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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。+ l7 m, Q% g; `
' }# S: N# m+ E; CVolume I0 z( M" u3 H1 N3 [3 a" V
1 Introduction
; Z# B: f% z% P/ D! x+ yAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 M% R; e: ~* m9 C" |$ I
2 Historical Perspective; e" u H2 n% @/ O5 E
Henri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9: v D! X& \& ^/ J& c
3 Basic Principles of Asymmetric Synthesis# W. R- e; r9 a* ^1 f# a
Johann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33$ {( q) p( M0 h' N5 ^8 G
4 General Aspects of Asymmetric Catalysis
' N. r+ E4 w* B4.1 Non-Linear Effects and Autocatalysis9 a8 {# \& Y. u$ r% ]
Henri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 101" U, f! d2 B( i, l0 U1 O
5Hydrogenation of Carbon-Carbon Double Bonds* S5 L: k2 E$ k) u( ^( X. E; i
5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds
) r- Y1 Y* R' c$ L- ~% T, S! LJohn M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121$ x* l/ f0 ^0 Q+ O2 l
5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds/ p" S- @) n4 W( m# _
Ronald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183
+ Z x5 _, S' I1 G6 G" @6 Reduction of Carbonyl and Imino Groups# V4 {! F; o0 z- q2 H" `) h
6.1 Hydrogenation of Carbonyl Groups
/ Q& q' r7 b% I; R+ u8 ~- c7 B0 bT. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
6 K+ R8 { P, J3 v, ^$ ?/ w$ G6.2 Hydrogenation of Imino Groups/ K( Q( @6 a& y# ~
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 247* x+ t2 h# @3 a O5 R
6.3 Hydrosilylation of Carbonyl and Imino Groups
) z! C) c8 c3 N' g( {Hisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2671 W( \+ H8 o1 n# R- t, [
6.4 Hydroboration of Carbonyl Groups% s6 }. O1 a6 a3 R! j) x
Shinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289# W9 F# n5 q4 P* d6 I: D: f
7 Hydrosilylation of Carbon-Carbon Double Bonds
* }! R" a1 j! s& e2 wTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3195 L$ {% O2 t. n; Z4 M
8 Hydroalumination of Carbon-Carbon Double Bonds
( `& \: O2 h, l# O; j9 F7 K$ c. PMark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 337
9 \0 N; e7 h: k9 Hydroboration of Carbon-Carbon Double Bonds
$ Z# N$ U% p' `! N0 t6 a( O; FTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351
% c1 H0 P3 N! u. \% g9 l10 Hydrocyanation of Carbon-Carbon Double Bonds
/ T- a, T: }' p$ y$ T2 [: g% i5 k4 KT.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 367
. Y Y2 f% _" ^7 j! M( _11 Hydrocarbonylation of Carbon-Carbon Double Bonds
% |0 o- B1 {2 n8 PKyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 381
# q( H4 J S: A' t+ Q1 l12 Hydrovinylation of Carbon-Carbon Double Bonds, ~$ d w, ?3 O: M; k/ t
T.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 417
6 T r3 ]* [- b13 Carbometalation of Carbon-Carbon Double Bonds* O# y9 J' p$ w' L: o
Amir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 431 r7 v, h! s- E1 g
14 Heck Reaction8 ?& B& J; p! k% [" Z- o
Masakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 457+ K. D6 x7 l* I$ b( ]8 V% c
Volume II' E% I0 m. E& ?+ K' f6 ^
15 Pauson-Khand Type Reactions
U3 v% u i% F1 ~( ZStephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 491
' }1 l, D2 u, h$ B: v16 Cyclopropanation and C-H Insertion Reactions
+ r4 P( @- \4 m16.1 Cyclopropanation and C-H Insertion with Cu
! a- {% Y, b% T `- r" JAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513+ A3 R* K: j7 m1 K; e
16.2 Cyclopropanation and C-H Insertion with Rh) B2 z1 O. ?' D% l. t* q1 C% W: C
Kevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 5395 q6 W, o8 g, g& o. {
16.3 Cyclopropanation and C-H Insertion with Metals ; R* z/ [- J9 ?5 Y
Other Than Cu and Rh7 F0 @' D7 | x( \
André B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 5819 U F: l# |3 N ^9 e" q+ G
17 Aziridination
$ ^. t: _) @7 s( ^Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 607) B1 d: h$ o- e q& }
18 Epoxidation3 O' b) \+ \) b W" v! h* @' J
18.1 Epoxidation of Allylic Alcohols
% a6 a5 o+ y/ P) z7 {Tsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 621$ ]" {8 Z R7 D2 j* Z5 `, c9 M
18.2 Epoxidation of Alkenes Other than Allylic Alcohols) ]! N, r$ I. ?7 l; D
Eric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 649
. Q; g/ a2 x1 ~1 i, e$ P2 D18.3 Epoxide Formation of Enones and Aldehydes
M! F" x: S8 ^! N7 T; u+ SVarinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679) E! }4 I( U; p. E z
19 Oxidation of Sulfides
3 Y+ ?$ Z3 [: [Carsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 6975 N4 ^* g! m- X# h. t; w7 ~
20 Dihydroxylation of Carbon-Carbon Double Bonds7 c! y4 I: r5 N; O
Istvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 713
9 e5 ^1 a9 Q0 p; A21 C-H Oxidation
- \/ W& H0 L- J! H+ i# Z- tTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 791
9 p4 k5 t3 k+ D, s% v22 Baeyer-Villiger Reaction
' c& V9 k) X0 k; G# h2 p$ B* tCarsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 803# K$ }& f# t' N' W+ I( c: k
23 Isomerization of Carbon-Carbon Double Bonds/ ?4 p0 P a3 d* Y8 `3 ^
Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 813
6 m0 f' E. W* \/ c2 k+ z( n: I0 D24 Allylic Substitution Reactions9 l! Q/ @( w! Z% G/ J0 c6 M( ~
Andreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 833
, j' K' Z) J! G9 h( z25Cross-Coupling Reactions
- p1 P9 j2 n' J# C3 UTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 887
1 y& b( S, V8 X& z" L2 m26 Alkylation of Carbonyl and Imino Groups
. r5 J( v2 V& h* o8 @' Y26.1 Alkylation of Carbonyl Groups: C, w9 O2 \ @: I. R
Kenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 911# f4 S: N+ d- s$ }
26.2 Alkylation of Imino Groups
7 o6 V( P% ^6 w" z( o! gScott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 923
& ]1 Q3 R8 s1 d5 c+ H1 w( v27 Allylation of Carbonyl Groups
& V: o9 q+ |/ f1 h7 ]' I8 hAkira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9658 p; E6 R; G- Y1 \
28 Cyanation of Carbonyl and Imino Groups' a/ A5 [* H5 N* r9 d$ ]7 J
Atsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 983
" Z# I: Y' H1 {" VVolume III0 S% I# D# \5 Y" _1 I m* |& m, l, @
29 Aldol Reactions% G, l+ Z! H' f) w6 y; ]
29.1 Mukaiyama Aldol Reaction
3 O4 i( f' g* {5 r- N9 W# _Erick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997. Y8 K9 Q$ G9 {; u; s
29.2 Addition of Isocyanocarboxylates to Aldehydes& ]( S& }5 ]; V$ F7 c6 m( D
Ryoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 1067
* P g+ F% Y9 [5 U0 ~5 }: m29.3 Nitroaldol Reaction
) F, K4 c* q N4 |Masakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 1075
& h4 A4 N+ p& {: |4 @: R# Z6 c( D30 Addition of Acyl Carbanion Equivalents to
% N$ p# X7 M4 A' G! _6 d cCarbonyl Groups and Enones& X4 c. V- ?1 s$ x) L' E
Dieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093" S: c1 P8 ]% h$ o
31 Conjugate Addition Reactions
. n6 c" y- E- {6 u31.1 Conjugate Addition of Organometallic Reagents
' @- e+ J* _5 C4 D: CKiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 1105( _1 T. o% |$ ]3 `
31.2 Conjugate Addition of Stabilized Carbanions8 r& m! i& Z0 Y/ f3 p3 l
Masahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121# X4 L& S4 O( n5 N- O! H
32 Ene-Type Reactions
/ Y" o& t" @2 i. i* b5 S FKoichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 1143
/ u- }" B# ~( @3 Y [0 Q2 p33 Cycloaddition Reactions
5 _. H* v( Z7 _; `6 Z3 O3 e* M) Y33.1 Diels-Alder Reactions, V9 Q5 b j4 q$ A( w# k
David A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 1177
- P* S" u: h0 \% G, L) G33.2 Hetero-Diels-Alder and Related Reactions( I7 ]; P3 l' |" ^0 ?( T2 c
Takashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237
0 O, l/ K' u ^8 A# U4 y33.3 [2+2] Cycloaddition Reactions
3 _( b' b! ^0 \" Y% \Yujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 1255/ d' x7 t' n1 R! j
34 Additions to Enolates \0 A! z& u4 H+ u1 A: V
34.1 Alkylation of Enolates
F% H# H* @& m5 Z, z. xDavid L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12733 Q# o/ G4 k% t/ D' o
34.2 Protonation of Enolates
0 W) \ t) m6 H3 wAkira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 12959 m2 d2 F. ^9 J1 V5 G! C; R
35Ring Opening of Epoxides and Related Reactions
, \# o: o5 e1 q# \: a. oEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 13092 g# i5 m) G# U d- ]
36 Polymerization Reactions, v8 h! ?+ _1 W. N) z6 C
Geoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1329) q0 G% G: d" [8 p% v# X7 M8 a
37 Heterogeneous Catalysis
' M t6 j) B7 O; V, ~Hans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 1353
" [5 v& r, G% c) z* Z5 _8 c! t8 W4 e38 Catalyst Immobilization& U+ v; l3 F) Y- A, q1 p% k
38.1 Catalyst Immobilization: Solid Supports- C9 K; Q6 L' x9 [
Beno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 13677 p2 r8 O+ W' ?
38.2 Catalyst Immobilization: Two-Phase Systems
3 k( X8 M6 X6 Q. \: AGünther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377
$ r' M, v( I6 f$ S( U" I39 Combinatorial Approaches: a8 G* O8 D5 Q/ S1 j4 | C+ ~
Ken D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 1389. L! d5 X9 w1 L# `9 u6 y
40 Catalytic Antibodies
3 y2 u9 \' e, bPaul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 1403
4 F q! l( H" q4 C41 Industrial Applications/ H) P5 I, v1 r& z% Z5 ~$ {4 S
41.1 The Chiral Switch of Metolachlor: ]" s, }: p: M2 p
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 14272 R, k) L" R" E
41.2 Process R&D of Pharmaceuticals, Vitamins,
4 K4 o4 J8 A2 e, {+ _" k' Cand Fine Chemicals
, e: Z' Z1 |3 s4 q- `6 XRudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 1439% V8 |. Q2 D+ ?
41.3 Cyclopropanation
$ K. ^+ `( D& FTadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1451' ^) {" T% j3 g) j6 N
41.4 Asymmetric Isomerization of Olefins
4 P& w# R2 `. ~% GSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14612 ?- f) M1 G8 x% B. s/ u/ L
42 Future Perspectives in Asymmetric Catalysis* G6 f5 Z* C2 Z$ f. g2 Z8 L o" u9 o
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14734 v7 b9 F2 D4 U# B+ N7 I- N) b
Subject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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