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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。
) X/ V) a0 @( O: m. m! ^% z3 s2 ^" Z( j) T
Volume I8 K4 W. o& J# o! N% L6 J" ?% ?
1 Introduction2 H' g& `4 Z: E4 a# |
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 T1 P( X# Q* J/ P
2 Historical Perspective
& X% ?; D+ b% n$ r2 Y5 W8 F% CHenri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
8 y0 ^' w8 Y4 _: [$ N! d" F1 w3 Basic Principles of Asymmetric Synthesis* y: @6 o: S4 d/ S4 i) ]! M
Johann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
% o( Q& S4 u. _: q- v4 t. l& d4 General Aspects of Asymmetric Catalysis0 ^7 \$ e( ^+ S: N3 T
4.1 Non-Linear Effects and Autocatalysis* n4 D- u, t+ C+ U$ Y0 S9 a
Henri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 101
& n0 m' F/ Y ] O0 C- M d5Hydrogenation of Carbon-Carbon Double Bonds# n- B; z/ M$ J
5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds
- C+ \6 @8 H# p, p7 Q+ s, eJohn M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121
8 d; o! u/ d. b* B1 k5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds
9 ^# g: `- N O9 I2 J' N; J, J5 nRonald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183
- C: K" y5 d+ U. g$ I/ l6 Reduction of Carbonyl and Imino Groups
+ p# _! s7 e! z6.1 Hydrogenation of Carbonyl Groups, E6 ~; s- r6 P0 @- l! U
T. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
/ ]* _. I9 t8 a* J6.2 Hydrogenation of Imino Groups
; o% z+ f# N* M* o- I c7 S% h J, zHans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 247$ l$ N M, ?5 N
6.3 Hydrosilylation of Carbonyl and Imino Groups
! F; J$ O" r+ WHisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267* H& {$ b; i" I3 |; S+ t8 k
6.4 Hydroboration of Carbonyl Groups
' |" B7 R8 ^; y. V& g5 W4 ]Shinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2893 a% C" j0 o! v. G5 B3 @4 b/ F
7 Hydrosilylation of Carbon-Carbon Double Bonds
& a* @: D1 |! Q7 w V5 ^+ }! I' M; WTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3199 L/ `+ e+ _, P# [; D
8 Hydroalumination of Carbon-Carbon Double Bonds
& L/ i6 i6 B" T) _/ \5 IMark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 337
. \3 F6 `! i! H+ x8 `9 Hydroboration of Carbon-Carbon Double Bonds
8 P9 Y+ E" F, A. p) C W2 nTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351
: |5 D x& y/ ]7 j10 Hydrocyanation of Carbon-Carbon Double Bonds# G7 @7 H' t3 G2 Q: o* ~$ X- g) g& X: R
T.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 367& `7 \3 C& \' J; t* | P- V8 u+ T
11 Hydrocarbonylation of Carbon-Carbon Double Bonds
% C) g" u) Q# CKyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 381, I3 y! }& T( q3 j; x1 x
12 Hydrovinylation of Carbon-Carbon Double Bonds
# ~/ T/ a* G9 D. B$ H$ Q5 OT.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 417
- b$ w2 q' Y3 x/ N% U13 Carbometalation of Carbon-Carbon Double Bonds
9 f$ k- _. @: v; G' N* c( gAmir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 431
1 ~! [6 g$ g- Q- T. c4 c6 b14 Heck Reaction
( }% k2 i" Z5 z" `9 uMasakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 4578 N+ s5 o5 ^3 l
Volume II" N9 o2 ~& ?/ R1 l
15 Pauson-Khand Type Reactions9 @9 I9 [$ U S2 x, T# R
Stephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 491( _( O& a1 c4 [1 ]7 t. Z
16 Cyclopropanation and C-H Insertion Reactions4 j4 q5 `5 Q( T4 g% e
16.1 Cyclopropanation and C-H Insertion with Cu
7 _9 |. \) f. E$ G$ ]+ X& _8 k$ o. G# YAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513
' A8 V' n n; d. |# w16.2 Cyclopropanation and C-H Insertion with Rh
/ S" F: Q$ Q! S" aKevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 539
& }8 O/ k# n: D16.3 Cyclopropanation and C-H Insertion with Metals * n% Z6 J7 D# _( {/ g8 X A9 N
Other Than Cu and Rh1 @5 b2 v: r$ A* I$ W. J# M
André B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 581
/ p, g8 i7 y: B$ \) |/ t+ x7 i, i7 j17 Aziridination
4 q9 t! U9 O% K2 yEric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6071 Z1 O6 a! g4 X( @/ Z% c
18 Epoxidation
4 c( h+ [* z0 I5 \18.1 Epoxidation of Allylic Alcohols4 V) E" y, [% y5 }
Tsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6215 U# O+ Q5 r( g
18.2 Epoxidation of Alkenes Other than Allylic Alcohols
2 s0 x% u; f, |. X9 aEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 649
: x# O) v" f/ n0 \" g/ z7 q18.3 Epoxide Formation of Enones and Aldehydes - S4 T8 }4 I, F- f' f
Varinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679, K% _5 ?( r" w: n2 [$ I8 Z
19 Oxidation of Sulfides
# b7 i* Q5 `1 v0 t+ ~. HCarsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 6977 B* @) r; E& c7 O0 j; s& y
20 Dihydroxylation of Carbon-Carbon Double Bonds* A8 G. H" _' q4 N2 d/ w
Istvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 713# S1 g+ r2 `& O) ?! {
21 C-H Oxidation
' p1 S$ J* t/ H. p0 H) _Tsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 791
; Y) Q, G' @) n" ` j% ]22 Baeyer-Villiger Reaction- Z' q1 S h/ P& X! n* @4 u
Carsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 803+ _4 ~' \* R' E4 Z0 B& d. q
23 Isomerization of Carbon-Carbon Double Bonds/ p; Z1 x" _9 a1 ~$ R1 T! h
Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 813
7 _$ t3 S6 S$ J- J! A3 Z* q' X. F24 Allylic Substitution Reactions
: ] i1 n5 c5 w& L3 Q8 vAndreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 833
}7 g& Q( q# v9 E- [25Cross-Coupling Reactions; l; t; A$ X# V5 g
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8871 e8 Y. W4 n# Z \, b, j) u6 m& l
26 Alkylation of Carbonyl and Imino Groups
& s& K7 Y/ I8 k G: N7 \5 i/ `9 Z26.1 Alkylation of Carbonyl Groups
" b, {+ L3 \ C+ b" wKenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 911 w" Y# B% ]1 r2 q
26.2 Alkylation of Imino Groups
+ U$ c5 {- H- j+ h0 F8 sScott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 923 T, n5 n8 G: M" W6 v- j! @
27 Allylation of Carbonyl Groups
; o! I- b3 l% O1 Y0 Y9 a- b* sAkira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 965' C9 N# h6 D. Z4 j7 p
28 Cyanation of Carbonyl and Imino Groups% f9 N9 q" M! S! h# ^* ]
Atsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 983& q/ s3 S2 f: Q4 e: q
Volume III8 M4 J" q8 I/ H, D5 q
29 Aldol Reactions
2 n. `4 ]" b U! ?& A! d; t29.1 Mukaiyama Aldol Reaction
' G( V. b' K: KErick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997
* X! @; I$ D0 Y' f/ s1 |- d29.2 Addition of Isocyanocarboxylates to Aldehydes% p" c" g( @0 ]( a0 W( z. J1 K/ A
Ryoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 1067' n/ k4 ]9 Y! p, \8 w6 }( u G
29.3 Nitroaldol Reaction
& x5 Y4 x4 p; b L; M% }Masakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 1075
, _2 ]8 @9 Q) U* l30 Addition of Acyl Carbanion Equivalents to " w3 C+ w0 X" F9 A) ]# k
Carbonyl Groups and Enones+ u W3 [% C/ x5 L$ [1 l8 n0 g
Dieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093/ r4 m4 z3 v+ Z- M
31 Conjugate Addition Reactions
- w* t/ u& V$ s7 c H9 f+ N4 T8 r31.1 Conjugate Addition of Organometallic Reagents$ r! e( G1 r7 M% N' V% r
Kiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 1105, @" v% O c5 S& r
31.2 Conjugate Addition of Stabilized Carbanions
7 F6 D! o2 z z" A& J7 AMasahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 11210 _$ G7 y: m X0 c2 m" x
32 Ene-Type Reactions
5 t7 ^! \6 W* h( U$ XKoichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 11433 K# N, d+ o- {6 F: B- a; p& `+ \) o
33 Cycloaddition Reactions
+ D+ Q" d8 K% \4 A; O q33.1 Diels-Alder Reactions. X- i; D3 u' {) f( [$ K1 d9 j; p
David A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 11774 J# z* `6 d9 x9 x, u
33.2 Hetero-Diels-Alder and Related Reactions
- d& V' f! H2 b# dTakashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237* T6 @) K' f/ M$ f" D) I1 Y
33.3 [2+2] Cycloaddition Reactions + t: \4 w" w) ]+ M( j
Yujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 1255
5 T0 W) U6 k# l! [7 |34 Additions to Enolates# z! G- F' c" P/ t2 Z
34.1 Alkylation of Enolates
" H- ~# ~) d2 I# [$ ~# q7 RDavid L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1273, T: F/ y9 ?* p J0 p( w9 H- ~( ~
34.2 Protonation of Enolates y2 K& n, c$ g( }( e
Akira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 1295' R" A3 h1 Y& C2 d" |# ~+ N
35Ring Opening of Epoxides and Related Reactions
4 [5 x8 { w- F) Z5 j' T* \' KEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 1309
0 d2 T6 [$ u2 ?2 W$ Y' n36 Polymerization Reactions& w: A4 D. }1 d) D$ b8 N
Geoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1329
) @, x9 y: N+ A, V' P. { q% u37 Heterogeneous Catalysis- C3 H, t6 h' W5 X: F
Hans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 1353
+ @# P6 Z# r1 P+ j7 L/ q. m: v% S38 Catalyst Immobilization! W. F' S- F3 H; o( y* d
38.1 Catalyst Immobilization: Solid Supports# Z* k% V( X' c: ?) \ ~; u4 ], A
Beno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 1367
' j& X7 |6 ]- h# s38.2 Catalyst Immobilization: Two-Phase Systems+ w- l( R/ m. Z- u4 F$ e9 V% K7 z
Günther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377
k6 i& T! {% {% c39 Combinatorial Approaches
' [) ]; _7 `' @. iKen D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 1389& R% X; `4 m1 m. j' u
40 Catalytic Antibodies
, s! l! ]1 N& tPaul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 1403
" P& I: Q) B9 \, z4 d1 h5 h41 Industrial Applications* i$ K. ~6 {( W0 z! a
41.1 The Chiral Switch of Metolachlor6 {- c9 U' a. U. S$ v8 n
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 1427
$ F2 f7 f* z: `) K6 A41.2 Process R&D of Pharmaceuticals, Vitamins,
$ O, H4 x7 U* zand Fine Chemicals* [9 y) x) P: [) s4 u) O& q& c
Rudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 1439
, p8 t2 P, e6 P' r# A41.3 Cyclopropanation
}& N* T8 b: F5 k! h0 \Tadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1451" l% y# @, G" E3 T# Q# Q
41.4 Asymmetric Isomerization of Olefins
5 E# Q) y5 @6 wSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14619 B( [ |1 I! E8 } U5 l5 c
42 Future Perspectives in Asymmetric Catalysis9 c' L. s! V4 b2 x) a
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1473
; {% g# h2 S$ qSubject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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