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【书名】《Emulsions, Foams, and Suspensions - Fundamentals and Applications》(PDF+书签) ! A$ v& Q3 B) n* Y; Y
【作者】Laurier L. Schramm编著 . I# y. C6 J9 L B
【出版社】Wiley
- u" p# z1 P2 E2 K4 y【出版日期】2005
0 H- E8 v* A( r【ISBN】 3-527-30743-56 u8 ?# d2 g" }
【开本】32开
; V1 {3 [ c: X+ S2 E ^【页数】465页/ i/ z& h0 g k: `/ i5 F
【大小】4.61M& J- }) W# a4 U8 K% Q
【格式】PDF+一级详细书签 高清晰扫描版
$ O- h$ t! u( _/ ]" l# E
( ?3 p! [/ W# ~全书共有3个压缩包
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【内容简介】
" W& W# C6 L$ v9 @" q, g! x' q* @3 c 本书是表面界面牛人Laurier L. Schramm根据自己的教学课件 经验 结合实际问题, 编著而成.$ o+ F3 v. T+ ?; `# w& O7 q$ O& r
文中 对乳液 发泡 悬浮 现象, 从理论基础 实验 出发, 以实践应用为根本, 详细讲述. 是涉及本领域 的初学者必备读本.( j' F- K; g0 N/ j
Preface XIII
: n1 W3 \# j% i+ b' p1 Introduction 1* l9 A# f' A3 Q8 } d
1.1 TheColloidal State 16 ^# q( S0 {# B# K* e% A5 [5 s
1.2 Classification of Emulsions, Foams,and Suspensions 4
: E+ W1 y1 R, C: P( Z8 [1.2.1 Emulsions 4
$ H" g* u/ j; J1.2.2 Foams 7
( p# d! [4 Z2 `) a1.2.3 Suspensions 9
4 Z# Y2 K5 h) `- L V' j1.3 Characterization andStability 115 K* N) x9 a0 s$ F0 r E
2 Dispersion and Dispersed Species Characterization 13
3 ] B" }7 X5 j7 X& _2.1 SurfaceArea, Porosity,andPermeability 13
5 F# }' X+ m* y* }3 W$ g' W2.2 Size andSize Distribution 18* N8 m9 v" S- T9 H7 g" x; J; A
2.2.1 Microscopy 20
% v/ F2 D6 e' l4 f1 V( s' o% W2.2.2 Sieving 23
! R$ h; |7 `+ x3 L& @2.2.3 Radiation Scattering 240 q# Y6 O& a" [3 d7 b
2.2.4 Ultramicroscopy 264 O, ]( d3 z: E6 d1 n% W
2.2.5 OtherTechniques 27
# ?1 b0 _1 W/ |; x# O$ D0 a) ]) T2.3 Conductivity 285 `& V I+ x6 ]& B3 v
2.3.1 Dispersed Phase Identification 28! Q+ p" n0 [' S1 G/ O
2.3.2 Sensing-zone Techniques 28/ O6 d7 Q* j% H7 G5 A1 F" P; w) y& c9 {
2.3.3 Conductivity of Dispersions 29
X9 y9 N2 F" L6 Y2.4 Sedimentation, Creaming,and Centrifugation 30
& B4 e5 m& Q; R# N; W0 _6 ?2.4.1 Sedimentation andCreaming 30/ T, ?- }6 z9 j; A7 j6 i
2.4.2 Centrifugationand Ultracentrifugation 38
* W: M+ v4 w6 ]2 m% F$ f2.5 Characterization ofEmulsions 41
0 l' ~5 E( }4 ?3 L+ f2 r; }0 d2.5.1 Appearance andEmulsion Type 417 _1 @0 t& ~% ]9 D
2.5.2 Experimental Assessment ofEmulsion Stability 433 l; w5 x! w. V2 O/ ], G9 f4 ~
2.5.3 Composition 442 I& l$ L( s+ e5 V
2.6 Characterization ofFoams 44
* ]8 S. L6 a. e2.6.1 Appearance andFoamType 44
' Z8 O. {& Y' r+ w3 Y7 O4 M2.6.2 Experimental Assessment ofFoamStability 472 P% h( o+ m$ S8 b9 ~4 ?
2.7 Characterization ofSuspensions 50* |, V" G8 E# W! i2 D1 V$ Q1 @
2.7.1 Chemical andSurface Analysis 50
. A* n* A. u- J U' h( c2.7.2 Experimental Assessment ofSuspension Stability 50
! w. z, n$ x& t a7 u3 Interfacial Energetics 53# b2 M9 A0 [7 k- z
3.1 SurfaceArea 53
2 M5 A, C6 R1 C# W3 O+ y3.2 Surfaceand InterfacialTensions 54
2 }: v3 D, k1 `! f/ \$ u$ a3.2.1 Principles 54
6 P; B# T* M3 b3.2.2 Equationof Young–Laplace 61) }0 C8 A& _/ z% ^" @
3.2.3 Measurement 615 T' `" J7 L# p' }* y, ]5 J
3.2.4 Experimental Results forDispersions 70
/ A* W2 D8 f; Z0 O5 _3.3 Pressure andCurved Surfaces 72. f. S, C% I$ Y9 l
3.4 Contact Angle andWettability 73
6 @0 e5 \+ w% |# T7 r3.5 Surfactants andMicelles 76
+ r/ ~( ~4 n/ J* ~) L% e3.5.1 SurfaceActivity 769 g( |0 `" c5 v2 H5 ]5 Z P o1 y
3.5.2 Classification and Analysisof Surfactants 80
' Z( D. z2 R( ]3 u4 ?, \3.5.3 Micelles 82
/ T1 j: `9 @* i- D3.5.4 SurfaceElasticity 86
& K/ m% k1 f. F" t! C7 {+ V3.6 Applications ofSurface Activity 897 B. Z# n+ ~2 v. s
3.6.1 Surfactants andEmulsification 89
: [0 D* _! R1 `& K' e$ D3.6.2 Surfactants andFoaming 91
4 \; R; ~! d5 K' m# D, w3.6.3 Surfactants andFlotation 92
8 t, ^! G3 C1 H9 X1 v3.6.4 Surfactants andSuspensions 93 h. q. D" N$ }$ O0 E8 L
3.6.5 Surfactants andWetting 94
6 q. k+ ]5 N: ?) l, v3.6.6 Surfactants andDetergency 94) O- v% Y# n$ B
3.7 OtherLyophilicColloids: Microemulsions 97
. b; n: c9 C* d; d2 ^- I4 Electrokinetics 101
& e5 H! j- g$ R8 `6 _4.1 Charged Interfaces 101
t" d. K0 n6 {4.2 ElectricDouble Layer 103 ~- m4 p: g6 L
4.3 Electrokinetic Phenomena 105* I1 y, r M) K8 Y% s2 p
4.3.1 Electrophoresis 109
8 \ E; J) e u2 I; h4.3.2 Point ofZero Chargeand Isoelectric Point 1133 E+ U0 H* D' r/ C! L
4.3.3 Electrodialysis 114; v9 g i1 r6 ?! T
4.4 Electrostatic Propertiesin Non-aqueous Media 115: [+ x+ r/ D5 Y) L; d
5 Colloid Stability 117; ]* W: ~, |. E* S" s9 f
5.1 Electrostatic andDispersion Forces 119! R' {* X6 ~' k
5.1.1 Repulsive Forces 120
0 ]- \+ i3 x% {& \% `* a5.1.2 Dispersion Forces 121
0 h, o8 T9 {" \3 S' U* H5.2 DLVO TheoryandPractice 122
, {' R) u+ V( M1 L- n- W5.2.1 Theory 122
$ W& ]: z$ B4 c( }5.2.2 PracticalGuidelines 1282 s) i+ g* n, E) p% ?& o" J
5.2.3 Schulze–HardyRule 130
% j3 X, x; }3 c" U9 o5 ^0 i6 E, Y* V8 K5.2.4 Peptization 132
. N, A( g" t/ y L5 e1 ~& b5.3 Hydrationand StericEffects 132% }& d/ E# F4 J. R' A5 A
5.3.1 Steric Stabilization 135
. Z( ~& Y: [# o) `% }5.4 Additional Stabilizing Influences 1373 {- E% b( S+ M- B8 e" e2 _3 [
5.4.1 OtherStabilizing Influencesfor Suspensions Stability 137
1 O4 A) x7 W# o5.4.2 OtherInfluences on Emulsion Stability 1382 O+ h/ \4 C' e; \+ m
5.4.3 OtherInfluences on FoamStability 141
/ X2 q: w) }1 U! I3 `; e$ }5.5 Kinetics 143# }# s, S. X ~
5.6 Destabilization ofColloids 146
, J1 f; @/ J! s% s6 g* m9 }( r5.6.1 AggregationandFlocculation 1475 o; ~: @- d, W
5.6.2 Structures inFlocculation 1482 U& [+ ~/ B+ t! q
5.6.3 BridgingFlocculation 149
6 Y' w1 O! g/ G/ v5.6.4 AgglomerationFlocculation 151/ r9 k0 |) i& U1 x3 J
5.6.5 Depletion Flocculation 151& S' Q# [2 N( H5 R' g i
5.6.6 Filtration 152
0 `* y. w/ p5 i) ~; T5.6.7 FoamStability inthePresence of Oil 152
5 I7 f- A. `0 l" |! y6 Colloid Rheology 155
7 W1 U- {, R1 `7 Z! B+ m- |% f. c z5 A6.1 Principles 156* ~; r. Q- F) {# }1 w& X; ^/ N) W
6.2 Measurement 159
; P, v2 L% G' a; z: A. C% D! d6.2.1 Tube Methods 160
0 z7 D5 J2 B& i5 H. u6.2.2 Rotationalmethods 164
! A( o$ j) W8 C6 R# L9 c' P. l& ?6.2.3 Othermethods 1675 P- D4 L' W9 D: W
6.3 Non-Newtonian Flow Properties 170
) z; u: J& A n4 {. P6.3.1 Pseudoplasticity 1730 {3 F2 V) F# w( z) S6 E; v
6.3.2 Dilatancy 174+ y6 r& H1 D V" a' g
6.3.3 Plasticity/Pseudoplasticity withYield Stress 174
' ?. S/ H! I) j. a: e, H6.3.4 Thixotropy 176( x! }' R' [. S+ U
6.3.5 Rheopexy 177% h- q: @6 a' T2 v
6.3.6 Viscoelasticity 178* {- W' v5 w" a1 u2 w; X8 V6 `2 P
6.3.7 Rheomalaxis 1786 E4 L$ S( W) Q' r& v& h
6.3.8 Summary 179
. p7 C5 ^/ p. [6.4 OtherViscosityNomenclature andParameters 179
6 p+ M/ z# L( y& J6.4.1 ViscosityNomenclature 1791 G3 M+ |$ {. u* |4 d3 L4 n
6.4.2 OtherViscosityParameters 180
! w4 @ E% i! u7 }- j8 a" O( ` F! v6.4.3 Experimental Considerations 182
& G6 @' C0 x2 E6 K& M6.5 Dispersion Rheology 183
" b9 l* G, I. B% t* k6.5.1 Einstein’s Equation 183! h, W7 I, p5 e0 v4 L1 j
6.5.2 VirialExpansions 186
" E$ v/ A# u6 y3 I: N& a6.5.3 OtherEmpirical Equations 188
/ r5 _! [8 _) B" v+ H; r( F6.5.4 Dispersed Phase Size andPolydispersity 188 k7 k+ M( \' e8 M
6.5.5 Additional Considerations forEmulsions andFoams 189% G# Y' U# M) w
6.5.6 OtherEquations 192" j, a, ?, {8 e6 g4 L" L! f* q* ?3 C
6.6 SurfaceRheology 193
) y" d. Z6 w) j, w( P6.7 Flow inPipelines andConstraining Media 1949 ^6 z6 D# F% Z2 n# j& W) G
6.7.1 Applications inPipeline Flow 194
: R/ y6 U& [/ D6 O6.7.2 Applications inPorousMedia 197" w- `' q) b q* b$ E8 j9 t
7 Preparation, Inhibition, and Destruction of Dispersions 201
0 R& c! l2 B( c7 u! b9 l7.1 Preparation 2024 E: v" e( p. ~, N4 {$ P1 s
7.1.1 Preparation ofEmulsions 202
& A9 Z- S. M+ ^: Q8 q& q3 n7.1.2 Preparation ofFoams 209
e* U1 m6 ? P0 v6 x7.1.3 Preparation ofSuspensions 211
9 d( h0 ~( r; r; ~8 V5 w7.1.4 Ostwald Ripening 2152 f. k& B. s- d! y9 d% S. J
7.2 Destructionand/or Inhibition 215. K3 [+ Z3 q; S
7.2.1 Demulsification 215
2 s, `9 G( h+ ?; {4 ?7.2.2 Antifoaming andDefoaming 220
: m- `3 s, p# o- @" X8 Introduction to Practical and Industrial Applications 223
* `; u2 ?# b& f" U8.1 General Uses 2231 J$ D! \" ]9 d
8.2 Emulsions 224" x2 G; L7 }8 [! C3 [2 @' ~
8.3 Foams 227
" l% g/ Y& k A" v u1 e/ y8.4 Suspensions 2289 f! X2 u }$ J- N4 e
8.5 Hazards 229; b7 Y; r: ~4 t( W
9 Applications inthe Environment 231
4 I% A8 j. E9 V9.1 Introduction 231! p* L/ P7 u5 i& B: W
9.2 Rocks,Sediments, andSoils 231/ Z8 ~! Q6 S3 L
9.3 Environmental Soil Remediation 234+ b9 A% h2 ]+ O: ?
9.4 Water andWastewater Treatment 236
3 a$ g1 [8 `; m9.5 Spillsand OtherHazards 2384 B" \2 I+ r+ ?
9.6 Environmental FoamBlankets 2401 G. B7 F6 S4 `3 w
10 Mining and Mineral Processing Applications 243 r. T; W$ y+ T2 h, c5 { c/ e: J
10.1 Introduction 2439 @2 H8 ?- m. K/ X4 }6 ~ V3 i
10.2 Hydraulic Mining andHydrotransport 243
6 G3 w# M. U, A9 o2 P10.3 Mineral Flotation 245
/ L! I& X h* V8 |/ |' Q10.3.1 Carrier,Emulsion,andFloc Flotation 257
2 O$ c4 o! J( R1 K2 |5 w2 x5 {* s10.4 Tailings andTailings Ponds 258$ N M7 I& A, k7 w
10.5 Dust-Suppressing FoamBlankets 261& `9 F; T L1 b
11 Petroleum Industry Applications 263, T* d; {- r% s( \5 N
11.1 Oil Wells andNear Wells 265 Z+ S, R m' [4 j4 w% @
11.1.1 Drilling andCompletion Fluids 265
( `: O9 X, q( ]- k$ {3 X* X# ?11.1.2 Well Stimulation: Fracturing andAcidizing 267, s7 z t z0 R
11.2 Reservoirs 268
' U4 v9 P% _6 A) c: f11.2.1 Primary andSecondaryOil Recovery 2685 g8 x( R$ t, h2 E
11.2.2 Enhanced (Tertiary) Oil Recovery 270
4 L) ~/ a8 f, p+ n11.3 SurfaceOperations 278
& |/ P. q* r8 o! N) |11.3.1 SurfaceTreatment 278
* q: o0 B0 T& e. c+ X! t* j/ y11.3.2 Oil SandsProcessing 280
- Q {5 L# Z( \2 X11.3.3 Pipeline Transportation 2821 `' V/ D/ \! i
11.3.4 Upgradersand Refineries 283
; ~2 i/ D) J6 [3 a: l1 O3 f12 Manufacturing and Materials Science Applications 285: r; R) [4 c7 `5 ~. k3 l
12.1 Introduction 2857 b+ L, B2 K2 K9 a* N
12.2 Papermaking 285
7 X" A8 r, R5 X# A' L0 k12.3 Emulsions forRoadPaving 2874 H4 N4 b! } o+ V6 k0 P1 w
12.4 Metal-working 288% n1 {8 U, F+ b' c; D; J0 r h
12.5 Cleaning Processes 289# R8 q3 N) H' Q' R1 P' M8 D
12.5.1 Detergency 2897 E1 O# H( }' C. i W9 o
12.5.2 De-inking 292
- x+ Z1 X' i% g. i3 {# c. c6 R3 Z2 P12.6 SurfaceCoatings including PaintsandInks 294
; O7 G& o6 q$ @9 ?, x5 ^9 ?# Y p12.7 Polymer Synthesis 297$ }7 Y" j3 U6 V! z- X. Y: T- O
12.8 CeramicsManufacture 297/ q! S% Z- l9 z
12.9 Fire-FightingFoams 298) Y; R: g% j. ?) c/ v7 _1 w
13 Food Productand Agricultural Applications 301
* ~1 U! D' j7 N p) v5 r/ b13.1 Introductionto Food Colloids 301
3 S. q- a2 Z- @9 H9 t9 `; R9 u6 A; j13.2 Stabilizing Agents 302. [: {; _0 g- \- S
13.3 Preparation 304) {! S, Z# V1 J' o
13.4 Stability 304) H8 l' D3 e* @1 s
13.5 Protein-stabilized Emulsions 306) z5 N! b9 @& L* R, S+ D/ d( v
13.5.1 IceCream 3096 K$ J I; s$ M1 D
13.5.2 Cream Liqueurs 311
i, M; ^ r8 E/ U13.6 Non-protein-stabilized Emulsions 3126 M1 ~, D0 X' Y+ u* o
13.6.1 Carbonated Soft Drinks 314
8 Q, |- @" c4 S4 M% N13.7 FoamFood Products 314) L) w2 ~! U4 R! a8 w6 e
13.7.1 Baked Products 315
3 A' P v. o* }" N% k, \' {1 _13.7.2 FoamToppings 316
+ r" x1 u, D5 m( }* T% }13.7.3 Champagne andBeer Foams 317
6 G* l' R/ x: z/ o13.7.4 Coffee Beverage Foam 318- h$ ? d* w* A. |
13.8 OtherFood Colloids 318; y3 z0 Z+ r! I" M
13.9 Introductionto Agricultural Colloids 321& G, }0 C/ w0 F0 d& u2 v
14 Biological and MedicalApplications 325
" _1 A v* J. W) C14.1 Introduction 325
4 V' u$ ~# i- b' ^/ P14.2 Vesicle Carriers 329
1 S2 c* t( T$ k A4 c3 w14.3 Polymer Coatings 330$ {! c3 O& z6 r, Z, d
14.4 Emulsion Carriers 332
5 o2 n( H- u( @, l% Y8 i14.5 Colloids inDiagnostics 334
$ Y; i- z8 U4 m* @. a15 Personal Care ProductApplications 337' E E& q0 N; D/ ~4 {* D O
15.1 Introduction 337# Z2 X9 G2 d7 m( v$ h( G
15.2 Detergents,Shampoos andConditioners 338
/ J- ?% |3 a2 t7 I9 {: k15.3 CosmeticSkin CareProducts 339- Q6 c, `( _9 S4 V" J
15.4 OtherPersonalCare Products 344. y6 s& \" B( k* w4 f
16 Emerging Areasin Emulsions, Foams and Suspensions 347% [; Z% {+ S) v- I9 x. _" n
16.1 SmartColloids 347
* R/ y* r- ?- B( _+ b t4 c16.2 Nanodispersions 3482 N! p2 T6 p- p
16.3 Combatting TerrorAgents 3532 s! y' D- W& m* E
17 Glossary of Emulsion, Foamand Suspension Terminology 357
4 F* F7 _8 {) G/ j2 U$ v17.1 Introduction 357
1 k+ v& ^: U) y; s17.2 Terms 357( u% G# L+ z8 h4 y0 i
18 References 401 z7 x9 z6 x9 I( i! K
Index 431
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) X% E. X3 c8 m+ z1 l+ J[ 本帖最后由 云动风清 于 2008-6-24 16:00 编辑 ] |
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