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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。+ w) a' Q9 w8 J* P8 {
/ h. C0 s. A! M7 C! f
Volume I0 l1 f: h, }! t" o0 @
1 Introduction" l5 w3 m& Z1 Y- J1 R: W
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
' o6 }! Q" Q/ L. c% t$ f2 Historical Perspective) l5 T0 e0 q1 S0 B6 b5 V9 P+ Q
Henri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
5 r% j9 a0 u" r0 ~( A3 Basic Principles of Asymmetric Synthesis& m0 [1 T# ]; ~$ o3 s! x
Johann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
8 W3 g' D) h7 M _4 General Aspects of Asymmetric Catalysis5 ` |" j5 a3 Z2 M7 N0 T- Q
4.1 Non-Linear Effects and Autocatalysis N; O% y9 c4 {9 s* I$ G1 U
Henri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 101# T+ H) T# x: D
5Hydrogenation of Carbon-Carbon Double Bonds; J9 s" L/ b/ ] ?% a. c
5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds7 |$ j, x5 d$ S( R/ u
John M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1216 G$ _* y4 h" ^7 ~ h
5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds
. B" i4 D3 h8 j2 J0 w- i0 b& SRonald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183
! }: R' u# z6 z3 ^ h- s6 Reduction of Carbonyl and Imino Groups
# {+ J4 e/ S: i# K; Q! @/ p8 w6.1 Hydrogenation of Carbonyl Groups
6 R" ]6 ~5 [5 H& Z' \& H; tT. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
( f# ]! i5 T+ U9 a" u: [: N6.2 Hydrogenation of Imino Groups% I3 v( N7 Z6 H. i9 _$ x
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 247; a3 Q$ F+ ~0 ~2 s: ~9 q! t
6.3 Hydrosilylation of Carbonyl and Imino Groups
4 F9 b. u# w$ T$ bHisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267
) ]" c! u5 I0 N4 P ?9 f. t6 O6.4 Hydroboration of Carbonyl Groups; E" c E+ t7 p, c; f
Shinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289* W; h& R u$ }2 z! b9 C
7 Hydrosilylation of Carbon-Carbon Double Bonds
; u6 B: ^1 `' {8 ?/ {/ TTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319
6 k1 a, G& w8 I( i8 Hydroalumination of Carbon-Carbon Double Bonds
* N: P% f* m4 I' Y! f7 SMark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 337, b6 \" I3 u; k8 B& J$ H) @
9 Hydroboration of Carbon-Carbon Double Bonds. ]6 r8 D/ ]2 ^
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351, G/ S2 G+ g, B+ h2 T+ \/ L
10 Hydrocyanation of Carbon-Carbon Double Bonds" R7 _) ^, F ^' J9 i8 N; ^+ C
T.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 367, l' M7 \7 M$ I% O9 {4 p
11 Hydrocarbonylation of Carbon-Carbon Double Bonds N1 p7 z5 `0 F1 o7 u
Kyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 381
& `2 b$ l% @( s" p4 b: v) J% C2 O12 Hydrovinylation of Carbon-Carbon Double Bonds6 H" L3 l+ ~4 U& T" ?' x
T.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 417
8 G2 ^% n# U! q7 I8 Z" b13 Carbometalation of Carbon-Carbon Double Bonds" a# `8 G* c/ _
Amir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 431
* O7 x. [" l* `* K$ y# g14 Heck Reaction
- Y* o4 z s, L. b# c. K$ yMasakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 457( l( U' D9 w3 ]. s
Volume II
; @% j( n- Q% b( T3 f15 Pauson-Khand Type Reactions" m- [% H: \. a! v
Stephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 491 _9 f& E) f/ J; M _: r
16 Cyclopropanation and C-H Insertion Reactions% u/ f" |3 ~- _( C' S! Q
16.1 Cyclopropanation and C-H Insertion with Cu
, P- I4 f; R* a6 Q2 \2 R* eAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513- B" f$ T' M3 n; l1 b) a
16.2 Cyclopropanation and C-H Insertion with Rh
& N- U1 X, u& \: |5 `( qKevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 539
; T- h ~- A+ ~4 J) G2 a4 o16.3 Cyclopropanation and C-H Insertion with Metals
! L1 x& d% @8 o0 |% f5 s/ POther Than Cu and Rh
2 |: J6 z, \! S1 D, |6 AAndré B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 581
% y# z5 {. l- L+ C3 q5 w5 J2 S17 Aziridination" y$ k- j/ R" _9 I" x$ w" W
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 607% k5 U# N4 E" Q( R7 c& n
18 Epoxidation
3 [# F, H0 y! c6 Y- n2 [# M18.1 Epoxidation of Allylic Alcohols9 l& j: p1 \. n* T* F
Tsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 621
& |2 n% t2 }' n) H! J5 d" c18.2 Epoxidation of Alkenes Other than Allylic Alcohols t- q) B: [' O; x
Eric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 6491 D- D5 {0 C' Y$ T' q; C
18.3 Epoxide Formation of Enones and Aldehydes
5 W$ B- k0 P3 ^" G- A+ dVarinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679, L5 R- \& x/ h, X
19 Oxidation of Sulfides4 _4 C6 i: j$ a/ j2 r, L6 R& O
Carsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 697
. H& A$ q6 Z. O1 ~& U* H20 Dihydroxylation of Carbon-Carbon Double Bonds n- V0 S5 R: C
Istvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 713
2 L0 a8 e# F- v3 G3 l9 I21 C-H Oxidation
/ |5 w) u1 u8 o. q: w, ZTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 791# V) _9 l, o6 W0 \3 w% F& ~
22 Baeyer-Villiger Reaction1 t+ b7 m% f$ [) k3 I" S
Carsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 803, n8 u- c. m6 c! I2 X4 O
23 Isomerization of Carbon-Carbon Double Bonds
2 D6 V! T. O' K9 x* t- QSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 813
' r- ?& N: C/ X) L, o24 Allylic Substitution Reactions8 T3 i- o1 N g( x3 C$ y
Andreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 8335 A y7 O1 I+ E$ d
25Cross-Coupling Reactions* o. I1 ? B0 M% I1 W
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 887
, a$ F" ?: M' g- i- X26 Alkylation of Carbonyl and Imino Groups
. Y3 @ Z$ ~4 K) O26.1 Alkylation of Carbonyl Groups- C6 y& u0 y/ a4 [# f/ w C
Kenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 911
* [8 c7 t3 f" v26.2 Alkylation of Imino Groups8 G2 w/ Z: E( x/ }5 H; L
Scott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 923/ F3 ^( q4 ~; l3 }# ]
27 Allylation of Carbonyl Groups% H- t( U6 s: O2 a" v/ h
Akira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 965; c# ?4 g; W) } Q; [
28 Cyanation of Carbonyl and Imino Groups& r$ P; q" ^4 ^! ^6 _$ w
Atsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 9838 z2 D7 i2 t" M$ E4 N
Volume III
4 v& Z, X" W3 ~/ s4 M$ Q2 j5 p29 Aldol Reactions) U/ u* G1 _: O- q" r* z- t5 T
29.1 Mukaiyama Aldol Reaction
L3 x c' q8 t( C3 ?, O; |Erick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997
: P9 }' K$ ?: i& N9 r- ]3 X9 A8 r29.2 Addition of Isocyanocarboxylates to Aldehydes
8 T' J. s; E+ B* p( a% u9 H0 KRyoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 1067
& Z* O& s: J( b! [3 d: @29.3 Nitroaldol Reaction/ o. s1 h& z, T4 r+ y! p; p# E" |
Masakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 1075
( Z9 `0 L( G2 E0 x* Q! G' H30 Addition of Acyl Carbanion Equivalents to 7 L5 y* j' ]' W8 X- p
Carbonyl Groups and Enones
0 ^2 o: ^7 A% [3 |9 y0 ~% _6 ^! TDieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093
# {0 I0 h+ \4 i. Q3 Q0 p31 Conjugate Addition Reactions
& t1 y8 L$ _$ K7 X31.1 Conjugate Addition of Organometallic Reagents6 x l+ L1 S: E
Kiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 1105
i X5 r5 W. C0 P% a; w; I! s31.2 Conjugate Addition of Stabilized Carbanions' g0 N5 `- E, z% K, y* O1 ]
Masahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121
9 [% ]3 M# R9 ]$ {. A32 Ene-Type Reactions0 k- w/ }9 \ J
Koichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 1143
7 ^' g/ W8 P0 q1 v5 B: v33 Cycloaddition Reactions
7 s1 r+ c3 i+ x33.1 Diels-Alder Reactions6 x J( ^9 }) [$ F& J
David A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 1177
. p* ^, s) z; u- g0 ~33.2 Hetero-Diels-Alder and Related Reactions5 c# s; p; `' X% Q
Takashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237
9 N3 N( N* q) W33.3 [2+2] Cycloaddition Reactions
+ A2 v9 a, b! y6 X/ ]5 o4 iYujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 1255. P' D- ~' {+ O( D
34 Additions to Enolates0 U6 O2 U* r' y! _7 Y1 T
34.1 Alkylation of Enolates
7 e8 ~! s1 g, |1 ^: SDavid L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1273
8 |; ~9 f' ?# k# k. g! ~; L34.2 Protonation of Enolates
5 e* R4 s; S" w6 t O* `* YAkira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 1295: k9 Q$ o1 I/ U9 U! ]* V& t' L
35Ring Opening of Epoxides and Related Reactions0 e1 W& i' F/ s2 }+ k( r3 Q
Eric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 1309& Z0 L2 a/ y- L: E0 x' ^' W
36 Polymerization Reactions0 A" v) X& w0 ^4 u$ G' q) ]- s
Geoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1329
$ A! j: y1 U' }& m6 q37 Heterogeneous Catalysis: Z& @/ C7 k& s& ]1 ]: v
Hans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 1353
2 V; z; c8 Y& I* u+ R& o38 Catalyst Immobilization
; A! c. e0 s+ A/ v38.1 Catalyst Immobilization: Solid Supports
: Y: C# Z( r1 d, QBeno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 1367
6 ]! f* L( e1 C1 v38.2 Catalyst Immobilization: Two-Phase Systems
+ m+ d q% y2 }4 y3 m1 W$ IGünther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377
" W6 A/ c0 f' b* x7 k7 r, @2 l39 Combinatorial Approaches& }$ x6 f8 w( L7 T
Ken D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 13895 b4 P. x# P4 ^' F' o# v# `
40 Catalytic Antibodies: [/ `1 q3 X7 G2 ?
Paul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 14033 f2 k% K5 N2 v% a1 R5 Z
41 Industrial Applications
3 {4 ?" G6 ]& t% V! z41.1 The Chiral Switch of Metolachlor4 K0 i, f ^' J
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 1427
7 S2 u3 C; A1 e1 {* E41.2 Process R&D of Pharmaceuticals, Vitamins,
; s9 k& W+ G. G* L; aand Fine Chemicals8 v2 z! s( q: J4 L; O2 R; C+ x
Rudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 14393 Q: R! U5 J J/ Q+ H
41.3 Cyclopropanation
- H, L0 V1 E5 M& i {Tadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1451
5 y h2 d1 `6 R9 H5 K% n41.4 Asymmetric Isomerization of Olefins
" R" c7 h9 N: O4 P+ i! YSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1461
7 T4 i7 W! w3 O8 ^2 Y8 s42 Future Perspectives in Asymmetric Catalysis
' h) S1 [+ `! h t8 [8 KEric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14730 L; x/ X) r/ {
Subject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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