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POLYMER SOLUTIONS（聚合物溶液）
) x0 Q7 o. X* T$ k0 cPOLYMER SOLUTIONS
7 r% ]3 P5 C3 k
0 l! t0 |* H& p3 W& v: t3 B. wAn Introduction to Physical Properties; h% i3 e( B# r4 s
! x7 {( N# i3 ]9 H" x
IWAO TERAOKA7 T `* O2 J* O
Polytechnic University6 i0 k) [2 w8 L: Y, T: D% v1 Q0 D
Brooklyn, New York/ g$ ?! K3 }" U k8 e& @
; \0 L* i; p4 Y5 q) w+ n, TDesignations used by companies to distinguish their products are often claimed as trademarks.
) x) @4 C7 v& p9 bIn all instances where John Wiley & Sons, Inc., is aware of a claim, the product names appear - r+ ?2 f" Q6 Q2 `* s
in initial capital or ALL CAPITAL LETTERS. Readers, however, should contact the appropriate companies
+ ^0 o$ v& Y1 e5 v* efor more complete information regarding trademarks and registration.
( y; m% I' y; N; \Copyright © 2002 by John Wiley & Sons, Inc., New York. All rights reserved.
+ o$ W2 e# g1 D: ^! cNo part of this publication may be reproduced, stored in a retrieval system or transmitted in any
1 t3 ?) C# d( J2 b) @0 Cform or by any means, electronic or mechanical, including uploading, downloading, printing,
" v, a6 L: _2 L# J' j. Ldecompiling, recording or otherwise, except as permitted under Sections 107 or 108 of the 1976
+ U/ x4 l6 w/ G9 L- OUnited States Copyright Act, without the prior written permission of the Publisher. Requests to the$ s: Y) k" K: N7 Z. a% _
Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc.,& l- \- X( _8 S, d9 I; M; j
605 Third Avenue, New York, NY 10158-0012, (212) 850-6011, fax (212) 850-6008,
( G0 F) v/ d5 I* w- BE-Mail: PERMREQ @ WILEY.COM.3 `) s& \! f9 p+ {2 b) U# T, @
This publication is designed to provide accurate and authoritative information in regard to the subject! L& l6 |1 J( E5 e0 d. _4 ?
matter covered. It is sold with the understanding that the publisher is not engaged in rendering
0 Q% g y% Z: q+ \professional services. If professional advice or other expert assistance is required, the services of a) _+ J9 Q. M( d9 u6 M0 J4 e+ P8 Q
competent professional person should be sought.
6 h2 e+ W( Z! A" q# S6 ^- t: n# \4 D
& O2 _; g! o+ [- ]ISBN 0-471-22451-0
$ F! f$ s/ k' h1 @$ W
" A) v+ S! }9 }2 p5 D" n" x# CThis title is also available in print as ISBN 0-471-38929-3.
& i3 I4 e& D* A& @8 D0 VFor more information about Wiley products, visit our web site at www.Wiley.com.
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5 R, U! D( r& }6 D* p+ F) ~1 i, p
PREFACE
% @4 |7 i- ~( r* t( d8 c# D" F
1 D- R0 A2 R" GThe purpose of this textbook is twofold. One is to familiarize senior undergraduate$ t, c( s. m3 @5 Y
and entry-level graduate students in polymer science and chemistry programs with
. ]! q' S! U& _) M* bvarious concepts, theories, models, and experimental techniques for polymer solu-: i% p% q: D" r9 H. E% L; A: e
tions. The other is to serve as a reference material for academic and industrial- L6 S2 G/ T) \
researchers working in the area of polymer solutions as well as those in charge of
7 O9 Q! C2 ^& s# i, o' C# s/ X: xchromatographic characterization of polymers. Recent progress in instrumentation of
2 z9 J2 u9 v+ O6 zsize exclusion chromatography has paved the way for comprehensive one-stop char-
6 E# ~+ V# a2 Y- t; ` _9 Nacterization of polymer without the need for time-consuming fractionation. Size-( A6 T- I* ^# z5 G$ F$ S0 [
exclusion columns and on-line light scattering detectors are the key components in' i4 e: p! s$ w# V) t1 y7 @3 t
the instrumentation. The principles of size exclusion by small pores will be explained,
3 e; A4 W- W) Y: Mas will be principles of light-scattering measurement, both static and dynamic.4 U4 Q2 N% c2 y/ R1 M% O% g
3 Q/ h+ b) ]+ b& C* q- a* R" FThis textbook emphasizes fundamental concepts and was not rewritten as a re-0 _) j+ p$ E7 M9 t
search monograph. The author has avoided still-controversial topics such as poly-$ \$ K. F' C0 O$ p+ C
electrolytes. Each section contains many problems with solutions, some offered to
& D0 L: N/ w( radd topics not discussed in the main text but useful in real polymer solution systems.
" n0 I W' T; ^" ]0 q5 k) O1 BThe author is deeply indebted to pioneering works described in the famed text-
! W* C% Y( \* j2 F6 ~books of de Gennes and Doi/Edwards as well as the graduate courses the author: s8 @0 u- G. i2 G, t; a
took at the University of Tokyo. The author also would like to thank his advisors
# B+ P( c2 R' Y0 T$ o, Q, |and colleagues he has met since coming to the U.S. for their guidance.
, H; k# V; P# m6 S: \9 IThis book uses three symbols to denote equality between two quantities A and B.( E8 j7 W K' K7 g" V; J3 E
+ r- Z% q4 w" t/ X- b. O1) ‘A B’ means A and B are exactly equal.
o+ N" B4 E& D) P; |8 h: a' F M9 }% L3 ^$ I/ L
2) ‘A B’ means A is nearly equal to B. It is either that the numerical coefficient" A4 U p" G3 W3 y) D0 a! f, w6 N
is approximated or that A and B are equal except for the numerical coefficient.9 A7 q& F7 s6 T4 b, C- _$ L) `6 _
, P! H* \( F3 v) s
3) ‘A B’ and ‘A B’ mean A is proportional to B. The dimension (unit) may; s/ u$ B' i; p
0 z. I7 M) U; f; m9 |$ G" kbe different between A and B.4 q5 l2 @ ?1 A$ s5 \7 Y) ?( r) f: M
Appendices for some mathematics formulas have been included at the end of the
. w. I9 |& B8 L2 S* l8 Qbook. The middle two chapters have their own appendices. Equations in the book-1 T0 f( Q9 `- x
end appendices are cited as Eq. Ax.y; equations in the chapter-end appendices are
+ b& d) O1 x5 Bcited as Eq. x.A.y; all the other equations are cited as Eq. x.y. Important equations' p+ O8 o3 Q* G \9 n. G
have been boxed. |
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发表于 2007-10-27 12:05:57
