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发表于 2008-2-11 14:19:15
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来自: 中国江西南昌
Efficiency increases in fossil energy boilers and steam turbines are being achieved by increasing the0 u' T, _4 V* h
temperature and pressure at the turbine inlets well beyond the critical point of water. To allow these
+ r' ]7 H" [$ Y. I3 H1 pincreases, advanced materials are needed that are able to withstand the higher temperatures and6 `/ r; Y1 f2 Q4 ~* `
pressures in terms of strength, creep, and oxidation resistance. As part of a larger collaborative effort,5 M2 L9 D7 d7 E+ C
the Albany Research Center (ARC) is examining the steam-side oxidation behavior for ultrasupercritical
z) b! L9 `! Q& M: @(USC) steam turbine applications. Initial tests are being done on six alloys identified as0 Q, F1 _$ w9 J& i6 W. s
candidates for USC steam boiler applications: ferritic alloy SAVE12, austenitic alloy Super 304H, the
- s1 ^- k/ o! y/ G0 Ahigh Cr-high Ni alloy HR6W, and the nickel-base superalloys Inconel 617, Haynes 230, and Inconel8 m' h8 m% ^5 \* n4 b7 y* J
740. Each of these alloys has very high strength for its alloy type. Three types of experiments are
1 L$ G7 z& J1 U5 j6 U0 wplanned: cyclic oxidation in air plus steam at atmospheric pressure, thermogravimetric analysis (TGA)$ l- j; }& x/ o6 a4 E' R5 n3 O
in steam at atmospheric pressure, and exposure tests in supercritical steam up to 650ºC (1202°F) and3 j5 D% L" H3 [
34.5 MPa (5000 psi). The atmospheric pressure tests, combined with supercritical exposures at 13.8, l1 [, q5 G. Y0 W' u/ S$ |0 a4 Q
20.7, 24.6, and 34.5 MPa (2000, 3000, 4000, and 5000 psi) should allow the determination of the effect
7 D9 J$ N# Z- s R: _" A0 Rof pressure on the oxidation process. |
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