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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。& l8 @! |! X. y1 K0 N
* C, M D( Z& A( o% N# G+ S% ^. ]( A
Volume I2 R" ~# x8 x3 `. I8 {0 q
1 Introduction
" r2 J4 Z. [- R9 Y( [ Z5 gAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 e4 g0 V+ g, i# {3 G
2 Historical Perspective
* R3 R5 G G( ]! X* ^( V5 hHenri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94 P1 Q: | \+ s: W& v
3 Basic Principles of Asymmetric Synthesis. t- d1 b1 a2 z+ D& S: t/ G7 ]! B
Johann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 333 _) U& S6 [/ s( ?1 A b: ^: P
4 General Aspects of Asymmetric Catalysis* F) h' q9 l5 G* o' c
4.1 Non-Linear Effects and Autocatalysis/ P+ q( k. m0 W. ^8 k( b
Henri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 1011 M. p2 E0 T) [, S+ \4 I+ u
5Hydrogenation of Carbon-Carbon Double Bonds
! D6 P0 e8 ] @: i* {5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds
5 e9 K2 {$ k( F4 n5 K5 ?John M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121) I; z2 z% r% o/ T& N" ?0 T
5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds- d' Z/ j' D4 I8 M
Ronald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183$ ^" A4 j1 i3 E: I) Y3 o
6 Reduction of Carbonyl and Imino Groups9 h1 x( Z; a; N2 n
6.1 Hydrogenation of Carbonyl Groups
6 U' v7 C$ P# QT. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 199- @0 B. _+ r* Q7 {) @
6.2 Hydrogenation of Imino Groups: S w5 p5 E; H P6 }, i6 X( O
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 2473 r$ B- [3 U; S' v' E4 t- r
6.3 Hydrosilylation of Carbonyl and Imino Groups S# m2 b* f+ e$ C' W5 U, C
Hisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267' ?+ \( x2 [1 u; J+ ~
6.4 Hydroboration of Carbonyl Groups
, d) ]& ~5 D8 H/ e ^Shinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289
, {; l. p3 V9 b! s; C7 Hydrosilylation of Carbon-Carbon Double Bonds0 V% T4 z/ X+ \" n- R, L
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319
! k7 o# H; W9 x' V! q8 Hydroalumination of Carbon-Carbon Double Bonds! q0 i- {% i( F7 O* }
Mark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 337
& K$ @9 I2 S* K6 {! }. S' R9 Hydroboration of Carbon-Carbon Double Bonds# d7 T8 I- r1 x9 E9 n6 e4 ?* v
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351
h' s' d( {* c7 J4 e. S10 Hydrocyanation of Carbon-Carbon Double Bonds9 B( J5 b6 ]2 M) A) j
T.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 367
) e9 R. V1 A# S: p) `: c& k11 Hydrocarbonylation of Carbon-Carbon Double Bonds
( X- d/ T7 a9 ?& J; eKyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 381
" k) x( I+ C, R [% f12 Hydrovinylation of Carbon-Carbon Double Bonds; }5 v! g) m2 S4 J7 v) z2 f5 n
T.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 417 @; K. H9 z, A: d
13 Carbometalation of Carbon-Carbon Double Bonds( ^9 P3 w( Q+ ], f4 K8 P* Q
Amir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 431
. Y7 Y% ?- T9 ?( S* f14 Heck Reaction0 g; h5 L0 _, `9 f
Masakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 457, F# q! `3 |" u' N
Volume II# E: G% n% q( X
15 Pauson-Khand Type Reactions: N3 m& a* s8 Y, \5 C* P
Stephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 491' \- M8 P8 I; g! b8 W, h
16 Cyclopropanation and C-H Insertion Reactions
. g$ ?$ i) ]' L: j8 T16.1 Cyclopropanation and C-H Insertion with Cu2 z3 j, X/ \( a- V [
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513
1 h$ x& b2 d* Y d& h9 I4 x4 D- l16.2 Cyclopropanation and C-H Insertion with Rh) w% r( B# k+ ?# h7 @) d! B
Kevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 539
* D% [6 v2 A7 b; t! M) }2 F16.3 Cyclopropanation and C-H Insertion with Metals & J8 a2 F# x. `0 F; I
Other Than Cu and Rh Y6 |, V: \9 t# f: p
André B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 581
; `. B; i8 G' W: L17 Aziridination6 b* @% }+ I+ N$ J
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 607( u2 Q9 z5 q3 }; [6 g3 q5 O
18 Epoxidation
& i9 }9 K: R, b# d/ u* G7 ]1 ~18.1 Epoxidation of Allylic Alcohols5 Z- k$ y# J: s9 B% m7 _9 U% b/ A
Tsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6216 m8 Z/ X5 R' O$ j0 P
18.2 Epoxidation of Alkenes Other than Allylic Alcohols
7 @. {1 r h2 `! B+ {0 h, y2 YEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 649' J8 {& r W; ^8 {% ~: k4 k& `& R
18.3 Epoxide Formation of Enones and Aldehydes 4 A; y$ `% S6 j3 Q. L
Varinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679
: Z, {. C# t T) n19 Oxidation of Sulfides
0 A/ S b1 X4 H( ]7 K- eCarsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 6978 Y- ^/ W+ e+ ~. t! b: Q
20 Dihydroxylation of Carbon-Carbon Double Bonds$ w! a: j2 n* |: U+ w
Istvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 713
! R7 ^4 K2 M* U8 Y8 i V7 e9 \% H21 C-H Oxidation* c% o8 n- h: D7 e d
Tsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 791
0 v' @7 ?: e5 E6 T2 N/ U/ r22 Baeyer-Villiger Reaction- t. w$ `3 t! L" n! ^1 R, Y
Carsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 803
. `- O6 L6 i2 ~1 w+ u23 Isomerization of Carbon-Carbon Double Bonds
& u" ^' q& z: S4 v5 LSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 813
/ W; Y: i4 b) W24 Allylic Substitution Reactions- x4 L8 y0 t5 {1 m1 W- z$ \8 s
Andreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 833
" M; M( i* z w" v25Cross-Coupling Reactions
b- H+ t6 o0 w1 A! sTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8877 c6 o% ?7 [7 R) x! {7 A
26 Alkylation of Carbonyl and Imino Groups# A# `* v, ~2 m9 |, `& H! A
26.1 Alkylation of Carbonyl Groups0 C2 m- t! i9 l8 [
Kenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 911
4 D! x& \, \/ f. N26.2 Alkylation of Imino Groups0 X. d" ]8 P- Y
Scott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 923% {( T( b- d4 l I, _! u' t
27 Allylation of Carbonyl Groups# c3 |" M6 R+ O; Q; H" a \& G
Akira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9658 w2 C( t7 s( i
28 Cyanation of Carbonyl and Imino Groups
5 l+ w6 }; n( T! E. f4 EAtsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 983
1 Q+ ?, w) G$ C9 J/ Y2 A oVolume III' J+ [; F# p% }* \$ M
29 Aldol Reactions
- [, E" O1 \9 J" |, ~# g/ z29.1 Mukaiyama Aldol Reaction: S: K6 f. r" p: R# e
Erick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997% P/ n# I0 \4 \9 b- x
29.2 Addition of Isocyanocarboxylates to Aldehydes
0 W5 X7 M7 \1 f+ J1 yRyoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 10674 W$ {- \7 y1 r8 `5 Y- I
29.3 Nitroaldol Reaction9 f- |, X! O7 y3 w) |
Masakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 1075
" D6 j- Z. q% Z p5 P/ z30 Addition of Acyl Carbanion Equivalents to
. Q5 l0 D( D$ }( @0 u) a' hCarbonyl Groups and Enones
, i+ `. w5 G) C* c- c2 Y {Dieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093! {/ Z, A0 o) ^" r2 r3 e$ p; I
31 Conjugate Addition Reactions/ D' E9 C7 x% \! V% T$ f* k
31.1 Conjugate Addition of Organometallic Reagents) T3 y# ], o0 U d; J' K& H, o: @
Kiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 11055 W- q' b: i# _" l- K4 J& K
31.2 Conjugate Addition of Stabilized Carbanions
* n/ `" N% ~+ B! B5 k$ NMasahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121
0 H9 d3 J; H& N2 m* y" Q32 Ene-Type Reactions
. W6 L* f1 N' `* o+ z) T5 f! x8 y, KKoichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 1143- ?6 t6 b5 A' b7 C0 ?6 x
33 Cycloaddition Reactions
/ d+ ~5 E+ R9 e33.1 Diels-Alder Reactions
8 w4 Q, N5 ~9 v! {$ uDavid A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 1177
+ `, n6 K0 e. S33.2 Hetero-Diels-Alder and Related Reactions. E6 d: T) N4 g6 u/ q
Takashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237' ?7 Q+ O0 o! L: R$ x2 G2 a
33.3 [2+2] Cycloaddition Reactions
5 Y$ }. Q5 X0 m/ I0 L: Y& ~Yujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 1255
* S. m r7 w' J$ w. j34 Additions to Enolates
1 K' ?9 u% K8 E- y. Q t) N34.1 Alkylation of Enolates# x8 @( s) A% U2 G5 V) T' J/ _( U
David L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1273. F" M. L) P. D
34.2 Protonation of Enolates
% x& K. n. q5 [7 r8 W+ rAkira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 1295; Z, p2 \! L& V' e6 _
35Ring Opening of Epoxides and Related Reactions4 p6 @* x% G) r; b" Y {. x/ v
Eric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 13093 r+ {. L" V. f7 I
36 Polymerization Reactions9 h, ^, ? }, W. {
Geoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1329 O$ I7 h5 }) f* ?. b" i9 K
37 Heterogeneous Catalysis
7 z9 [% a. m9 j, SHans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 13534 K% S9 ~' G& ^8 q' Y( a
38 Catalyst Immobilization
9 W! p6 ~( w6 R5 i# B# u, `38.1 Catalyst Immobilization: Solid Supports% ^+ q! _; U% v" O! D! _+ |
Beno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 1367$ A2 Y* S R. L) {4 R" k
38.2 Catalyst Immobilization: Two-Phase Systems
+ u: D7 @) ^/ ]7 r. e0 W* ]) E9 L0 EGünther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377
0 A. I. `9 c% p1 a" I6 }& |/ M39 Combinatorial Approaches- k) y9 I; E _
Ken D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 13898 q5 f2 O% a/ k: u/ e5 n4 w
40 Catalytic Antibodies4 _& c1 _; W/ K
Paul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 14032 p! J2 {, N3 \- h; B
41 Industrial Applications
7 r9 \; o" ?4 B- M. U, T* D41.1 The Chiral Switch of Metolachlor
( o. }; p' Y- W! p! Q3 G% x' SHans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 1427
1 D: o8 r& h. z- U: n9 \) b41.2 Process R&D of Pharmaceuticals, Vitamins, ' N5 U- M! V5 s0 B
and Fine Chemicals
; U8 r/ \9 J* {Rudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 14399 x/ m4 s* x, A# l3 b' J6 m) |
41.3 Cyclopropanation
2 R* V- D( t* O" XTadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14517 a% P% f2 f" n8 }1 K6 D) R
41.4 Asymmetric Isomerization of Olefins3 \' C3 \9 [: T5 \0 z
Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1461
K6 w$ m& `2 A5 H7 `* c6 Z/ F42 Future Perspectives in Asymmetric Catalysis O, `1 T2 [0 c0 A5 X
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1473
1 t6 h) b% m: T3 f# h% e; e( eSubject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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