7 [of the Second Industrial Revolution, it was a generation focused on building
7 r% f: F/ x6 h$ ^( r, Y& othe future. Once again, we were there, supplying the critical scientific, technical,
! f6 V) Z0 i( G3 i2 ^and engineering knowledge that helped frame the world. Throughout the 20th
6 l( P. n, {( e# L/ i( aCentury, and into the new millennium, nations began to reach out beyond their
# B$ D$ a* P+ a, b1 L* F) Xown borders and a new international community was born. Wiley was there, ex-
( r- O6 z3 x9 s* b# z, _ Hpanding its operations around the world to enable a global exchange of ideas,; q- m( k5 W( p
opinions, and know-how.
/ [, t! h# ^9 r9 A2 _5 M5 uContents
" d/ J# e: K& H0 n( UPreface XI
f, @! t& r. V0 v. v. }. wForeword XIII
& q( `+ E( n9 i( G( i" T1 Introduction: Green Chemistry and Catalysis 1& a1 H) B) k6 t4 w* M! f$ T* h
1.1 Introduction 1
+ i2 Y- A# U4 N t9 e5 {1 G1.2. E Factors and Atom Efficiency 2# o7 S2 d1 H2 }4 s
1.3 The Role of Catalysis 5+ C9 g6 @5 [' H J- g! V
1.4 The Development of Organic Synthesis 8
# D# W! O) Q% ?1.5 Catalysis by Solid Acids and Bases 10
$ Q" w2 r8 ~# E1.6 Catalytic Reduction 14
5 `$ b' {/ A- c6 d. D1.7 Catalytic Oxidation 18
* S$ s4 T7 l* M* `' @4 U% w& w1.8 Catalytic C–C Bond Formation 23
+ O( W2 P. ~! H7 D1.9 The Question of Solvents: Alternative Reaction Media 27
6 a9 |4 J( Y) s# P4 ^ D, Z5 U1.10 Biocatalysis 29
( h6 d# q4 F7 L1.11 Renewable Raw Materials and White Biotechnology 34% j, _+ S8 k3 u, D* Y2 G
1.12 Enantioselective Catalysis 35
$ m* o% P2 E# D( N1.13 Risky Reagents 387 T( t2 J% D& ^# h0 k5 Z( A3 @
1.14 Process Integration and Catalytic Cascades 39
6 b9 @" A* w, W7 {& HReferences 43
2 Y# U u7 H7 s1 u2 R- @- x5 ]" z3 n1 O............................ N) j* t1 H+ u- L+ \; [+ a& ?4 S& M0 r
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