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全书3个压缩卷,解压后5.67M5 N( A# m' V- a) Y9 {
书名An Introduction to the Analysis of Spin-Spin Splitting in High-Resolution Nuclear Magnetic Resonance
# U. i: x5 v' Z6 O! E `作者John ID. Roberts
* F! p9 p: X7 h6 [6 O' x: C. g出版社W. A. Benjamin, Inc., New York
% J3 Y3 O5 r" }6 m* O出版日期1961
0 \" H# z4 q. `) I3 L+ P* v7 Q出版号 61-12990
$ O6 y! a) x4 y* q7 M页数133
. K; ^% p2 V% J8 {内容简介; f" t- x% w. V' r- ?
learn to apply the methods of wave mechanics in a prac- : Q. d+ O! a) I8 r
tical way seems to involve a quantum-like transition with a
2 f; i$ k# ?! W- k% h/ F7 Erelatively low transition probability. Chemistry students by * y. [* a3 ]0 ~% z$ v# n) D
the thousands are exposed to the principles and jargon of ; A) t7 _1 |& S2 X2 g2 K
wave mechanics and are able to talk in a most knowing way
- E' F; s/ J% D9 m7 _" D/ g. j3 qabout orbitals, overlap, spin, etc. But very few of these stu-
5 k5 E7 m2 ^) n8 X( Odents can set about to make any sort of an actual calculation + K1 g9 |/ W' V/ ~6 }% ~" C, H
of resonance energies of conjugated systems or the energy : c _( @% R/ j1 r! g
levels of nuclear spin systems, and this despite the fact that
& l9 o2 w5 X! u. H. [3 xthe mathematics involved, although perhaps tedious, usu-
* k7 t0 n4 ] m5 m+ M; G+ Oally does not require more than college algebra. + I4 ?" Z8 S% \* w; r
目录 4 W |; O- W0 f5 C# `/ A& ]* p
1. INTRODUCTION. NUCLEAR MAGNETIC RESONANCE ABSORPTION 1 - w: ~5 o6 m) D U: ^& {6 C
1-1. Nuclear magnetic resonance absorption, 2 7 G6 B* k. R+ P! `& w: r
1-2. Chemical shifts, 4 1 F) K3 Z# ^' X, V- v
1-3. Spin-spin splitting-qualitative theory, 7
9 g/ p6 f7 ~" H- V4 e% r( l2. QUANTUM MECHANICAL TREATMENT OF SPIN-SPIN 25 8 ~8 ]; Y( O- j, ]8 H$ O
INTERACTION BETWEEN TWO NUCLEI ; ~! s. B6 @9 ?# O
2-1. Qualitative treatment of the AX system, 25
: S( j. r* M6 M7 X9 c- _5 j. a2-2. Qualitative and quantitative treatment of the
& W+ k+ G0 B6 m2 R! U0 ~. TA2 system, 30
" [$ g' H. a" S2-3. Quantitative treatment of the AB system, 49 6 l- v* V7 v4 R) H; b
3-1. The AMX and AX2 systems, 63 e d5 r& h( o1 |$ m: |! x
3-2. The AB2 system, 65 $ c# Y6 I" _/ ]; w. T9 `
3-3. The ABX system, 71
' Y: C/ s2 D+ {4 V v& J X, P; C3-4. The ABC system, 85
- s# c7 \- D9 d- ~$ c* }4. A FOUR-SPIN SYSTEM. A2X2 89 3 h) ~& Y& s. W1 x
4-1. The A2X2 system, 90 9 U0 m3 j/ D, j) b( H
Prognosis 103
; K8 N6 q$ N' }, [- L: c) GName Index 107 5 ~% }3 L6 K* E- f k. w( V: q
Subject Index 109
! x+ ^# d) `- k1 U$ ~
( g, z. S9 w0 b[ 本帖最后由 fenglianxiang 于 2008-6-26 16:59 编辑 ] |
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