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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。1 c; z9 `6 n: p7 H5 g% ], ^' F
3 h6 G' n1 Y- J. O+ |0 ]8 t z
Volume I
8 ^, P& ^1 y8 }1 Introduction0 n: B1 Q1 P% }) T
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 q( \+ r6 @. i6 E/ h* m
2 Historical Perspective
& V+ E8 n0 r, H* @. w5 @, THenri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
& j% f, {% V$ O, B# ~& }0 _! v3 Basic Principles of Asymmetric Synthesis
( T5 \' S" Z1 B5 O: Q$ }( WJohann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
% b3 C2 p3 I( x$ J% _) Y0 W$ L) J4 General Aspects of Asymmetric Catalysis3 R* K+ N5 N; E% O9 z, Y
4.1 Non-Linear Effects and Autocatalysis
, r; A: Q* ?& R6 p, `$ JHenri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 101( K# ?6 \2 M7 t- l* W# \! t
5Hydrogenation of Carbon-Carbon Double Bonds# k$ T, d, K# Y0 q+ Y8 c! h
5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds
' o7 d0 U" m8 [1 v. ZJohn M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121
: y& E7 Z) {" u* F! a& l2 v5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds p! x0 H2 T v& Q4 [
Ronald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183
8 p7 l0 U' K4 v9 B' X6 Reduction of Carbonyl and Imino Groups
( i' I% O; ~, g( k% e$ o9 w6.1 Hydrogenation of Carbonyl Groups
, H& E. X+ ^ E2 E( G" hT. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 1993 m" O% z: u# T- ?; B
6.2 Hydrogenation of Imino Groups
: Q$ o) R: [! Y' L% vHans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 247
# B# A. K5 k) o0 P) |3 N) ^; C& _6.3 Hydrosilylation of Carbonyl and Imino Groups
. }! E, {( e2 o3 n" qHisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267% R3 @; }$ l7 ?8 ]
6.4 Hydroboration of Carbonyl Groups
1 k2 @! e, z, G+ `+ W8 a7 LShinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289
0 t0 t# u5 _! q; @6 }. b& K7 Hydrosilylation of Carbon-Carbon Double Bonds
6 R. s9 \2 G7 {# {: XTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319& j' ]) u; F- ^1 T
8 Hydroalumination of Carbon-Carbon Double Bonds
- y E0 K# [7 dMark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 337" u% a M5 ]4 s' S/ S
9 Hydroboration of Carbon-Carbon Double Bonds
, h, Q# w% U% F+ Q6 _Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351
v, P, S# q4 P; }8 f10 Hydrocyanation of Carbon-Carbon Double Bonds4 E+ b$ D7 \( e- l+ a
T.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 367
6 Y4 }4 C2 ]8 t) D% ^0 U4 R11 Hydrocarbonylation of Carbon-Carbon Double Bonds+ u! ?8 Z) B( [7 W- w
Kyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 381
) l: Y0 Q4 y6 Q7 m% n, j5 w7 C12 Hydrovinylation of Carbon-Carbon Double Bonds
# N2 o# p% m( [2 l/ K8 Y) bT.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 417# [: `$ \7 [" ?; L9 J# O. |) l
13 Carbometalation of Carbon-Carbon Double Bonds- J( k) `2 n% E. X- X
Amir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 431
* f3 \6 U# V1 J7 @14 Heck Reaction' p+ R/ o: E6 T( L
Masakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 457* B3 O, g3 W. h1 E, e6 c
Volume II
( O! U' p4 z3 d+ I5 n4 W; ~15 Pauson-Khand Type Reactions6 u, F6 b6 {$ i: L% f
Stephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 491 r4 H% N& d# |9 E2 `
16 Cyclopropanation and C-H Insertion Reactions
, ` \3 t3 E& \% L- d8 @8 m16.1 Cyclopropanation and C-H Insertion with Cu
- l( M6 m; N3 X( T8 U$ jAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513* r5 G. u+ D2 p. p* B
16.2 Cyclopropanation and C-H Insertion with Rh
, C# J0 J5 ?0 N8 nKevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 5394 \: y F5 ~. r) |) u* K
16.3 Cyclopropanation and C-H Insertion with Metals 7 t; U) |- D& T
Other Than Cu and Rh6 ^" `5 D$ U* q+ x6 @8 R
André B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 581
1 Q) E0 r$ k" Q, V: x6 h* e7 w17 Aziridination- W3 a' n6 J8 X6 X& R+ m
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 607
7 Z: i) [9 Q3 P2 u18 Epoxidation; N) x) N! P* g5 G4 k J. Y7 i
18.1 Epoxidation of Allylic Alcohols7 C, ]5 p8 M; j* A
Tsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 621
: m$ X7 z X6 B% F2 r( B18.2 Epoxidation of Alkenes Other than Allylic Alcohols
- ^/ z8 B6 v4 w1 xEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 649% S) u8 m% Y9 y) N4 O/ I
18.3 Epoxide Formation of Enones and Aldehydes . w& P$ Y0 u+ D6 [4 b! N
Varinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679. @7 ?2 |. Y7 f! n4 S% O
19 Oxidation of Sulfides8 I. E- O0 [- ^
Carsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 697. ^/ W' R/ k" c8 e) w+ I4 w" d
20 Dihydroxylation of Carbon-Carbon Double Bonds
. J* i* \) x! L# fIstvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 713! X: l& \4 I5 T7 \1 O9 C# a
21 C-H Oxidation
6 S8 e5 a6 X8 y1 ^( h# H cTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7918 h# X8 a( V( a: J
22 Baeyer-Villiger Reaction- @. f) @; C% B! j7 a- p8 I( t
Carsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 8032 L @7 _7 f# L' O3 n9 X, A
23 Isomerization of Carbon-Carbon Double Bonds
! B( A$ X# R; fSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 813
( n2 n- w1 L4 s* p7 I& t* C24 Allylic Substitution Reactions
: U% G/ X/ S) f4 GAndreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 833( s6 O+ U5 U0 q6 i' ~6 n8 z2 `
25Cross-Coupling Reactions
; C& ]- ~3 h4 E N. o$ eTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 887) u/ C9 ~) m5 k! b8 S
26 Alkylation of Carbonyl and Imino Groups
& T" d4 q. |( d$ K26.1 Alkylation of Carbonyl Groups# k( q! X) T& B) M+ X" g8 e" l- E* ~6 k
Kenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 911
4 @0 K3 o: F1 Y; d1 y26.2 Alkylation of Imino Groups7 H, K" v5 L; n8 H+ M( G
Scott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 923
6 l8 m" S4 r' z- G- M; K% Z27 Allylation of Carbonyl Groups" g4 M u( }# k' |0 g* B3 m' z
Akira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 965, Z+ E% O3 ^7 t6 L
28 Cyanation of Carbonyl and Imino Groups
# i9 o6 V) U0 o7 r! b3 i& i- zAtsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 983
& R* H* V" E1 N4 _Volume III
9 W: O* X: @, g2 P29 Aldol Reactions
( A( A( X' s* a7 m* z! Y29.1 Mukaiyama Aldol Reaction
9 t6 W1 Q+ q! [4 _$ DErick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997: f8 h0 p w2 N* E6 W
29.2 Addition of Isocyanocarboxylates to Aldehydes( `( Q! r* A+ P4 x% e3 R
Ryoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 10677 R, B( a& r- D1 c% z
29.3 Nitroaldol Reaction# A8 L5 ~9 T: t P1 e6 n. y
Masakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 1075, s7 i! n) [* o4 `- l- Y5 J
30 Addition of Acyl Carbanion Equivalents to
, ^1 B3 j7 A# q7 @7 J; JCarbonyl Groups and Enones1 ]$ s+ m# F$ R% Z: c" ~
Dieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093
; ^5 Q& a, L( v4 H31 Conjugate Addition Reactions
4 V. X5 k% L0 N9 i$ l31.1 Conjugate Addition of Organometallic Reagents7 I) r) h6 ^9 y8 b
Kiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 11050 W/ h/ Q* q( t0 H4 k J
31.2 Conjugate Addition of Stabilized Carbanions9 v: H# ^ u, y% c
Masahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121: U% r5 [4 T% M# q" |# `
32 Ene-Type Reactions
* \! v, {8 y7 }Koichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 11430 s0 X: X6 {9 ~+ P) y
33 Cycloaddition Reactions* V- J# S: c. Z+ Y
33.1 Diels-Alder Reactions
1 r8 ]3 p3 r F/ ?# m+ BDavid A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 1177
3 \( Q, [7 y7 U8 h33.2 Hetero-Diels-Alder and Related Reactions( N/ Y: W- [3 n. N3 I
Takashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237. V. i2 H x: u" |/ H6 W) c
33.3 [2+2] Cycloaddition Reactions 7 Z7 C/ H1 W9 i. c, x
Yujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 12551 }5 Q% W( a1 A% S
34 Additions to Enolates5 m# S+ i3 p6 s8 M W( {0 e
34.1 Alkylation of Enolates
$ E% a+ D' q7 }: k3 e# X' Y" |. lDavid L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1273$ b' p! y" n0 G$ I; o( A4 w
34.2 Protonation of Enolates0 l" ?) U- U4 j1 i
Akira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 1295
; A& O. j) [, c* Q: l7 s. K. t35Ring Opening of Epoxides and Related Reactions
- ~ u7 q2 ~% B8 U% z& D8 nEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 1309) T3 }) J) H+ ]/ q9 d& x5 Z
36 Polymerization Reactions
. `& D& N2 p: b( R$ qGeoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1329
' d) l0 F- o% |/ W0 H37 Heterogeneous Catalysis
3 N% Q- [9 w+ K" m- d: m5 z0 MHans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 1353# j# w, V2 n, m8 W
38 Catalyst Immobilization
0 Y% B) {( `5 a, w& j38.1 Catalyst Immobilization: Solid Supports
) G- H6 g- Y0 ]1 dBeno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 1367
. U. ?/ ]/ ?: p38.2 Catalyst Immobilization: Two-Phase Systems
. ~8 `) D0 x% z5 C/ i3 ?Günther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377% |+ G; r9 S& _% @6 {& N
39 Combinatorial Approaches; F5 S) H$ p0 a% }3 \" l
Ken D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 1389
5 A% a+ `1 f% n% d7 I9 G40 Catalytic Antibodies
, c# V7 x# [0 g; T; _2 iPaul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 1403# g' r6 V7 o. D
41 Industrial Applications0 G2 m7 o7 _; T4 \% \' h
41.1 The Chiral Switch of Metolachlor0 ~1 a& Y9 S2 Y) E
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 1427
1 X, p3 V3 d3 T0 N41.2 Process R&D of Pharmaceuticals, Vitamins, . F8 s0 x/ T/ S5 m: {, j$ a
and Fine Chemicals0 `& o C. q8 e4 e- \
Rudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 1439# {7 g: g# o A" V8 [
41.3 Cyclopropanation
* |( v# [! q& [% {Tadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1451
* L( ^: @/ ?/ p41.4 Asymmetric Isomerization of Olefins
: e+ r" l1 ~ x/ ]) YSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1461 g" R, D9 x; k. Y) P5 E
42 Future Perspectives in Asymmetric Catalysis$ s5 p# v; z7 w
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1473
5 w- X: G& L9 K% JSubject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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